Showing posts with label kiln forming. Show all posts
Showing posts with label kiln forming. Show all posts

Sunday, 5 January 2025

CoE Varies with Temperature

Information from Bullseye shows that the Coefficient (average) of Linear Expansion changes rapidly around the annealing range.

The following is from results of a laboratory test of Bullseye clear (1101F)
Temperature range.......................COE
20C-300C (68F -­ 572F).................90.6
300C-400C (572F - ­752F).............102.9
400C-450C (752F - 842F).............107.5
570C-580C (1058F-1076F)............502.0

Bullseye glass is probably typical of soda lime glasses designed for fusing.

The change of CoE by temperature is further illustrated by Kugler (a blowing glass) who state their CoE by temperature range. Remember CoE is an average expansion over a stated range of temperatures)
CoE 93 for the range 0C-300C
CoE 96 for the range 20C - 300C
CoE 100 for the range 20C - 400C

The extension of the range by 100C beyond the brittle phase of glass has a distinct effect on the average expansion over the (larger) range. 

This shows why it is not helpful to refer to CoE without also mentioning the range of temperature.

In addition, here is an illustration of the effect. 




Image credit: Kerwin and Fenton, Pate de Verre and Kiln Casting of Glass,2000, p.32

It is understandable and common sense that as the temperature increases, so the rate of expansion increases and this applies to most solids.  Glass behaves differently as the graph above shows.  The change in expansion of Bullseye glass shows a relatively consistent average expansion until the strain point is reached.  Once out of the brittle phase, glass expansion rates change very much more rapidly.  It is not be coincidence that viscosity of glass changes at almost the same rates.  It is the viscosity that is controlling the CoE, not the other way around.   



Revised  5.1.25

Wednesday, 1 January 2025

Heat Work

“Heat work” is a term applied to help understand how the glass reacts to various ways of applying of heat to the glass. In its simple form, it is the amount of heat the glass has absorbed during the kiln forming heat-up process.

There is an relationship between how heat is applied and the temperature required to achieve the wanted result.  Heat can be put into the glass quickly, but to achieve the desired result, it will need a higher temperature. If you put the heat into the glass more slowly, the reverse applies.


For example, you may be able to achieve your desired result at 816C/1500F with a 400C/hr (720F/hr) rise and 10min soak. But you can also achieve the same result by using 790C/1454F with a 250C/hr (450F/hr) rise and 10min soak. The same amount of heat has gone into the glass, as evidenced by the same result, but with different schedules. This can be important with thick glass, or with slumps where you want the minimum of mould marks. Of course, you can achieve the same results with the a rise and a longer soak at the lower temperature, e.g. a 400C/hr
 (720F/hr) to 790C with a 30 min soak, but you will have more marking and difficulty with sticking separators.

In short, this means that heat work is a combination of time and temperature.  The same effect can be achieved with: 
- fast rates of advance and high temperatures.
- slow rates of advance and low temperatures.
- long soaks at low temperatures.

You obtain greater control over the processes when firing at slower rates with lower temperatures.  There is less marking of the back of the piece.  There is less sticking of the separators to the back and so less cleanup.  There is less needling with the lower temperature.  More information on heat work is here.

The adage “slow and low” comes from this concept of heat work. The best results come from lower temperature processing, rather than fast processing of the kiln forming.

More information is available in the eBook Low Temperature Kilnforming available from Bullseye and Etsy.


Revised 1.1.25

Monday, 30 December 2024

Slump Point Test


At a time when we are all going to be trying a variety of glass of unknown compositions to reduce costs of kiln working, the knowledge of how to determine the slump point temperature (normally called the softening point in the glass manufacturing circles) and the approximate annealing temperature becomes more important.  The slump point test can be used to determine both the slumping point and the annealing soak temperature.  This was required when the manufacturers did not publish the information, and it continues to be useful for untested glasses.

The method requires the suspension at a defined height of a strip of glass, the inclusion of an annealing test, and the interruption of the schedule to enter the calculated annealing soak temperature.

