Showing posts with label Low Temperature Kilnforming. Show all posts
Showing posts with label Low Temperature Kilnforming. Show all posts

Wednesday 13 March 2024

Heat Up vs Annealing

I am amazed by the effort put into ramp up rates, bubble squeezes, and top temperatures in comparison to annealing.  The emphasis on social media groups seems to be to get the right ramp rates for tack fuses and slumps, bubble squeezes, etc.  Most of the attention is on the way up to processing temperature.

The treatment of annealing and cooling is almost cavalier by comparison.  The attention seems to be on what temperature, and how long a soak is needed.  Then some arbitrary rate is used to cool to 370ºC/700ºF.



Annealing, in comparison to firing to top temperature, is both more complex and more vital to getting sound, lasting projects completed.  Skimping on annealing is an unsound practice leading to a lot of post-firing difficulties.

Annealing is more than a temperature and a time.  It is also the cooling to avoid inducing temporary stress. That stress during cooling can be large enough to break the glass.  This temporary stress is due to expansion differentials within the glass.

People often cite the saving of electricity as the reason for turning off at 370ºC/700ºF.  My response is that if the kiln is cooling off slower than the rate set, there will be no electricity used.  No electricity demands.  No controller intervention.  No relay operation.

Annealing at the lower end of the range with a three-stage cooling provides good results.  The results of Bullseye research on annealing are shown in their chart for annealing thick items.  It applies to glass 6mm and much larger.  It results from a recommendation to anneal at the lower end of the annealing range to get good anneals.  Other industrial research shows annealing in the lower end gives denser glass, and by implication, more robust glass.  Wissmach have accepted the results of Bullseye research and now recommend 482ºC/900ºF as the annealing temperature for their W96.  The annealing point of course remains at 516ºC/960ºF.

Bullseye research goes on to show that a progressive cooling gives the best results.  They recommend a three-stage cooling process.  The first is for the initial 55ºC/º100F below the annealing temperature, a second 55ºC/100ºF cooling and a final cooling to room temperature.

It is a good practice to schedule all three cooling rates.  It may be considered unnecessary because your kiln cools slower than the chart indicates.  Well, that is fine until you get into tack and contour fusing.  Then you will need the three-stage cooling process as you will be annealing for thicknesses up to 2.5 times actual height.

 

Of course, you can find out all the reasons for careful annealing in my book "Annealing; concepts, principles, practice" Available from Bullseye at

https://classes.bullseyeglass.com/ebooks/ebook-annealing-concepts-principles-practice.html

Or on Etsy in the VerrierStudio shop

https://www.etsy.com/uk/listing/1290856355/annealing-concepts-principles-practice?click_key=d86e32604406a8450fd73c6aabb4af58385cd9bc%3A1290856355&click_sum=9a81876e&ref=shop_home_active_4


Wednesday 27 December 2023

Scheduling with the Bullseye Annealing Chart

This post is about adapting the Bullseye chart Annealing Thick Slabs to write a schedule for any soda lime glass as used in kilnforming.

I frequently recommend that people should use the Bullseye chart for Annealing Thick Slabs in Celsius  and Fahrenheit.  This chart applies to glass from 6mm to 200mm (0.25” to 8”).

“Why should the Bullseye annealing chart be used instead of some other source?  I don’t use Bullseye.”

My answer is that the information in the chart is the most thoroughly researched set of tables for fusing compatible glass that is currently available.  This means that the soak times and rates for the thicknesses can be relied upon.

“How can it be used for glass other than Bullseye?”  

The rates and times given in the chart work for any soda lime glass, even float. It is only some of the temperatures that need to be changed.

"How do I do that?"  

My usual response is: substitute the annealing temperature for your glass into the one given in the Bullseye table.

 "It’s only half a schedule."

That is so.  The heating of glass is so dependent on layup, size, style, process, and purpose of the piece.  This makes it exceedingly difficult to suggest a generally applicable firing schedule.  People find this out after using already set schedules for a while. What works for one layup does not for another.

Devising a Schedule for the Heat Up

There is no recommendation from the chart on heat up.  You have to write your own schedule for the first ramps.  I can give some general advice on some of the things you need to be aware of while composing your schedule.

