Monday 7 May 2018

False Lines in Leaded Glass

False lines are used in leaded glass where the design calls for an angle that cannot be cut into the glass. This includes right angles and even more acute angles. E.g., the petals of a fuchsia flower. 


The design would call for an angle of about 60 degrees. This is impossible to achieve through hand cutting. So the glass is cut in a curve and the cames on the side and bottom of the petal have their hearts cut out so they overlap each other. 

In the example above, the red petal points would be cut rounded, so that the clear glass below can be rounded as well.  The came or foil is extended beyond the glass to give the visual points required.

The overlap is then trimmed to the shape of the outside of the petal. When soldered, the appearance is of the glass being cut at the angle required for the flower.



At other times, the requirement is for a line to go into a piece of glass, but not all the way across. As in this stained glass panel by Justin Behnke.  The hanging lines are those on the lower left of the panel, giving a great flow to the whole.


Again you cut the heart out of the came, and overlay the smoothed lead onto the glass. You can use just a little silicone to hold the lead in place until you finish cementing. After this you can lift the piece of came and use silicone or epoxy resin to firmly attach the came to the glass. You do not want to do this before cementing as any excess of glue will be made dirty by the cementing process and be very difficult to clean up.


There are also times when you may want to have a silhouette, you can cut it out of lead foil and solder it into place. This allows intricate shapes to be made when a dark representation of the shape is required. If the panel can be seen from both sides, the overlays should also be on both sides. These should be glued to the glass just as for cames.

Further information on removing the heart of lead came are given in this post on leading of acute angles.

These principles can be applied to copper foil too.

Wednesday 2 May 2018

Slumping a Form Flat


There are a variety of reasons that you might want to make a formed piece flat again for another kind of slump or drape.

There are lots things you think about when preparing to make a shaped piece flat.

I am going to assume there are no large bubbles in the piece.  You can see the posts  Large bubbles and Bubble at bottom  on the causes.

The following comments are things in five groups to consider when contemplating flattening an already formed shape.

Shape/form
  • ·         Shallow forms with no angles have the fewest difficulties.  Take it out of the mould, put it on the prepared shelf and fire to the slump temperature.  Observe when it is flat and proceed to the annealing.
  • ·         Forms with angles or multiple curves are a little more difficult.  If the piece has stretched in some areas to conform to the mould, you will have some distortion in the pattern and possibly some thinner areas.  It should be easy to flatten pieces on a prepared shelf with the same schedule, but a slightly higher top temperature as used to slump it.
  • ·         Forms where the sides have pulled in will become flat, but continue to have curved sides.
  • ·         Deep forms are possibly the most difficult.  The glass may have stretched, giving thin areas.  It may be that the process of flattening the glass will cause a rippled effect as the perimeter of the piece is a smaller size than the original footprint.  These deep forms are the least likely to flatten successfully.


Orientation
  • ·         Which way up? Upside down or right side up?  Shallow forms are easiest to flatten by placing them right side up on a prepared shelf.  For deep or highly formed pieces, it may be best to put it upside down to allow the now higher parts to push the perimeter out if it is necessary.


Thickness
  • ·         Thick glass will flatten more quickly than thin glass, so you need to keep a watch on the progress of the work to avoid excess marking of the surface of the glass.
  • ·         Very thin pieces are likely to develop wrinkles as they flatten.  Even if they do not, there will be thick and thin areas which might cause difficulty in subsequent slumping.
  • ·         Tack fused pieces are likely to tend to flatten at different places and times due to the differences in thickness and therefore weight. This makes shallow forms easier to flatten.


Temperatures
  • ·         In all these processes, you should use the lowest practical temperature to flatten.  This means that you will need to peek at intervals to see when it is flat.
  • ·         Your starting point for the top temperature to use will be about 10°C lower than that at which the original was slumped, normally.  The amount of time may need to be extended significantly. The reason for this is to avoid as much marking on the finished side as possible.
  • ·         Shallow forms and thick pieces will flatten more quickly than others, so a lower temperature can be used.  You will still need to observe the progress of the flattening.
  • ·         Angled shapes and deep forms will need more heat and time than the shallower ones. 
  • ·         Thin pieces may require more time than thick pieces.
  • ·         Tack fused pieces need more attention and slow rates of advance to compensate for the differences in thicknesses.


Separators
  • ·         Kiln washed shelves are usually adequate for flattening.
  • ·         Thinfire or Papyros are needed when flattening upside down to ease any sliding necessary.
  • ·         Powdered kiln wash or aluminium hydrate can be dusted over the kiln washed shelf when it is felt the form will need to slide on the shelf while flattening.



