Showing posts with label Devitrification. Show all posts
Showing posts with label Devitrification. Show all posts

Wednesday 15 August 2012

Bottle slumping

Results

Devitrification is a major problem on bottle slumping. Some means of reducing the problem are
  • clean labels off thoroughly
  • remove all adhesives
  • scrub the whole bottle and polish dry
  • apply a devitrification spray before firing.
  • Spend as little time in the devitrification range (700C – 750C) as possible
  • Vent the kiln up to 540C if you are using fibre papers
  • sandblast off the devitrification and fire again if the devit is slight
  • in severe cases of devitrification, throw the bottle away.

Champagne and large bottles of sparkling wine split easily due to the differences in thicknesses. Firing of these needs to be very slow until you get past 715C.

Bottles with printed labels need particular care. The enamels used in the printing may contain lead and any other elements in the paint may contaminate your kiln.
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Sunday 13 March 2011

Placing Clear on the Top

One effect of placing clear under a coloured glass, especially a dark one, is that the bubbles rising will thin the colour, even to the extent of giving a small clear circle in the midst of the colour. Placing clear on top almost completely eliminates this effect.


An additional effect of placing clear over colour, especially opals, is that it reduces devitrification.

Thursday 30 December 2010

Application of devitrification solutions

Smooth and complete coverage of the piece is the aim when applying devitrification solutions. A soft brush, an air brush, a mouth atomiser are some of the ways to apply the solution. Some even use a sponge - all these application methods will do the job.
It is a pretty simple process, but requires concentration to ensure the piece is evenly covered. If it isn't, there will be areas of devitrification left after firing.

Sunday 26 December 2010

Longevity of Borax as a devitrification agent

It is true that Borax is water soluable. However, the borax has done its job by preventing the devitrification, so it does not matter whether it has or has not disolved, nor whether it is inside or outside.

Borax as a flux for paint in excessive quantities has the effect of corrosion on the paint or enamel it is mixed with. It is not actual corrosion, just that its effects are like that. The borax expands when wet. The expansion is very little, but over time "pops" off the paint - the time scale is 50-80 years. This happens on the inside of windows where the paint is. So it is not an inside/outside issue, just one of moisture.

But this irrelevant in kiln forming applications when attempting to prevent devitrification, or even to correct existing devitrification. The subsequent possible disappearance of the borax will not matter to the appearance of the piece. It has been reported that borax covered sushi dishes going through dishwasher cycles in a restaurant for years show no devitrification after the presumed disappearance of the borax. In fact, the proprietary devitrification solutions that contain lead would not be applicable in this food containing situation.

Other references to devitrification are:
Homemade devitrification solution
Description of devitrification
Temperature range

Wednesday 22 December 2010

Devitrification Prone Glasses

"Are there specific glasses that are more prone to devitrification, and knowing that, what steps can you take to try to avoid it?"


Glasses that are formulated and tested compatible for kiln forming are less likely to devitrify than other art glasses.

Opalescent glasses even if tested compatible for kiln forming are more likely to devitrify than their compatible transparent counterparts.

Yes, you can fuse some of the transparent glass made by a single manufacturer - Spectrum transparent and especially the water glasses are most often compatible within certain limits. But you will find that the edges show devitrification almost always. When using glass untested for compatibility, capping with clear glass often helps in reducing or preventing devitrification, as the clears seem less prone to devitrification than coloured glasses

You can clean very well and hope for the best, or you can clean and then use a devitrification agent - normally a flux or low firing glass in suspension - and spray or brush it on. If it is one of the low firing glasses in suspension, make sure you put it on before taking it to the kiln, as it will stick to other things when fired.

Another method is to avoid staying in the devitrification range of temperatures very long - both during temperature rise and cooling.

A description of what devitrification is


The temperature range in which devitrification occurs


A homemade devitrification solution

Thursday 26 August 2010

Cleaning Glass

Glass with dust, oil or other residues promotes devitrification. So first try to remove any excess of these.

Cutting without oil can avoid introducing more oils. Specially formulated cuttings fluids are available that are not oil.

Wash with only a few drops of washing up liquid of the kind without additives to keep you hands soft, or smell good. If there are soap bubbles on top of the water, you are using too much soap.

Window cleaning products are not usually appropriate, especially if they contain ammonia. A few products do not have additives that promote devitrification. One that works well for me is the Bohle aerosol cleaner (but not the concentrate).

Be careful about your rinsing water. If it has mineral salts in it, it can form nucleation points for devit.

Polish dry using plain paper towels or microfiber cloths. Change frequently and wash without softeners.

If you are grinding the edges, clean immediately before any part dries to avoid the powdered glass filling the scratches caused by grinding. Some put the ground pieces into a bowl of water immediately to keep the edges wet until cleaning can be done.

Wednesday 18 August 2010

Devitrification of Edges

Devitrification often occurs on the edges of glass, and can be seen as a thin line of devitrification -often looking like smudges that won't wipe off - where the edge has flattened during the fusing. There are some ways to avoid this.

Avoid grinding if at all possible.

If you must grind, use fine heads/grits. Then clean immediately before any part of the glass dries. You may need to clean part of the glass piece before the grinding is complete to avoid any drying of the powder on the edge of the glass.

Clean well with a minimum of soap and rinse with water that does not have a lot of minerals in it. Polish well with plain paper towels or frequently changed microfiber cloths.

Window cleaning products are not usually appropriate, especially if they contain ammonia.

Avoid introducing oils from the cutter by scoring with a dry cutter or use a specially devised cutting fluid. Cleaning solutions that have additives to be kind to hands or scents should be avoided.

The edges of some glasses devitrify more easily than others. If this continues to be the case after all cleaning efforts have failed, then use a devitrification spray, but continued cleaning is still necessary. There are no short cuts in cleaning.