The essential element to note is that the Bullseye chart is based on evenly thick pieces of glass.  Tack fusing different thicknesses of glass across the piece, requires more caution. The practical process is to fire as for thicker pieces.  The amount of additional thickness is determined by the profile being used.  The calculation for addition depends on the final profile.  The calculation for thickness is as follows:

  • Contour fusing - multiply the thickest part by 1.5. 
  • Tack fusing - multiply the thickest part by 2. 
  • Sharp tack or sinter - multiply the thickest part by 2.5.

The end cooling rate for the appropriate thickness is a guide for the first ramp rate of your schedule.  For example, the final rate for an evenly thick piece 19mm/0.75” is 150ºC/270ºF.  This could be used as the rate for the first ramp. 

Bob Leatherbarrow has noted that most breaks occur below 260ºC/500ºF.  If there are multiple concerns, more caution can be used for the starting ramp rate.  My testing shows that using a rate of two thirds the final rate of cooling with a 20 minute soak is cautious.  In this example of a 19mm piece it would be 100ºC/180ºF per hour.

Even though for thinner pieces the rates given are much faster, be careful.  It is not advisable to raise the temperature faster than 330ºC/600ºF per hour to care for both the glass and the kiln shelf.

Once the soak at 260ºC//500ºF is finished, the ramp to the bubble squeeze should maintain the previous rate.  It should not be speeded up.  The glass is still in the brittle phase.

After the bubble squeeze you can use a ramp rate to the top temperature of up to 330C/600F.   AFAP rates to top temperature are not advisable.  It is difficult to maintain control of the overshoots in temperature that are created by rapid rates.  

The top temperature should be such as to achieve the result in 10 minutes to avoid problems that can occur with extended soaks at top temperature.

In the example of an evenly thick 19mm/0.75” piece a heat up full fuse schedule like this could be used:

  • 150ºC/270ºF to 566ºC/1052ºF for 0 minutes
  • 50C/90F to 643C/1191F for 30 minutes
  • 333ºC/600ºF to 804ºC/1479ºF for 10 minutes

 

If a more cautious approach to the heat up is desired, this might be the kind of schedule used:

 

  • 100ºC/180ºF to 260ºC/500ºF for 20 minutes
  • 100ºC/180ºF to 566ºC/1052ºF for 0 minutes
  • 50C/90F to 643ºC/1191ºF for 30 minutes
  • 333ºC/600ºF to 804ºC/1479ºF for 10 minutes

This approach is applicable to all fusing glasses.

 

Adapting the Bullseye Annealing Chart

After writing the first part of the schedule, you can continue to apply the annealing information from the Bullseye chart.  The first part of the anneal cooling starts with dropping the temperature as fast as possible to the annealing temperature.

The method for making the chart applicable to the annealing is a matter of substitution of temperatures.  

First, determine the annealing point of the glass.  Go to the web page of the glass manufacturer to get their annealing temperature.  You can use the information in this blog post giving some of the critical temperatures for a range of glasses.  This information has been taken from the manufacturers’ web sites as they are sometimes difficult to find.  A brief listing of some published annealing soak temperatures:

  • Bullseye                               482C/900F
  • Oceanside                            510C/960F
  • Uroboros by Youghiogheny     510C/960F
  • Old Uroboros                        519C/967F
  • Wissmach 96                        482C/900F
  • Youghiogheny96                    510C/960F
  • Float Glass
  • Pilkington Optiwhite               559C/1039F
  • Pilkington Optifloat                548C/1019F
  • USA float (typical)                 548C/1019F
  • Australian float (typical)         548C/1019F

Use the annealing temperature from your source as the target temperature in place of the Bullseye temperature.

The annealing soak times are important to equalise the temperature within the glass to an acceptable level (ΔT=5ºC).  The annealing soak time is related to the calculated thickness of the piece.  This measurement is done in the same way as devising the appropriate rate for heat up. 

Applying the Cooing Rates

Then apply the rates and temperatures as given in the chart.  The three stage cooling is important.  The gradually increasing rates keep the temperature differentials within acceptable bounds with the most rapid and safe rates.

The temperatures and rates remain the same for all soda lime glasses – the range of glass currently used in fusing, including float glass.  The soak time for the calculated thickness of your glass piece will be the same as in the Bullseye chart.  

This means that the first cooling stage will be to 427ºC/800ºF.  The second stage will be from 427ºC/800ºF to 371ºC/700˚F.  And the final stage will be from 371ºC/700˚F to room temperature.

