Friday, 21 February 2025
Element Coatings
Wednesday, 19 February 2025
Time and Temperature
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credit: timeanddate.com |
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Credit: Shutterstock |
“What are the pros and cons on turning up the max temperature slightly Vs. a longer hold time”? Lea Madsen
This is a difficult question
to answer, because there are variables such as
the temperature range,
the ramp rates, and soaks,
the forces acting upon the glass at a given temperature,
the process,
the desired outcome of the firing,
etc.
When talking about temperature vs. time, it is heat work
that we are considering. In many processes
time and temperature are interchangeable, although the temperature range is
important too. This is a brief
discussion of heat work in various processes.
Slumps
Slumping
temperature is generally in the range of 620˚C-680˚C/1150˚F -1255˚F *, which is
below the devitrification range. This
allows the exchange of time for temperature without risk, allowing more time
rather than more temperature. Higher temperatures cause more marking from
the mould since the bottom of the glass is softer than at lower ones. Lower temperatures give higher viscosity, so
the glass is stiffer, resisting marks.
Low temperature fuses
Sharp tack fusing, freeze and fuse, some pate de verre
processes, and sintering occur in the 650˚C
-720˚C /1150˚F - 1320˚F range, risking devitrification only at the upper end of this
range. Extending the time rather than
the temperature is important to maintain detail in these processes. Higher temperatures will smooth the surface, risking
loss of detail.
Rounded tack processes (720˚C – 760˚C /1320˚F - 1400˚F)
These are within the devitrification range making the
choice between time and temperature a balance of risks. In my experience, it takes about an hour for
visible devitrification to develop. This
means that you can extend the time, if the total time between the end of the bubble
squeeze and the working temperature, including the hold time, is less than an
hour. It has the advantage of a more
secure attachment between the pieces of glass, without altering the surface
much.
But if extending the soak time increases the time in the
devitrification zone to be more than an hour, it is advisable to increase the
temperature, rather than time. Devitrification
develops in the presence of air, so reducing the time in that range reduces the
risk of devitrification developing. The
glass is moving during rapid ramp rates, reducing the chance of devitrification.
Drops
This includes drapes, and other free forming processes. Kilnformers will be observing the progress of
these firings, making it easier to balance temperature and time. There are already long holds scheduled for
the processes, so it is a matter of getting the right temperature. If, after half an hour at the scheduled top
temperature, the glass has not moved much, it is time to increase the
temperature by, say 10˚C/18˚F and observe after another half hour, repeating the temperature increase if
necessary. Be aware of thinning the
glass at the shoulder by setting a high temperature. Free drops may take as much as 6 – 8 hours,
so patience and observation are important to get good results.
Full fuse
At full fuse try to
get the work done in 10 minutes to avoid complications with
devitrification. So, increasing the
temperature rather than the length of the soak seems best.
Flows
Whether frit stretching, making pattern bars, pressing, etc.,
low viscosity is important. Viscosity is
closely related to temperature, so increasing the temperature is the better
choice. Increasing time without
increasing temperature does not change viscosity much.
Casting
Extending time at top temperature seems
best for open face casting, as the temperature is already high. A slow ramp rate to that top temperature may make
adding time unnecessary, because the heat work will be increased by the slow
rise. Experience has shown that a rate
of 200˚C/360˚F is enough to avoid devitrification. With enclosed castings devitrification is not
such a risk, so time can be added without concern.
Observation
In all these processes it is advisable to observe
the progress of the firing by quick peeks to determine the effective
combination of temperature and time.
Also note that heat work is
cumulative, making for changes in profile with repeated
firings.
* The softening point of float glass is around 720°C/1328°F, so
the slumping range is about 700°C/1292° to
750°C/1382°F.
Wednesday, 12 February 2025
Refractory Fibre on Top of Glass
“I've made this stencil out of rigidized SilkeMat. Can I fill it with powder and/or frit and leave the stencil on the glass when I fire it to a full fuse?“
SilkeMat is thicker,
with greater insulating properties than shelf paper. The base glass will be
insulated in two ways. The frit in the spaces of the stencil will insulate the
heat from reaching the base under it. The SilkeMat will have even greater
insulating effect on the glass it covers. So, the proposed layup would create
three heat areas on the base layer - the area insulated by the SilkeMat, the
portion under the frit, and the uncovered areas. These three heat areas are a
big problem for the glass to cope with, as they each will heat differently.
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An illustration of cutting holes in SilkeMat to form a stencil with thick edges Credit: Katie Chapman (not the origin of the question) |
At full fuse the SilkeMat
or any other refractory fibre blanket will mark the glass and may stick in
parts. Adding weight will only increase
the marking and sticking, as well as further insulate the covered area. The most important problem with
leaving refractory papers on top of the glass during a full fuse, is the
insulating property of SilkeMat or any other refractory fibre paper, creating
large temperature differentials, which require extremely slow heat ups, long
anneal soaks, and very slow cooling. If it were to be fired with refractory fibre paper on
top, in spite of these warnings, I would fire it as though two inches thick.
A much better approach is to make a
card stencil that is stiff enough to lift easily without spilling any excess
powder as it is removed. Apply multiple
thin layers of powder, firing between each application. Careful application and firing to a low
temperature tack fuse each time will give a crisp edge to the powdered
image. This can be glossed with a full
fuse firing after the last application.
A silicone rubber colour pusher or stiff
brush can move the powder, either to the powder image or away and off the base
to give a crisp edge to the image.
If you have not already built the
piece in the kiln, powder and frit are heavy enough that they will not be
disturbed easily on the way to the kiln. An aerosol adhesive that drifts down onto the
powder will be enough to hold it in place if concerned about movement.