A strip of 3 mm transparent glass is required.  This does not mean that it has to be clear, but remember that dark glass absorbs heat differently from clear or lightly tinted glass. The CoE characteristics given are normally those of the clear glass for the fusing line concerned.  The strip should be 305 mm x 25 mm.  

Suspend the strip 25 mm above the shelf, leaving a span of 275 mm. This can be done with kiln brick cut to size, kiln furniture, or a stack of fibre paper.   Make sure you coat any kiln furniture with kiln wash to keep the glass from sticking.


The 305mm strip suspended 25mm above the shelf with kiln furniture.


Place some kiln furniture on top of the glass where it is suspended to keep the strip from sliding off the support at each end. Place a piece of wire under the centre of this span to make observation of the point that the glass touches down to the shelf easier.



The strip held down by placing kiln furniture on top of the glass, anchoring it in place while the glass slumps.

If you are testing bottles, you may find it more difficult to get such a long strip.  My suggestion is that you cut a bottle on a tile saw to give you a 25 mm strip through the length of the bottle.  Do not worry about the curves, extra thickness, etc.  Put the strip in the kiln and take it to about 740C to flatten it. Reduce the temperature to about 520C to soak there for 20 minutes.  Then turn the kiln off.  

Also add a two layer stack of the transparent glass near the suspended strip of glass to act as a check on whether the annealing soak temperature is correct. This stack should be of two pieces about 100 mm square. If you are testing bottles, a flattened side will provide about the same thickness.  This process provides a check on the annealing temperature you choose to use.  If the calculated temperature is correct there should be little if any stress showing in the fired piece.


The completed test set up with an annealing test and wire set at the midpoint of the suspended glass to help with determining when the glass touches down.


The schedule will need to be a bit of guess work.  The reasons for the suggested temperatures are given after this sample initial schedule which needs to be modified during the firing.
In Celsius
Ramp 1: 200C per hour to 500C, no soak
Ramp 2: 50C per hour to 720C, no soak
Ramp 3: 300C per hour to 815C or 835C, 10 minute soak
Ramp 4: 9999 to 520C, 30 minute soak
Ramp 5: 80C per hour to 370C, no soak
Ramp 6: off.

In Fahrenheit
Ramp 1: 360F per hour to 932F, no soak
Ramp 2: 90F per hour to 1328F, no soak
Ramp 3: 540F per hour to 1500F or 1535FC, 10 minute soak
Ramp 4: 9999 to 968F, 30 minute soak
Ramp 5: 144F per hour to 700F, no soak
Ramp 6: off.

Fire at the moderate rate initially,
and then at 50C/90Fper hour until the strip touches down. This is to be able to accurately record the touch down temperature.  If you fire quickly, the glass temperature will be much less than the air temperature that the pyrometer measures.  Firing slowly allows the glass to be nearly the same temperature as the air.  

Observe the progress of the firing frequently from 500C/932F onward.  If it is float or bottle glass you are testing you can start observing from about 580C. Record the temperature when the middle of the glass strip touches the shelf. The wire at the centre of the span will help you determine when the glass touches down.  This touch down temperature is the slump point of your glass.  You now know the temperature to use for gentle slumps with a half hour soak.  More angular slumps will require a higher temperature or much more time.


Once you have recorded the slump point temperature, you can skip to the next ramp (the fast ramp 3).  This is to proceed to a full fuse for soda lime glasses. Going beyond tack fusing temperatures is advisable, as tack fuses are much more difficult to anneal and so may give an inaccurate assessment of the annealing. Most glasses, except float, bottles and borosillicate will be fully fused by 815C. If it is float, bottles or borosilicate that you are testing, try 835C. If it is a lead bearing glass, lower temperatures than the soda lime glass should be used. In all these cases observation at the top temperature will tell you if you have reached the full fuse temperature. If not add more time or more heat to get the degree of fuse desired.