I will repeat, because it is so important, that the thickness to be used for the anneal soak and cooling rates for your schedule relates to the profile you desire.  A fuse with even thickness across the whole piece can use the times, temperatures, and rates as given in the chart as adapted for your glass.  The thicknesses to use are for:

Contour fusing - multiply the thickest part by 1.5. 

Tack fusing - multiply the thickest part by 2. 

Sharp tack or sinter - multiply the thickest part by 2.5.

An annealing cool schedule for 19mm/0.75" Oceanside glass is like this:

  • AFAP to 510˚C/ 951˚F for 3:00 hours
  • 25˚C/45˚F to 427˚C/800˚F for 0 time
  • 45˚C/81˚F to 371˚C/700˚F for 0 time
  • 150˚C/270˚F to room temperature, off.


Many will wish to turn off the kiln as early as possible.  This is not part of best kilnforming practice.  If you still wish to do this, the turn off temperature must be related to the thickness and nature of the piece.  To turn off safely, you need to know the cooling characteristics of your kiln.  This can be determined by observing the temperature against time and then calculating the kiln’s natural cooling rateAnd then applying that information to cooling the kiln.

 

The best source for devising schedules is the Bullseye chart for Annealing Thick Slabs.  It is well researched and is applicable with little work to develop appropriate schedules for all the fusing glasses currently in use.

 

 




Wednesday 29 November 2023

Stuck Kiln Wash

 

Moulds

Kiln wash on ceramic moulds lasts a very long time. But sometimes you want to use a different separator. First you need to prepare yourself and the area for the process.

Preparation

It is best to wear a mask while removing kiln wash or other separators to reduce the amount of dust you inhale. Wearing an apron or other outer wear will keep the dust off your clothing.

Spread a cloth, newspaper or other covering around the area. This is to be able to easily gather the removed kiln wash and place it in the waste.  Have a vacuum sweeper at hand to remove powder rather than blowing it around the workspace.  Of course, if you can do this outside, there is much smaller risk of contamination.

Removal Methods

The method of removing kiln wash depends in part on what the mould material is.

Metal

You can sandblast, manually sand, or wash off the kiln wash from metal moulds.

Ceramic


Sandblasting is not a safe method for ceramics, as it is so easy to damage the surface of the mould. Removing the kiln wash while dry is a good first approach. It saves having to wait long times for air drying and long kiln drying of the damp mould. You can lightly sand off the kiln wash from smooth surfaced
moulds, and for detailed areas use rounded point wood and plastic tools. This can be backed up with a stiff nylon brush to clear out the narrow or detailed areas.

When these dry methods are insufficient, there are wet approaches. I recommend dampening the kiln wash rather than immersing the mould in water. The same tools can be used as for the dry removal.

Soaking or washing the mould does not remove the kiln wash as easily as you might think.  It is especially to be avoided where the mould has an internal hollow, as it may take days to dry sufficiently to apply other separators.  To put it in the kiln risks breaking the mould by the steam build up during the initial rise in temperature.

If you must soak the mould, I recommend that you use a 5% solution of citric acid because it has a chelating action on the kiln wash.

More information on removing kiln wash from moulds.

Remember that once the mould or shelf has been coated with boron nitride, it is almost impossible to go back to kiln wash again.  The boron nitride irreversibly fills the porous element of the ceramic, making it difficult for the kiln wash to adhere to the mould.

Shelves

The easiest surfaces to remove kiln wash from are flat or ones nearly so.

Dry Methods

Abrasive methods work well with a variety of tools. They can range from large paint scrapers to smaller ones with a Stanley blade inserted. 

 


Coarse open mesh plaster board (dry wall) sanding sheets are very useful. There are frames that you can fix them to, but sanding without the frame works well too.


Using power tools to sand the shelf is not advisable.  It is too easy to remove lots of material, including the surface of the shelf – even the hard, ceramic ones.  This leads to minor depressions in the shelf and consequent bubble difficulties when firing.

Do not be tempted to sandblast either, as that can easily create the small depressions in the surface of the shelf that subsequently lead to bubbles. 

Wet methods

Wet methods can be used if you are concerned about the dustiness of the process.  You can dampen the kiln wash on the shelf and sand or scrape as with the dry methods.  You will create a paste or slurry which can be bagged and put in the waste. You can also use the green scrubby washing up pads.  Unless you frequently rinse the pads, the kiln wash builds up and clogs the pads. making them ineffective.