But best of all, is to create a powder wafer where the thickness and crispness of the image can be controlled, and then placing it onto the base glass. This avoids the risks of temperature differentials being created by the refractory paper
Monday, 10 February 2025
Reversibility of Boron Nitride
After using Zyp/MR97, can I sand it off and use kiln wash?
The most accepted way to get rid of the boron nitride is by sandblasting. Then apply kiln wash as normal. The sandblasted ceramic mould previously coated accepts kiln wash with no difficulty. In the absence of a sandblaster, you can use a sanding pad. You do need to be cautious about taking the surface of the mould when using abrasive removal methods, as the ceramic is relatively soft in relation to the abrasive materials.
However, boron nitride is soluble in various alkaline chemicals, such as potassium hydroxide (caustic potash), sodium hydroxide (caustic soda or lye), and sodium nitrate (Chile saltpeter). Soaking or washing the surface with one of these will dissolve the boron nitride, and should return a surface that will accept kiln wash. Be cautious in the use of these chemicals as they are dangerous to the skin.
Another use of boron nitride is to spray a very small amount on a fiber strip to be used for damming. This will give you fewer needles as it provides a non-wetting surface at relatively high temperatures. This allows the glass to slide down the fibre paper without hanging up and creating the needles.
One advantage of kiln wash over boron nitride is that you do not have to reapply every firing as with boron nitride. With the boron nitride it is recommended to apply before every firing. It is best to use a paint brush to dispose of any lose material before giving a light re-coating. Not a whole lot is required on subsequent coatings.
If you are using boron nitride to get a smoother surface to the object, also consider using a lower slumping or draping temperature, as this will also minimise mould marks.
Friday, 7 February 2025
Cutting thin strips
Another method is to use the edge of the bench or work board as a guide. With a small adjustable carpenter’s square, you hammer in nails at the predetermined width (plus half the thickness of the cutter head). Align the glass to the edge of the bench between the nails. Place a straight edge against the nails and score. This gives strips of the same width every time, but works best with strips of 10mm (3/8”) or more. This is illustrated in the processes section.
The thinner the strips are to be cut, the more important it is to make the scores and then divide the sheet in half - the two halves in half each - the 4 quarters in to halves, etc, until you are down to the piece that only needs to be divided in two.
The thinnest strip that can be cut is a fraction wider than the thickness of the glass. This is because the glass will always break toward the weakest area. If the strip is thinner than the glass is thick, it will break within the strip. The narrowest strip that can practically be cut is at least one or two millimetre wider than the glass is thick. So, if you have 3mm glass, the narrowest you can cut is 4 or 5 mm. Four millimetre wide strips can only be cut from really smooth consistent thickness of glass sheets. It is much more practical with decorative glass to limit the width to twice the thickness of the glass you are cutting.
Cutting from Cartoon
Although the glass is normally only three millimetres thick, there is some possibility of a refraction of the light if you look from the side of the cutter. As described elsewhere, you should be holding your cutter upright in the left to right plane and angled slightly back toward you so that you can look with your dominant eye along the barrel of the cutter and head. This ensures you are directly above the cut line and do not have any refraction caused by the glass.
Diagnosis of Cutting
Adjusting Cut Runners
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The apparently most popular is this:
Cushions
Use without covers
Setting the spacing
The principles
Thicker glass
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One example of cut runners for thick glass. There are a variety of others. |
Lead Corrosion
Tapping Glass Scores
- Move the score line to the edge of the bench or cutting surface and use a controlled downward force on the glass off the edge while holding the remainder firm. Works best if at least a third is being broken off.
- You can place a small object, such as the end of your cutter or a match stick, directly under the score and place your hands on either side and press firmly, but not sharply, down on each side at the same time. This is good for breaking pieces off from half to a quarter of the full sheet.
- Make your hands into fists with the thumbs on top of the glass and the fingers below. Turn your wrists outwards to run the score. Works best if the glass is approximately half to be kept and half to be broken off.
- Take the glass off the cutting surface, hold in front of your knee at about 45 degrees and raise you knee quickly to the glass. This will break the glass cleanly, but is only useful for moderate sized sheets and where you are breaking off about half of the sheet.
- Use
cut running pliers to run the score. Be
sure the jaws are adjusted for the thickness of the glass, and do not apply
excessive pressure. If the score does
not run all the way, turn the glass around and run the score from the opposite
end. Best where there are approximately equal thin parts to be broken away from
each other and when the score line is no less than an oblique angle to the
edge. It does not work very well for thin pieces or acute angles.
- Use two grozing pliers nose to nose and flat side up at the score line and bend them down and away. This works best on thin and or pointed pieces.
- Breaking pliers can be used at intervals along the score. This is most useful on long thin pieces.
- Gentle curves can be dealt with as though they are straight lines, although the breaking at the edge of the cutting surface is a bit risky. This means the two-fist, running pliers, two grozing pliers and breaking plier methods can be used.
- Lines with multiple curves usually require cut running pliers to start the run at each end of the score.
- Deep curved scores may require the running pliers whose angle can be adjusted to be at right angles to the score. The ones I know are Silberschnitt, made by Bohle, although the ring pliers by Glastar work in the same way. This usually requires that the edge of the glass is not more than 5 cm from the score. This blog gives information on a variety of cut running pliers.
- Taps that are either side of the line will either not be effective, or will promote breakage other than along the score line.
- Tapping to either side of the score also promotes shells to either side of the score line. These are not only dangerous when handling, but also require further work to remove these ledges of glass.
- The taps need to be firm – neither light nor hard.
- Each tap should be at the end of the run begun by the previous one. This promotes a smoother run of the score with less opportunity to start a run off the score line.
- To avoid the incomplete running of the score that leaves parts of the score untouched you need care. As the glass begins to break along the score line, place the next impact at the end of that start to continue the run.