It may be that after all this, you feel it is not worth it to flatten.  It certainly is worth the effort, if only to learn about the characteristics of the form and its behaviour in reversing the slump or drape.

Tuesday 24 April 2018

Thinfire* and Devitrification


There are reports that Thinfire causes devitrification by rising over the edges of the piece.  There as many saying they have no difficulties with the Thinfire curling.  This indicates there are several factors that may be at work.

If the Thinfire curls over the edge of the glass while firing, it will deposit a fine powder on the edge and perimeter of the piece.  This gives an ideal condition for devitrification to form.

Bullseye recommends placing dams or other kiln furniture on the edges of the paper to resist any tendency for the paper to curl.  Of course, if the paper is put upside down, it is much more likely to rise over the edge.  The smoothest surface should face upwards. Now that Bullseye prints their logo on the bottom, this is unlikely to be a problem.

Cutting the paper to the size of the piece is initially an attractive idea.  However, it does not account for the expansion beyond the initial footprint that glass goes through while heating to the working temperature, and before it contracts to its final size.  The Thinfire must be cut larger than the piece. The amount depends on the thickness of the piece.  6mm larger may be adequate for a 6mm thick piece.

Bullseye does not recommend using Thinfire under multiple small pieces of glass because the paper can shrink and move, disrupting the glass placement on the kiln shelf.  Instead using kiln wash as the separator may be better in these circumstances.

There are other things that can affect the deposit of the separator powder from the Thinfire onto the glass.

Venting – It seems to be good practice to open the peep holes or leave the door/lid slightly ajar during the heat up.  These should be carefully closed once the smell of the binder burning out disappears.  This is usually around 500°C.  The idea here is that the combustion products from the binders are allowed out of the kiln without settling on the glass.  I do not find this necessary, but many do, so it is worthwhile trying it out.  When the smell of the burnout of the binders ceases close the lid slowly and place the bungs gently into the peep holes to avoid disturbing any dust within the kiln.

Opening the kiln or ports - Opening or closing the kiln above ca. 500°C, if done quickly, will create a draft that will distribute the powder around the kiln.  Some of this will land on the surface of the glass. Other parts of the Thinfire will be moved up onto the edges of the piece.  This dust and the pieces of Thinfire will create nucleation points for devitrification.  Always open or close any part of the kiln slowly when there are powders or anything else which can be disturbed by a gentle waft of air.

Over firing - Another element that can bring Thinfire onto your pieces are a too hot a firing.  During high temperature firings, the glass will expand and thin more than usual.  During the cooling phase, the glass will draw back to being 6-7mm thick. This means the glass will have expanded over the Thinfire and drawn some of it back onto the edges as it thickens and retreats.  The solution for this is to reduce the top temperature and possibly lengthen the soak time, but do not do both at the same time.  First see what a lower temperature with a 10-minute soak will do.

Of course, if you are not having problems with Thinfire or Papyros, continue your practice as normal.


*I have used the term “Thinfire” almost exclusively throughout, but remember all these notes apply to Papyros too.

Wednesday 18 April 2018

Rates of Advance with Soaks



I’m sure I have written about this before, but a repetition will not hurt.

I have seen many schedules with initial rates of advance interrupted by soaks.  These kinds of schedules that are written something like this:

250 degrees C to 200C, soak for 10 (or 20 or 30) minutes
250 degrees C to 500C, soak for 10 (or 20 or 30) minutes
300 degrees C to 1100C, soak for 10 (or 20 or 30) minutes
300 degrees C to 1250C, soak for 10 (or 20 or 30) minutes
600 degrees C to working temperature (1450, 1500 etc.)

When I have asked, I’m usually told that these are catch up pauses to allow all the glass to have an even temperature.  There are occasions when that may be a good idea, but I will come to those later.  For normal fusing, draping and slumping these soaks are not needed.

To understand why, needs a little information on the characteristics of glass.  Glass is a good insulator.  It is a poor transmitter of heat.  Therefore, glass behaves better with a moderate steady input of heat to ensure it is distributed evenly throughout the glass.  To advance the temperature quickly during the initial heat up stages where the glass is brittle risks thermal shock. 

The soaks at intervals do not protect against a too rapid increase in temperature.  It is the rate of heat input that causes thermal shock.  Rapid heat inputs cause uneven temperatures through and across the glass.  When these temperatures are more than 5°C different across the glass, stress is induced.  As the temperature differential increases, so does the stress until the glass is not strong enough to contain those stresses and breaks.  At higher temperatures these stresses do not exist as the glass is less viscous.

