Friday, 3 January 2025
Soldering Iron Maintenance
Wednesday, 28 August 2024
Visible Devitrification
"Why does devitrification appear on slumped pieces?"
A brief explanation
Scientific research in developing a glass matrix to support bone grafts
gives some information. This kind of
glass matrix requires to be strong.
Development showed that devitrification weakens the matrix. The crystals in a matrix are not as strong as
the amorphous glassy state. So,
devitrification needs to be avoided.
The research to avoid devitrification showed that it begins at about 600˚C/1110˚F.
It only begins to become visible above
700˚C/1300˚F. The process developed was
to introduce a “foaming” agent. The
process fired slowly to 600˚C/1110 ˚F and then quickly to 830˚C/ 1530˚F. It left a strong open matrix around which bone
can grow. Although the research used float glass, it is also a soda lime glass,
just as fusing glasses are. The formation
of devitrification begins at the same temperature for fusing glasses as for
float.
The result of this medical research shows that devitrification begins on
glass before it is visible. Devitrification is cumulative. A little becomes
greater with another firing. This is so
even with good cleaning between firings. The new devitrification builds on the
previous. It does this from 600˚C/1110 ˚F.
A subsequent firing can continue this devitrification to the point where
it is visible. This can happen, although the temperature at which we can see it after one firing has not been reached. This continued
devitrification at low temperatures can become great enough to be visible at
the end of one or multiple slumps.
Credit: Bullseye Glass Co. |
What can we do?
Clean all the glass before every firing very well.
·
Avoid mineralised water.
·
Final clean with isopropyl alcohol.
·
Polish dry at each stage with white absorbent paper.
Soak longer at lower temperatures.
·
Use longer soaks to achieve the slump.
·
Keep the temperature low.
·
Observe the progress of the firing with quick peeks.
Use slower ramp rates.
·
Slower rates enable the heat to permeate the glass.
·
Enables a lower slump temperature.
If there is any hint of devitrification after the first firing,
· use a devitrification spray, or
· provide a new surface.
- o remove the surface by abrasion on sandblasting,
- o cap with clear, or
- o cover whole surface with a thin layer of clear powder.
· Fire to contour fuse to give a new smooth surface.
· Clean very well and proceed to slump.
Wednesday, 31 January 2024
Care of Ceramic Kiln Shelves
Mullite kiln shelves credit: IPS Ceramics |
The most popular and easily available ceramic shelves are made
from Mullite, Cordierite, and CoreLite. Other hard specialist kiln shelves are
available. They are made of other materials. Shelves are also made from other
materials such as refractory fibre board, vermiculite, and fire-resistant
ceiling tiles. This concentrates on the care of ceramic shelves.
Composition and Characteristics
This table gives
some information about the characteristics of the materials involved in these
shelves.
Name |
Thermal Shock Resistance |
Brittle |
Strength |
Composition |
CoreLite |
Low |
Yes |
Moderate |
Ceramic with a high silica content |
Cordierite |
High |
Yes |
Strong, but heavy |
Magnesium, iron, aluminium oxide, silica |
Mullite |
High |
Yes |
Strong. but heavy |
Silica, Aluminium oxide |
CoreLite is a trade name for an extruded ceramic
shelf. It is strong, but brittle. It is subject to thermal shock below 540ºC/1000ºF.
This suggests the ceramic has a high silica content as the quartz inversion is at
573°C/1063°F,
where the ceramic has a sudden expansion on heating and an equal contraction on
cooling. The cooling rate at this temperature is normally slow enough to avoid breakage.
credit: Clay Planet |
cordierite - composed of magnesium, iron,
aluminium oxide, and silica. hard, brittle, and with low expansion
characteristics.
credit: refractorykilnfurniture.com |
Mullite –composed largely of silica and
aluminium oxide. It is strong, brittle, and has good thermal shock resistance.
Care
There is enough information from considering the composition
of these shelves to indicate they are all brittle and have differing vulnerabilities.
These have implications for storage, use and cleaning.