 



Some people use vinegar or chemicals such as lime away with the water. The material that makes the kiln wash stick to the shelf is China clay and the separator is alumina hydrate. Both of these elements are almost impervious to the chemicals available to kiln workers. Instead, use citric acid. It has a chelating action which will incorporate the particles of the kiln wash. This will require some scrubbing, but avoids the smells of vinegar and the risks of other chemicals.

Do not be tempted to use pressure washers. Yes, they will remove the kiln wash. But it will also leave divots in the shelf which will cause later problems with bubble creation.

A big drawback to using wet methods, is that the shelf becomes wetted throughout and needs careful drying before use. 

Both the wet and dry methods can be used on smooth, gentle curved moulds. These include wave moulds, shallow moulds without flat bottoms, cylinder moulds, and such like.

More information on Kiln Wash Removal from shelves is available here,

and here.

Boron Nitride

A note on the reversibility of boron nitride. This is sold under a variety of trade names such as Zyp, More, MR97, etc., and sometimes under its chemical name.

Some people are applying boron nitride to ceramic moulds for the "smoother" surface.  Boron nitride is an excellent separator for metal moulds and casting moulds whether metal or ceramic. But it has limitations, including the price and the requirement for a new coating at each firing.  Some are beginning to wonder if they can go back to kiln wash after having used the boron nitride.

The general experience has been that you can't apply kiln wash on top of the boron nitride. It just beads up and flows off, because the boron nitride creates a non-wetting surface that survives relatively high temperatures. The kiln wash which is in water suspension has no opportunity to adhere to the mould.

The most accepted way to get rid of the boron nitride is by sandblasting. Sandblasting risks pitting the mould. Manual sanding seems to enable the ceramic mould to accept kiln wash. Perhaps enough of the surface is removed to reveal the porous nature of the ceramic mould. You do need to be cautious about taking the surface of the mould away when using abrasive removal methods. The ceramic is relatively soft in relation to the abrasive materials.

The difficulty of removing boron nitride from ceramic moulds means that you must think carefully about which moulds you coat with it.  If the mould has delicate or fine detail, removing the boron nitride risks the removal of the detail.  This indicates that this kind of mould, once coated, should not be taken back to the bare mould.

If you are using boron nitride to get a smoother surface to the object, consider using a lower slumping or draping temperature. This will minimise mould marks very effectively. And without the expense of boron nitride.

More information on removal of boron nitride is given here. 

More information about mould treatment is available in the ebook: Low Temperature Kiln Forming and at Bullseye ebooks

Wednesday 22 November 2023

Slumping Schedules


 When slumping fired pieces, it is most often appropriate to use a slow ramp rate to avoid too rapid expansion of the glass that might lead to a break. Most glass breaks on the ramp up are below 300°C/573°F. It is in this range that there is a rapid expansion of ceramic. This means a slow rate is protective for both glass and ceramic moulds.


Slumping Schedules by Profile (Celsius)

Flat Fuse and Contour Tack

Actual thickness

Ramp 1 rate to 260°C

Soak time (min)

Ramp 2 rate

Slumping  temp. for mould *

Soak time (min)

Anneal as for contour:

6

240

20

240

 

30

9mm

Rounded Tack

Actual thickness

Ramp 1 rate to 260°C

Soak time (min)

Ramp 2 rate

Slumping  temp. for mould *

Soak time (min)

Anneal as for round tack:

6

150

20

150

 

30

9mm

Sharp Tack

Actual thickness

Ramp 1 rate to 260°C

Soak time (min)

Ramp 2 rate

Slumping  temp. for mould *

Soak time (min)

Anneal as for sharp tack:

6

120

20

120

 

30

9mm

 

Slumping Schedules by Profile (Fahrenheit)

Flat Fuse and Contour Tack

Actual thickness

Ramp 1 rate to 500°F

Soak time (min)

Ramp 2 rate

Slumping  temp. for mould *

Soak time (min)

Anneal as for:

0.250”

432

20

540

 

30

0.375”

Rounded Tack

Actual thickness

Ramp 1 rate to 500°F

Soak time (min)

Ramp 2 rate

Slumping  temp. for mould *

Soak time (min)

Anneal for:

0.250”

270

20

270

 

30

0.375”

Sharp Tack

Actual thickness

Ramp 1 rate to 500°F

Soak time (min)

Ramp 2 rate

Slumping  temp. for mould *

Soak time (min)

Anneal for:

0.250”

216

20

216

 

30

0.375”

 

*Of course, the slumping temperature will be altered for the glass according to the manufacturer’s stated range. The nature of the mould will also have a big effect on temperature and time. The soak times at the slump soak are those appropriate for the mould. The annealing soaks are related to the profile of the glass.


