Wednesday 19 May 2021

What are enamels?




Not all enamels are equal

Enamel paints
This description refers to a paint that air dries (or with minimal heat) to a hard finish (usually gloss). Most commercially available enamel paints are significantly softer than either vitreous enamel or heat cured synthetic resins. The term "enamel paint" generally is used to describe oil-based covering products, usually with a significant gloss finish. Many latex or water-based paints have adopted the term.

Enamel paint has come to mean a "hard surfaced paint" and usually is in reference to paint brands of higher quality, floor coatings of a high gloss finish. Most enamel paints are alkyd resin based. Some enamel paints have been made by adding varnish to oil-based paint. Enamels paint can also refer to nitro-cellulose based paints. Nitro-cellulose enamels are also commonly known as modern lacquers.  These have been largely replaced by synthetic coatings like alkyd, acrylic and vinyl.


Enamel paints are used for coating surfaces that are outdoors or otherwise subject to hard wear, or variations in temperature.  A widespread application is in paints for cars. It is also used frequently to decorate or label bottles due to the low curing temperatures of some formulations.


Vitreous enamels 

Vitreous enamels are used in a variety of circumstances.  Metal signs are most frequently enamel coated; they are used in ceramics as over glazes;  and they are used on glass in many circumstances.

Vitreous Enamel is simply a thin layer of glass fused at high temperature on to the surface of a metal or glass. Vitreous Enamel can be defined as a material which is a vitreous solid obtained by smelting or fritting a mixture of inorganic materials.  The word enamel comes from the High German word ‘smelzan’ and from the Old French ‘esmail’.

The key ingredient of vitreous enamel is finely ground glass frit. Colour in enamel is obtained by the addition of various minerals and metal oxides. 

Vitreous enamel is made by smelting naturally occurring minerals, such as sand, feldspar, borax, soda ash, and sodium fluoride at temperatures between 1200°C and 1350°C  until all the raw materials have dissolved. The molten glass which is formed is either quenched into water or through water-cooled rollers. This rapid cooling prevents crystallisation. The resulting frit is ground in a rotating ball mill either to produce a water-based slurry or a powder.

At the milling stage, other minerals are added to give the properties and colour required of the final enamel. Different enamel colours can be mixed to make a new colour, in the manner of paint. Enamel can be transparent, opaque or opalescent.

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Metal enamelling
Modern frit for enamelling steel is typically an alkali borosilicate glass with a thermal expansion and glass temperature suitable for coating steel and other metals. Raw materials are smelted together between 1,150 and 1,450°C (2,100 and 2,650°F) into a liquid glass that is directed out of the furnace and thermal shocked with either water or steel rollers into frit. Vitreous enamel is often applied as a powder or paste and then fired at high temperature. This process gives vitreous enamel its unique combination of properties. The smooth glass-like surface is hard; it is scratch, chemical and fire resistant. It is easy to clean and hygienic.  It all started 3500 years ago in Cyprus. Since 1500 BC, enamelling has been a durable, attractive and reliable material.

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Enamels in Ceramics
Overglaze decoration, overglaze enamelling or on-glaze decoration are all names for the method of decorating pottery, where the coloured decoration is applied on top of the already fired and glazed surface, and then fixed in a second firing at a relatively low temperature.  The colours fuse on to the glaze, so the decoration becomes durable. This decorative firing is usually done at a lower temperature which allows for a varied and vivid palette of colours, using pigments which will not colour correctly at the high temperature necessary to fire the clay body.


Glass Enamels
Glass enamels are produced in the same way as enamels for metals and ceramics.  The frit characteristics are adjusted for various applications and temperatures.  This combination of finely ground frit and metals for colouring are often combined with a binder or carrier medium.  It is similar to vitreous enamel on metal surfaces, but the supporting surface is glass. It is also close to "enamelled" overglaze decoration on pottery, especially on porcelain, and it is thought likely that the technique passed from metal to glass (probably in the Islamic world), and then in the Renaissance from glass to pottery (perhaps in Bohemia or Germany). 

Glass may be enamelled by sprinkling a loose powder on a flat surface, painting or printing a slurry, or painting or stamping a binder and then sprinkling it with powder, which will adhere.  The powdered frit can be in the ceramic on-glaze composition suitable for fusing or casting temperatures, or it can be adjusted for slumping temperatures as in the traditional glass stainers’ enamels. It can produce brilliant and long-lasting colours, and be transparent, translucent or opaque. Generally, the desired colours only appear when the piece is fired, adding to the artist's difficulties.



The term enamel is applied to a wide variety of coating materials.  The range of usage is indicated, and the manufacture and applications of vitreous enamels is indicated.  The term enamel is not properly applied to finely ground coloured glass in a medium.

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