While the kiln is heating toward the top temperature you can do the arithmetic to determine the annealing point.  To do this, subtract 40C/72F from the recorded touch down temperature to obtain an approximate upper annealing point.  The annealing point will be 33C/60F below the upper point.  This is approximate as the touch down temperature is, by the nature of the observation. approximate.  

The next operation is to set this as the annealing soak temperature in the controller. This will be the point at which it usually possible to interrupt the schedule and change the temperature for the annealing soak that you guessed at previously. Sometimes though, you need to turn the controller off and reset the new program.  Most times the numbers from the last firing are retained, so that all you need to do is to change the annealing soak temperature.


The annealing soak should be for 60 minutes to ensure an adequate anneal. This may be excessive for 3 mm glass, but as the anneal test is for 6 mm, the longer soak is advisable. The annealing cool should be 83C/hr down to 370C. This is a moderate rate which will help to ensure the annealing is done properly. The kiln can be turned off at that temperature, as the cooling of the kiln will be slow enough to avoid any thermal shock to the annealing test piece.

When cooled, check the stack for stress. This is done by using two polarised light filters. See here for the method. 


Squares of glass showing different levels of stress from virtually none to severe
 (no light emanating for no stress to strong light from the corners indicating a high degree of stress.)


If the anneal test piece is stressed, there could be a number of reasons for the inadequate annealing. It could be that the glass has devitrified so much that it is not possible to fuse this glass at all. If you also test the suspended strip for stresses and there is very little or none, it is evidence that you can kiln form single layers of this glass. You now know the slumping temperature and a suitable annealing temperature and soak for it, even though fusing this glass is not going to be successful.

Other reasons for stress due to inadequate annealing could be that the observations or calculations were incorrect.  

  • Of course, before doing any other work, you should check your arithmetic to ensure the calculations have been done correctly. I'm sure you did, but it is necessary to check.  If they are not accurate, all the following work will be fruitless.
  • The observation of the touch down of the suspended strip can vary by quite a bit - maybe up to 15C.  To check this, you can put other annealing test pieces in the kiln.  This will require multiple firings using temperatures in a range from 10C/18F above to 10C/18F below your calculated annealing soak temperature to find an appropriate annealing soak temperature.
  • If stress is still showing in the test pieces after all these tests, you can conduct a slump point test on a strip of glass for which there are known properties. This will show you the look of the glass that has just reached touch down point as you know it will happen at 73C above the published annealing point.  You can then apply this experience to a new observation of the test glass. 

Revised 30.12.24

Friday, 27 December 2024

Characteristics of Some Glasses

This information has been taken from various sources. Some manufacturers may change the composition of their glasses or the published information about them from time to time. Therefore, this information can only be used as a guide. If the information about strain, annealing, and softening points is important, contact the manufacturer for the most accurate information.

The temperature information is given in Celsius.
Strain point – the temperature below which no annealing can be done.
Annealing point – the temperature at which the equalisation soak should be done before the annealing cool.
Softening point – the temperature at which slumping can most quickly occur.


Armstrong – Now made by Kokomo

Typical Borosilicate – nominal CoE 32
Strain point – 510 - 535C / 951 - 996F
Annealing point – ca. 560C/1041F
Softening point - ca. 820C/1509F

Blackwood OZ Lead – nominal CoE 92
Annealing point - 440C/825F

Blenko – nominal CoE 110
Annealing point – 495C/924F

Bullseye – nominal CoE 90

Transparents
Strain point - 493C/920F
Annealing point - (532C)  Note that Bullseye has changed this to 482C/900F for thick items
Softening point - 677C/1252F

Opalescents
Strain point - 463C/866F
Annealing point – (501C)  Note that Bullseye has changed this to 482C900F for thick items
Softening point - 688C/1272F

Gold Bearing
Strain point - 438C/821F
Annealing point - (472)   Note that Bullseye has changed this to 482C/900F for thick items
Softening point - 638C/1182F