Storage
If storing vertically, take care to avoid setting down on hard
surfaces. If they are in a rack, have a separate slot for each shelf. This
avoids friction between shelves and possible surface scratches. The most useful
material for these racks is wood, or harder materials covered with wood. These
racks can be horizontal or vertical.
If it is not possible to have a separate rack for each shelf,
do not lean them on each other. Shelves leaning against others or against hard
surfaces can become scratched. Provide a cushion against scratches such as
cardboard, or thin plywood.
When moving the shelves, avoid setting them down on their corners,
or bumping the shelf anywhere against hard structures.
Use
Reduce firing speeds to less than 220ºC/430ºF per hour up to
540ºC/1005ºF, especially for CoreLite shelves. Cordierite and Mullite shelves
are not as sensitive, but still can be broken by fast firing rates in this temperature region.
Cover a large portion of the shelf at each firing to avoid
uneven heating of the shelf. It is best to evenly distribute moulds and other
things that shade the heat from the shelf around the shelf to help avoid thermal
shock breaks.
If you cannot or do not want to cover the whole shelf, elevate
the mould(s). This helps to keep the whole shelf at the same temperature when only
small parts of shelf are covered. It does not seem to matter so much when flat
glass is in contact with the shelf. But continue to observe the moderate ramp
rates below 540ºC/1005ºF.
It is even more important to elevate damp or heavy moulds
from the shelf. These kinds of moulds shade the heat from the shelf immediately
below them while the rest of the shelf heats rapidly. This difference in
expansion over parts of the shelf becomes too great for the shelf to resist.
Another thing to avoid is cutting fibre or shelf paper on
top of the shelf. It often creates long shallow scratches in the shelf. These
can be the source of bubbles, but more often, flaws on the back of the fired
pieces.
Cleaning
Care is needed to avoid mechanical damage during cleaning. Scraping
can create scratches in the shelf. These are difficult to remove or fill smoothly.
So, scraping needs to be done carefully.
Any sanding also needs to be done carefully. If you use
power tools, it is very easy to create shallow depressions that will be the
source of bubbles in future firings. It is slightly more time consuming to manually
sand the kiln wash with a sanding screen with or without a holder. But it preserves
the flatness of the surface.
If it is decided to wash the shelf primer off the shelf,
consider how difficult it is to wash a very persistent baked on substance. It
requires thorough scrubbing to remove all the hardened material. Power washers are not advised since the high water pressure can abrade the surface of the shelf. But if you do
decide on washing, you need to air dry for several days afterwards. Then kiln
dry slowly to just below boiling point of water. Soak at that point for several
hours, or until a mirror held above the open port does not fog up.
There is more information on removing kiln wash here and
here.
Summary
Ceramic kiln shelves are hard, but subject to scratches,
impact breaks, excess dampness, failure due to uneven temperatures, and to
rapid rises in temperature below 540ºC/1005ºF.
Wednesday, 31 May 2023
Causes of Large bubbles
Let’s think about moisture and large bubbles from under the glass. It is not the water, but the gasses created by the decomposition of materials that can cause the bubbles. There are other causes of large bubbles too. The most common causes are discussed here.
The usual explanations are:
- · Uneven shelf
- · Heat resistant particles under the glass
- · Uneven heating
- · Glues
- · Organic material
- · Moisture
- · Amount of gas
Uneven shelf
Shallow depressions in shelves can cause large bubbles. Occasionally,
the shelf can be damaged in various ways causing scratches or dings in the
shelf. Air can be trapped in these depressions. And it does not take much
volume of trapped to be a problem. The heat of kilnforming causes the air to expand.
As the glass becomes less viscous with increased temperature, the pressure from
the expanding air forces the glass upwards. The amount of air and the amount of
heat work combine to create bubbles from simple uprisings to large thin walled
or even burst bubbles.
There are some things that can be done to detect and avoid
bubbles from forming. It is possible to screed powdered kiln wash over kiln
washed shelf. This gives pathways for the air to escape. It does leave a more
marked bottom surface than kiln wash.
Using 1mm or 2mm fibre paper allows air from under glass. You can maintain a relatively smooth surface with Papyros or Thinfire over the fibre. Even Thinfire or Papyros on its own will allow air from under the glass.
