Inadequate Annealing - Effects on Next Firing

Credit:

https://immermanglass.com/about-kilnforming/cracks/

The speculation about breaks caused by inadequate annealing of the piece on the previous firing is common.  I do not know if this can be proved to be inaccurate, but we should think about it.

A parallel condition to this poor annealing is toughened/tempered glass which is under a lot of stress between the inside and outside surface of the glass. As Bob Leatherbarrow mentioned to me, we can heat up the highly stressed toughened glass without breaking it by using moderate ramp rates. During this heat up in the brittle phase, the stress is gradually relieved. It does require the moderate ramp rates, of course. 

This parallel circumstance of heating toughened/tempered glass which is highly stressed raises the question: Why should mildly stressed kilnformed glass suffer breakage, if fired at a reasonable rate? Highly stressed toughened/tempered glass does not.

If we apply the experience of relieving the stress in toughened/tempered glass, you can see how inadequately annealed glass behaves. The under-annealed glass has stress distributed (possibly unevenly) across its substance. As the glass temperature moves toward the strain point it becomes less brittle and the stresses are reduced. By the time the glass reaches the strain point, the stresses from poor annealing are relieved.

Any glass not fired slowly enough for its thickness or layup toward 300˚C/573˚F will break. This has been observed to occur around 260˚C/500˚F.  This most commonly occurs in pieces that are laid up with different thicknesses  across the surface. The heat cannot reach the bottom layers as quickly as the overlying ones. The expansion of covered and uncovered glass - due to the heat exposure - is to different.

Thinking about the behaviour of glass in this way indicates that breaks early in the firing relate to a too rapid ramp rate, not necessarily a previous annealing problem. We should, of course, be checking on the stress in our pieces after each firing. This will alert us to the amount of stress in the piece and so to be more cautious in the ramp rate and in the annealing during the current firing. 

Speculation about inadequate annealing in a previous firing as a cause of breaks is misplaced. The thinking that stress will carry through the heat-up and cause breakage is misdirected. 

More information on this is available in the eBook LowTemperature Kilnforming, an Evidence-Based Approach to Scheduling at Etsy VerrierStudio shop and from Bullseye Ebooks.