Chicago – nominal CoE 92

Desag  Note that this glass is no longer produced
Artista – nominal CoE 94
Strain point – 480 - 510C / 897 - 951F
Annealing point – 515 - 535C / 960 - 996F
Softening point – 705 – 735C / 1302 - 1356F
Fusing range – 805 – 835C / 1482 - 1537

Float Glass (Pilkington UK)
Optiwhite
Strain point – 525 - 530C / 978 - 987F
Annealing point – 559C/1039F
Softening point – 725C/1338F

Optifloat
Strain point – 525 - 530C / 978 - 987F
Annealing point – 548C/1019F
Softening point – 725C/1338F

Float Glass (typical for USA) nominal CoE 83
Strain point - 511C/953F
Annealing point - 548C/1019F
Softening point – 715C/1320F

Float Glass (typical for Australia) nominal CoE 84
Strain point - 505-525C / 942 - 978F 
Annealing point – 540 -560C / 1005 - 1041F

HiGlass “GIN” range – nominal CoE 90
Annealing point - 535C/996F

Gaffer colour rod – nominal CoE 88

Gaffer NZ Lead – nominal CoE 92
Annealing point - 440C/825F

HiGlass
Annealing point - 495C/924F

Kokomo – nominal CoE 92 - 94

Cathedrals
Strain point - 467C/873F
Annealing point - 507C/946F
Softening point - ca. 565C/ca.1050F

Opal Dense
Strain point - 445C/834F
Annealing point - 477C/891F
Softening point – ca. 565C/1050F

Opal Medium
Strain point - 455C/834F
Annealing point - 490C/915F
Softening point – ca.565C/1050F

Opal Medium Light
Strain point - 461C/863F
Annealing point - 499C/931F
Softening point – ca.565C/1050F

Opal Light
Strain point - 464C868F
Annealing point - 502C/937F
Softening point – ca.565C/1050F

Kugler 
Clear – nominal CoE 96 +/- 2  (94-98)
softening point: - 694C/1281F
Annealing point: - 508C/946F
Strain point: - 485C/904F

Colours - nominal CoE 96 +/- 4 (92-100)
Annealing point: - 500C/932F
Strain point: - 460C-500C/860 -879F

Typical lead glass – nominal CoE 91

Lenox Lead – nominal CoE 94
Annealing point – 440C/825F

Merry Go Round – nominal CoE 92

Moretti/Effetre – nominal CoE 104
Strain Point: 448C/839F
Annealing Range: 493C – 498C / 920F - 929F
Softening Point: 565C/1050F

Pemco Pb83 – nominal CoE 108
Annealing point – 415C/780F

Reichenbach - 

nominal CoE 96 +/-2 (94 -98)

Annealing range; - 470C-530F/878F-986F; Ave 510C/950F

nominal CoE 104  no further information at present.



Schott Borosilicate (8330) nominal CoE 32
Annealing point - 530C/987F

Schott “F2” Lead – nominal CoE 92
Annealing point - 440C/825F

Schott “H” & “R6” rods - nominal CoE 90
Annealing point – 530C/987F

Schott “W” colour rod – nominal CoE 98

St Just
MNA
Strain point - ca.450C/843F
Annealing point – ca. 532C/ca. 991F

Spectrum
System 96 – nominal CoE 96
Transparents
Strain point – 476C  +/- 6C  /  890F +/- 11F
Annealing point – 513 +/- 6C  /  956C +/- 11F
Softening point – 680 +/- 6C  /  1257F +/- 11F
Opalescents
Annealing point – 505 -515C  /  942 - 960F

Spruce Pine 87 – nominal CoE 96
Annealing point – 480C/897F

Uroboros system 96 – nominal CoE 96

Transparents
Strain point - 481C/899F
Annealing point - 517C/964F

Opalescents
Strain point - 457C/855F
Annealing point - 501C/935F

Uroboros - nominal CoE 90

Transparents
Strain point - 488C/911F
Annealing point - 525C/978F

Opalescents
Strain point - 468C/875F
Annealing point - 512C/955C

Wasser - nominal CoE 89
Annealing point – 490C/915F

Wissmach
Wissmach 90
Annealing point - 483C/900F
Softening point - 688C/1272F
Full Fuse - 777+