Rates

It is most often best to use a slow ramp rate to at least 500°C/933°F. This avoids the risk of inducing a too rapid differential expansion within the glass as it heats up. Experiments relating to the first ramp rate have shown firing as for two layers thicker than indicated by the profile schedule provides the best results. It is then possible to increase the rate as determined by the profile schedule.

The rates for the anneal soak and cool are those that are one layer thicker than determined by the schedule for the profile. This has been shown by experimentation to give the best annealing result – i.e., least stress.

Temperatures

The slumping temperature needs to be altered for two factors:

  • ·        the glass according to the manufacturer’s stated range, and
  • ·        the nature of the mould.

Many manufacturers are giving recommended temperatures and times for slumping in their moulds. An example is the Bullseye “Quick Tip” which gives suggested temperatures and times for various sizes and natures of moulds that can form the basis for scheduling of slumps. The rates are normally for flat uniformly thick pieces. This will need alteration for tack profile pieces.

Take note of the soak time in these recommendations. If it is less than 10 minutes, it is possible to reduce the temperature by about 10°C/18°F by using a 30-minute soak. This will reduce marking on the back of the glass.

Soaks / Holds

Slumping schedules tend to be more difficult to devise than many other operations in kilnforming because of variations in moulds and what is placed on them. This, consequently, makes observation of the slump more important. It is needed from a point below the target temperature – say 20°C/36°F – to ensure the slump is stopped when it is complete.  If it is not complete, the soak can be extended. The controller manual will give the information on how to do these operations. In general, you schedule slower ramp rates for thicker pieces in combination with the half hour soak. This means for each thickness greater than 6mm, the top temperature can be reduced and still achieve a full slump.

The schedules here are applicable for pieces up to 9mm actual thickness.

Slumping of thicker pieces needs to apply the underlying scheduling method:

  • ·        Apply the rate for two layers thicker for the advance to 260°C/500°F.
  • ·        Increase the rate after that to one for a single layer thicker than calculated all the way up to the slumping temperature.
  • ·        For annealing, also select the rates and times for one layer thicker than indicated by the profile.

 

For example:

  • ·        Rounded Tack of Bullseye, 12mm/0.5” thickness
  • ·        Schedule for 25mm/1” (2 times multiplier)
  • ·        Initial ramp rate for 31mm/1.25” (two thickness greater)

Celsius schedule for up to 9mm actual thickness:

Segment >

1

2

3

4

5

6

7

Rate

150

150

ASAP

15

27

90

off

Temp

260

Top

482

427

370

RT

 

Time(mins)

20

30

240

0

0

0

 

and in Fahrenheit:

Segment >

1

2

3

4

5

6

7

Rate

270

270

ASAP

27

49

162

off

Temp

500

Top

900

800

700

RT

 

Time(mins)

20

30

240

0

0

0

 

 

A further example:

  • ·        Sharp Tack of Bullseye, 0.5” thickness
  • ·        Schedule for 31mm/1.25” (2.5 times multiplier)
  • ·        Initial ramp rate for 38mm/1.5” (two thickness greater)

 Celsius schedule for up to 9mm actual thickness:

Segment >

1

2

3

4

5

6

7

Rate

78

78

ASAP

11

20

65

off

Temp

260

Top

482

427

370

RT

 

Time(mins)

20

30

300

0

0

0

 

and in Fahrenheit:

Segment >

1

2

3

4

5

6

7

Rate

140

140

ASAP

20

36

117

off

Temp

500

Top

900

800

700

RT

 

Time(mins)

20

30

300

0

0

0

 

 

These examples show that considerable differences in scheduling are needed for different tack profiles. It also shows longer annealing soaks and slower cooling rates are required for sharp than rounded tack pieces.

 

More information is given in the e-Book Low Temperature Kilnforming. and at Bullseye eBooks