Checking for depressions can be done by spreading kiln wash
powder over shelf and drawing a straight edge over the shelf. Depressions will
be shown by the presence of the powder. It can also be done with powdered glass
frit.
Particles under glass
Any particle resistant to kilnforming temperatures holds the
glass up while it is forming so creating an air space. It is important to
ensure the shelf is clean as well as flat. Small pieces of grit or dirt that
are resistant to high temperatures will hold the glass up from the shelf enough
to create a bubble – small or large depending on the temperature. Vacuuming the
shelf before adding anything to the surface before each firing is important to
bubble free results.
Uneven heating
This is sometimes cited as a cause of bubbles. If so, the heat would need to be very localised. This is possible if the glass is very near elements. In general, the temperature is equalised at a distance equal to the width of the elements.
Glues
A wide variety of
glues are used in kilnforming. Those available to enthusiasts all burn away
leaving gasses between layers. These gasses - if trapped - can thin the glass
below as well as above the glue’s position. This will give the impression that
the bubble has come from between the shelf and the glass. Most often the bubble
forms between the glass layers, pushing a bubble only into or through the top
layer. The solution is to avoid using glue or minimise it and place it only at
the edges.
Organic material
Organic materials can be a problem. When you are using a
large or thick fibre paper sheet under a piece of glass, occasionally the
gasses from burning out of the binder can be great enough to create a bubble. Although
normally, this only leaves a grey to black mark on the underside of the glass.
Vermiculite boards need to be fired before use, as they contain significant
amounts of binder.
Inclusion of organic materials such as leaves, twigs, or bones,
leads to bubbles. Very long soaks below the softening point of the glass are
required to allow the organic material to burn out of the objects. The time required increases from an hour for
leaves to 24 for bones.
Moisture
Moisture is very often cited as the source of bubbles. It is
possible that the steam from water may be trapped in shelf depressions, or the
areas held up from the shelf. And anytime there are no precautions to allow the
air from under the glass, or between sheets bubble formation can be promoted.
If adequate precautions are taken (flat shelf, clean shelf, bubble squeeze) the
moisture will evaporate before the glass is hot enough to form a seal around
the edges and trap any steam. It is another good reason for moderate ramp rates
at the beginning of a firing.
Amount of gasses
Of course, if there is a lot of moisture there can be
problems. Simply applying kiln wash in four coats does not leave enough water
in the shelf to be a problem.
If you have washed the kiln wash off a mullite shelf, there
will be a lot of water in it even after it feels dry. Then it does need to be
kiln dried before use. To avoid breaking the shelf you need to fire slowly to 99°C/210°F
and soak there for a couple of hours with the vents open or lid propped up a
little to allow the moisture out of the kiln.
Wednesday, 1 December 2021
Cleaning masses of pieces
Wednesday, 24 November 2021
Playing in the Sandbox
Pouring the frit into the sandbox |
Moving the frit with a skewer |
Using a jewellers scoop to add the frit. |
A thick copper wire being used to poke down from an upper layer to the lower ones. |
Two sandboxes placed on separate shelves |
A corner of the shelf with the 6mm fibre spacer |
Pressing shelf placed on top of the glass sandbox |
- · Even with this additional mass, you can fire quickly. This is because the glass is in small pieces and that the mass of the shelves gains heat slowly.
- · The greater mass does require longer soaks than a normal fuse firing.
- · The upper temperature for a full fuse is required to get the glass to a sufficiently low viscosity to allow the glass to move.
- · The long soak at the top temperature does not promote devitrification as in normal fusing. My speculation is that the glass is not exposed to the air, so the devitrification cannot form.
- · A further difference in a pressing firing is that the annealing can be at the rate for the final thickness of the glass. The mass of the shelf and weights above the glass means the glass is cooling evenly from both sides, unlike normal fusing. The glass may be cooling more slowly than programmed, but the programmed rates limit any possibility of too rapid a cooling.
Untreated result of pressing |
This shows on the lower left a loosened piece of sellotape on the edge of the sandbox. |