Wissmach 96
Annealing point - 
483C/900F
Softening point - 688C/1272F

Full Fuse - 777+ / 1432+


Monday, 23 December 2024

CoE as the Determinant of Temperature Characteristics

Credit:: Ryan Rutherford



Many people are under the impression that CoE can tell you a wide number of things about fusing glass. 

What does CoE really mean?

The first thing to note is the meaning of CoE.  Its proper name is the coefficient of linear expansion.  It tells you nothing certain about the expansion in volume, which can be as or more important than the horizontal expansion. 

It is an average determined between 20°C and 300°C.  This is fine for materials that have a crystalline structure. Glass does not.  Glass behaves quite differently at higher temperatures. 

It may have an average expansion of 96 from 20°C-300°C – although there is no information on the variation within that range – but may have an expansion of 500 just above the annealing point. 

The critical temperatures for glass are between the annealing and strain points.  One curious aspect to the expansion of glass is that the rate of expansion decreases around the annealing point.  The amount of this change is variable from one glass composition to another.

credit: ScienceDirect


The CoE of a manufacturer’s glass is an average of the range which is produced.  Spectrum has stated that their CoE of their fusing compatible glass is a 10 point range.  Bullseye has indicated that their CoE range is up to 5 points. These kind of ranges can be expected in every manufacturer’s compatible glass.

CoE does not tell us anything about viscosity, which has a bigger influence on compatibility than CoE alone. 

Comparison of CoE and Temperature

Among the things people assume CoE determines is the critical temperatures of the strain, annealing and softening points of various glasses.

Unfortunately, CoE does not necessarily tell you fusing or annealing temperatures. 

“CoE 83”
Most float glass is assumed to be around CoE 83.  The characteristics depend on which company is making the glass and where it is being made.  These are the annealing points and softening points:

Pilkington Optiwhite              559ºC/1039ºF    720°C/1328°F

Pilkington Optifloat               548ºC/1019ºF    720°C/1328°F

USA float (typical)                548ºC/1019ºF    615°C/1139


Typical Australian float has a CoE of 84 and anneals in the range 505°C -525°C/941°F - 977°F.

“CoE 90”
Uroboros FX90 has an annealing point of 525°C compared to Bullseye at 482°C, and Wissmach 90 anneal of 510°C. 

Wissmach 90 has a full fuse temperature of 777°C compared to Bullseye's 804 - 816°C.   

There is a float glass with a CoE of 90 that anneals at 540°C and fuses at 835°C.

Bullseye has a slump temperature of 630°C-677°C and Wissmach’s 90 slumps between 649°C and 677°C, slightly higher.


“CoE 93”
Kokomo with an average CoE of 93 has an annealing range of 507°C to 477°C. Kokomo slumps around 565°C


“CoE 94”
Artista with a CoE of 94 has an annealing point of 535°C and a full
fuse of 835°C, almost the same as float with a Coe of 83. 


“CoE96”
Wissmach 96 anneals at 482°C with a full fuse of 777°C and a slump temperature of 688°C.
Spectrum96 and its successor Oceanside Compatible anneals at 510°C and full fuses at 796°C.


Conclusion


In short, CoE does not tell you the temperature characteristics of the glass. These are determined by several factors of which viscosity is the most important. More information can be gained from this post or from your own testing and observation as noted in this post.

Revised 23.12.24

Wednesday, 27 March 2024

Kilnforming Opalescent Stained Glass


The statement that a sheet of glass can be fused to itself is true in certain circumstances.  It applies to transparent and some streaky glasses best.  These forms of glass are more likely to fuse together successfully although not formulated for fusing.

