Although
glasses are often valued for their chemical inertness, this property
also presents challenges when attempting to form strong chemical
bonds with other materials. Silanes and polymer coatings offer
effective solutions by enhancing the bond between a glass and other
materials in a composite.
The
Challenge
The
challenge of bonding glass to polymers spans across several
industries, including industrial, automotive, and healthcare. In
biomaterial applications, polymer carriers are often used to deliver
glass or ceramic particles to specific treatment sites.
However, bioactive
glasses,
commonly used in treatment delivery and bone regeneration, face a
similar issue: the mismatch in critical surface tension and adhesion
properties between the materials in the composite.1 This
mismatch is primarily driven by differences in hydrophobicity and
hydrophilicity, making it difficult to create strong, stable bonds.
The
key question, then, is how to improve and strengthen the bonds
between glass and polymer materials to create stable composites that
benefit from the properties of both material types.
The
Solution
Fortunately,
there are several approaches to improving the bonding characteristics
of glass. One such solution is the use of silane or polymer materials
as adhesive treatments. These materials help bypass the challenges of
forming direct chemical bonds between the surface oxide groups on the
glass and the substrate of interest.
Silanes
Silanes
are particularly effective in improving the bonding between glass and
other materials due to their ability to form highly stable siloxane
bonds. These strong covalent bonds enhance the compatibility between
glass and various organic or inorganic surfaces, creating a stronger
interface than unmodified glass. Silanes are an excellent choice for
composites, retaining the properties of glass while significantly
improving surface chemistry and wettability.
One
challenge in forming glass-bonded materials is the introduction of a
new surface type, which can create potential regions of weakness and
shear. Silanes act as effective coupling agents by forming strong
covalent bonds with both the glass and the substrate, reducing these
weak points and enhancing the overall stability and durability of the
material.2
While
physical abrasion and etching with hydrofluoric acid can improve
adhesion by roughening the surface, chemical modification using
silanes is often preferable. Chemical bonds offer superior grafting
properties compared to physical methods, resulting in stronger, more
durable connections between glass and other substrates.
Polymers
Polymer
materials are widely used for bonding to glass due to their
flexibility, which is highly advantageous in adhesive applications.
While silicone-based materials can bond to glass, they are generally
not as strong as many polymer adhesive options.
One
such polymer adhesive, polyurethane, is a popular choice for bonding
glass in various industries. This popularity is due to its
flexibility, which helps absorb and mitigate vibrations induced by
movement, enhancing the durability and integrity of the bonded
structure. Similarly, acrylic adhesives are the ideal choice for oily
or corrosive environments or for use in high-temperature
applications. Epoxy adhesives also offer similar benefits, with
excellent chemical and electrical resistance.
While
many polymers show good adhesion to glass surfaces, their bonding
interactions tend to be weaker than the covalent bonds formed with
silanes, relying instead on intermolecular forces.3
Polymer
adhesion is sufficient for many applications, especially where motion
or substrate deformation is likely, as flexibility in the bonding is
beneficial. However, for applications that demand the highest levels
of adhesion, combining silane treatment with polymer bonding provides
a superior solution. This approach significantly enhances bond
strength, making it ideal for situations requiring both flexibility
and durability.
MO
SCI Solutions
MO
SCI has a long history of developing custom glass solutions for even
the most challenging applications. We can help you find innovative
and effective ways to overcome the challenges of glass bonding and
adherence to create devices that not only have the properties for
peak application performance but are also stable and resistant to
environmental degradation.
Contact
us today to
discuss your application.
Rebecca
Straw
References
and Further Reading
Brauer,
D. S. (2015). Bioactive Glasses — Structure and Properties
Angewandte. Angewandte Chemie – International
Edition, 54, 4160–4181.
https://doi.org/10.1002/anie.201405310
Yavuz,
T., & Eraslan, O. (2016). The effect of silane applied to glass
ceramics on surface structure and bonding strength at different
temperatures. Journal of Advced Prosthodontics,
75–84. https://doi.org/10.4047%2Fjap.2016.8.2.75
Park,
H., & Lee, S. H. (2021). Review on Interfacial Bonding Mechanism
of Functional Polymer Coating on Glass in Atomistic Modeling
Perspective. Polymers, 13, 2244.
https://doi.org/10.3390/polym13142244