[We’re] Having a few challenges with a stainless-steel S-curve mould
(15cm x 10cm [prepared with boron nitride]. … When we slump a piece of glass,
we get a frosted effect … in places where the glass was touching the mould at
the beginning. I don't think it's devitrification, because the glass itself
isn't cloudy, it's just hundreds of little bumps and dimples.
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Photo credit: Adrian Cresswell |
This is a mould that combines draping and slumping in the
same firing. The glass must drape over the hump and slump into the valley at
the same time. This is effectively two processes in the same firing. It does
require some compromise in scheduling as a result.
The evidence presented shows boron nitride – a slippery
surface – was used to prepare the mould. In another firing Thinfire – a
powdered surface – was used as a separator. Both created this marking on the
back. The schedule was not presented.
This indicates something other than the separator is
creating the problem. Note that the marking also occurs at the extreme right
end where the glass would be resting on the lip of the mould. The marking does
not occur where the glass is slumping down into the curve. It only occurs where
the glass is draping.
As suggested, this is not devitrification. That occurs on
the surface rather than on the bottom. This further indicates the difficulty is
between the glass and the mould.
I suggest the marks are from the glass sliding along the mould.
These are frequently called stretch marks. The glass is sliding and stretching
along the mould. This blog post contains much more information.
It is of course possible that insufficient boron nitride
was placed on the steel and the glass grabbed the steel. It is worth checking,
although I don’t think it likely.
You might think the Thinfire covering of the steel would
make everything smooth. However, Thinfire turns to powder and fibreglass
particles after about 400°C/753°F. These particles are drawn along as the glass
moves against the mould. The particles can bunch and remain as bumps on the
surface of the mould. This may account for the rougher surface with Thinfire
than boron nitride.
A summary
These stretch marks occur when the glass moves excessively against the mould. This
is usually a combination of high temperature and fast ramp rates. Slumping
should be done at the lowest practical temperature. The soak should be long,
rather than brief.
The Remedy
Fire more slowly and to a lower temperature. The Bullseye suggestion from their quick tips is for a double curve (or wave) mould of 250 x 210 x 40 mm (9.85"
x 8.25" x 1.6"). They suggest a ramp rate of 167°C to 660°C /1221°F
with a soak of 10 minutes for a 6mm/0.25” thick piece.
In my experience this is too fast. Slumping into this mould
can be done at 630°C/1167°F with a 30-minute soak in my kilns using the same
ramp rate.
This is a simple mould to slump and drape into. It is
essentially two partial cylinders pushed together in opposite directions. The
curves are gentle and progressive. There are no sharp changes of direction. These
factors mean that the slow and low approach will work well.
However, in this case the curves will be even tighter as the
full length is 150mm x 100mm/ 6” x 4”. The height is not given, but for a
self-standing piece, it likely to be a minimum of 40mm/1.6". This makes
for a tight curve on the mould. It is likely the glass will slide more than on
a gentle curve. My thought is that the steel mould has been produced without
knowledge - or testing - of the practicalities of getting the glass to bend to such
a small radius. This means that I would be trying a schedule of about
125°C/225°F per hour to a top temperature of about 630°C/1167°F with a 1.0 to a
1.5-hour soak. The glass is going slump much more slowly with this smaller span.
With gentle heating -slow ramp rate, long soak - the glass
gradually conforms to the shape of the mould without stretching over the
hump/crest of the mould. Instead, what happens is that the glass slips slightly
from the opposite end of the mould. To counteract this, I place the glass
6mm/0.25” over the upraised end of the ceramic mould. This then finishes just inside
the mould’s edge.
With a steel mould, this is not possible without the glass
hanging up on the hot and sharp edge. The glass will need to be at the edge or
just inside to prevent hanging up on the end of the mould. The glass will slip
down the mould a little, but not so much as to cause problems. It is possible
to prop a piece of fibre board at the upturned end of the wave mould to support
the overhanging glass if the full curve is required.
The glass on the high part of the mould will not stretch at
the low temperature, but gradually conform to the shape of the mould.
I have much more information on this and other things in the
eBook:
Low Temperature Kilnforming; an Evidence-Based Approach to Scheduling