Transparent and Streaky Glasses

Of course, the best practice is to test for compatibility.  I found in my early days of sticking stained glass together that it was beneficial to test. In doing so, I found Spectrum and Armstrong transparent and streaky glass to be largely consistent across many sheets.  I did not have access to much Kokomo or Wissmach.  I cannot comment on how their glass behaves in terms of compatibility across the production range.  Not all transparent and streaky glass remains stable at fusing temperatures. There are some glasses that opalise, some change colour, some devitrify. This variability makes compatibility testing important - even for the transparent form of stained glass.

Photo credit: Lead and Light


Wispy Glasses

The statement about fusing to itself is less applicable to wispy glass.  Not all the wispy stained glass from the same sheet can be fused.  It seems to be dependent on the amount of opalescence in any one area of the glass.  I found that it is possible - if you are very careful - to fuse certain Spectrum wispies with the clear fusing standard on top, but not on the bottom.  This should be applicable to other manufacturers’ wispy glass too.  There must be a marginal compatibility that is contained by the clear fusing glass on top, but I am not certain.

Photo credit: Lead and Light

Opalescent Glasses

The statement about fusing to itself is almost completely inapplicable to opalescent glass.  Stained glass opalescent glass does not have the compatibility requirements of fusing glasses.  They very often severely devitrify when taken to fusing temperatures.  This devitrification means that opalescent stained glass is often not compatible with itself.  So, no amount of twiddling with schedules will make stained glass opalescent glass fusible, even with itself.

Manufacturers have spent a lot of time and effort to produce fusing compatible opalescent glass.  It is as though there is a minor element of devitrification embodied in the opalising process.  Whether this is so, it becomes very apparent on doing compatibility testing that opalescent stained glass has severe devitrification at fusing temperatures.


Stock photo


Compatibility Testing

It is important to test for compatibility before committing to the main firing.  Some transparent and streaky glass changes colour, devitrifies, and some opalise at fusing temperatures. This applies with even more force to wispies.  They contain a significant proportion of opalescence within them.  Some opalescents are so unstable at fusing temperatures that the devitrification becomes so bad the glass crumbles.

The importance of testing pieces of the sheet for compatibility before committing to a firing is reinforced by these factors.

Slumping

Slumping temperatures are not so high as fusing, and it is often stated that single layers can be slumped.  Again, it is not always true.

Some glasses change colour at slumping temperatures.  A few opalise. It is not always certain what effect moderate temperatures will have on stained glass.  The compatibility testing will show.  Observe the test firing at slumping temperatures.  Also, you will learn if there are changes at moderate temperatures.

One element must be commented upon about slumping.  It is important to have the edges finished to the appearance that you want the final piece to have.  The regularity of the edges without bumps or divots, and the degree of polish need to be showing before the firing starts.  The slumping temperatures are not high enough to alter the shape or appearance of the edges.


Firing of stained glass to itself is normally a low risk activity, but with unpredictable results.  It can teach a lot about behaviour of glass at higher temperatures.  Slumping single layer pieces can give information about the way single layers of glass slump or drape.  But testing is important for fusing.  And can inform about how the glass will react at slumping temperatures too.

Saturday, 6 May 2023

Re-firing


A frequently asked question is “how many times can I re-fire my piece?”
This is difficult to answer as it relates to the kind of glass and the firing conditions.

Kind of glass

Float glass is prone to devitrification. This often begins to appear on the second firing. Some times it may be possible to get a second firing without it showing. Sandblasting the surface after getting devitrification will enable another firing at least.
Art glass is so variable that each piece needs to be tested.
Fusing glasses are formulated for at least two firings, and experience shows may be fired many of times. The number will depend on the colours and whether they are opalescent. Transparent colours on the cool side of the spectrum seem to accept more firings than the hot colours. Both of these accept more firings than opalescent glasses do.
Firing conditions

Temperature

The higher the temperature pieces are fired at, the fewer re-firings are possible. So if multiple firings are planned, you should do each firing at the lowest possible temperature to get your result. This may mean that you have relatively long soaks for each firing. The final firing can be the one where the temperature is taken to the highest point.
Annealing
You do have to be careful about the annealing of pieces which have been fired multiple times. A number of people recommend longer annealing soaks. However, I find that the standard anneal soak for the thickness is enough. What is required is cooling rates directly related to the anneal soak.  This is a three-stage cooling as described in the Bullseye chart Annealing Thick Slabs.  The slump firing can be annealed at  the standard. 

Slumping

In general, slumping is at a low enough temperature to avoid any creation of additional stress through glass changes at its plastic temperatures.  But any time you heat the glass to a temperature above the annealing point, you must anneal again at least as slowly as in the previous firing. Any thing faster puts the piece at risk of inadequate annealing.  Of course, having put all this work and kiln time into the piece, the safest is to use the cooling rate as for a piece one layer thicker.  My research has shown that this gives the least evidence of stress.

Testing

Testing for stress after each firing will be necessary to determine if there is an increase in the stress within the piece. In the early stages of multiple firings, you can slow the annealing and if that shows reduced stress, it will determine your previous annealing schedule was inadequate. When reducing the rate of annealing does not reduce the stress, it is time to stop firing this piece at fusing temperatures.
Revised 6 May 2023

Wednesday, 15 September 2021

Digest of Principles for kiln forming

Some time ago people on a Facebook group were asked to give their top tips for kiln forming.  Looking through them showed a lot of detailed suggestions, but nothing which indicated that understanding the principles of fusing would be of high importance.  This digest is an attempt to remind people of the principles of kiln forming.

Understanding the principles and concepts of kilnforming assists with thinking about how to achieve your vision of the piece.  It helps with thinking about why failures have occurred.

Physical properties affecting kiln work

Heat
Heat is not just temperature. It includes time and speed.

 Time
       The time it takes to get to working temperatures is important.  The length of soaks is significant in producing the desired results.

 Gravity
       Gravity affects all kiln work.  The glass will move toward the lowest points, requiring level surfaces, and works to form glass to moulds.

 Viscosity
       Viscosity works toward an equilibrium thickness of glass. It varies according to temperature.

 Expansion
       As with all materials, glass changes dimensions with the input of heat.  Different compositions of glass expand at different rates from one another, and with increases in temperature.

       Glass is constantly tending toward crystallisation. Kiln working attempts to maintain the amorphous nature of the molecules.

 Glass Properties
·        Glass is mechanically strong,
·        it is hard, but partially elastic,
·        resistant to chemicals and corrosion,
·        it is resistant to thermal shock except within defined limits,
·        it absorbs and retains heat,
·        has well recognised optical properties, and
·        it is an electrical insulator. 

These properties can be used to our favour when kiln working, although they are often seen as limitations.

Concepts of Kiln Forming
Heat work
       Heat woris a combination of temperature and the time taken to reach the temperature.

 Volume control
       The viscosity of glass at fusing temperatures tends to equalise the glass thickness at 6-7mm. 

 Compatibility
       Balancing the major forces of expansion and viscosity creates glass which will combine with colours in its range without significant stress in the cooled piece.

 Annealing
       Annealing is the process of relieving the stresses within the glass to maintain an amorphous solid which has the characteristics we associate with glass.

 Degree of forming
       The degree of forming is determined by viscosity, heat work and gravity.  These determine the common levels of sintering, tack, contour, and full fusing, as well as casting and melting.

 Separators
       Once glass reaches its softening point, it sticks to almost everything.  Separators between glass and supporting surfaces are required.

 Supporting materials
       These are of a wide variety and often called kiln furniture.  They include posts, dams, moulds, and other materials to shape the glass during kilnforming.

 Inclusions
       Inclusions are non-glass materials that can be encased within the glass without causing excessive stress.  They can be organic, metallic or mineral. They are most often successful when thin, soft or flexible.

A full description of these principles can be found in the publication Principles for Kilnforming