If, as is common and illustrated in the schedule above, you advance at the same rate on both sides of the soak, the soak really does not serve any purpose – other than to make writing schedules more complicated.  If the glass survived the rate of heat input between the soaks, it will survive without the soaks.

But you may wish to be a little more careful. The same heating effect can be achieved by slowing the rate of advance.  Just consider the time used in the soak and then slow the rate by the appropriate amount.  Take the example above using 30-minute soaks:

250 degrees C to 200C, soak for 30 minutes
250 degrees C to 500C, soak for 30 minutes

This part of the schedule will take three hours.  You can achieve the same heat work by going at 167 degrees C per hour to 500 degrees C.  This will add the heat to the glass in a steady manner and the result will be rather like the hare and tortoise.  If you have to pause periodically because you have gone too quickly, you can reach the same end point by steady but slower input of heat without the pauses.

But, you may argue, “the periodic soaks on the way up have always worked for me.”  As you work with thicker than 6mm glass, this “quick heat, soak; quick heat, soak” cycle will not continue to work.  Each layer insulates the lower layer from the heat above.  As the number of layers increase, the greater the risk of thermal shock. Enough time needs to be given for the heat to gradually penetrate from the top to the bottom layer and across the whole area in a steady manner.

To be safest in the initial rate of advance, you should put heat into the glass in a moderate, controlled fashion.  This means a steady input of heat with no quick changes in temperature.  How do you calculate that rate?  Contrary as it may seem, start by writing out your cooling phases of the schedule.  The cooling rate to room temperature is the safe cooling rate for the final and now thicker piece.  If that final cool rate is 300 degrees, the appropriate heat up rate is half of that or 150.  If you are in the habit of turning off the kiln at 370°C, you can use the cooling rate that is scheduled to get you there.  Normally, you would double the rate you used to get to 370°C as the rate to room temperature.  So, the rate to 370°C is the same as half the final cooling rate.

This “half speed” rate of advance will allow the heat to penetrate the layers in an even manner during the brittle phase of the glass.  This rate needs to be maintained until the upper end of the annealing range is passed.  This is normally around 55°C (110°F) above the annealing point.

Then you can begin to write the rate of advance portion of your schedule.  It could be something like:

150°C to 540°C, no soak
225°C to bubble squeeze, soak
300°C to working temperature, soak 10 minutes
Proceed to cool segments 

I like simple schedules, so I normally stick to one rate of advance all the way to the bubble squeeze.  This could be at the softening point of the glass or start at 50°C below with a one hour rise to the softening point with a 30-minute soak there before proceeding more quickly to the working temperature.

Exceptions.

I did say I would come back to an exception about soaks on the rate of advance segment of the schedules.  When the glass is supported – usually in a drape – with a lot of the glass unsupported you do need to have soaks.  The kind of suspension is when draping over a cylinder or doing a handkerchief drop.  This is where a small portion of the glass is supported by a point or a long line while the rest of the glass is suspended in the air.  It also occurs when supported by steel or thick ceramic.

The soaks are not to equalise the temperature in the glass primarily.  They are to equalise the temperature between the supports and the glass.  A thick ceramic form supporting glass takes longer to heat up than the glass.  The steel of a cocktail shaker takes the heat away from the glass as it heats faster. 

The second element in this may already be obvious.  The glass in the air on a ceramic mould can heat faster than that on the mould.  The glass on a steel mould can heat faster over the steel than the suspended glass.  Both these cases mean that you need to be careful with the temperature rises.

Now, according to my arguments above, you should be able to slow the rate of advance enough to avoid breakage.  However, my experience has shown me that periodic soaks in combination with gradual increases in the rates of advance are important, because more successful. 

An example of my rates of advance for 6mm glass supported on a steel cylinder is:
100°C to 100°C, soak 20 minutes
125°C to 200°C, soak 20 minutes
150°C to 400°C, soak 20 minutes
200°C to draping temperature

Call me inconsistent, but this has proved to be more effective than dramatically slowing the rates of advance. 

Note:
This exception does not apply to slumps where the glass is supported all around by the edge of a circular or oval mould, or where it is supported at the corners of a rectangular or square one.


Another exception is where you have a lot of moisture in a mould, for example. You need to soak just under the boiling point of water to dry the mould or drive out water from other elements of your work before proceeding.  This applies to situations where you need a burn out, of for example vegetable matter at around 500C for several hours.

In both these cases, these are about the materials holding or contained in the glass, rather than the glass itself.

Came: Straighten vs stretch


In dealing with lead came there is often reference to “stretching the lead”.  This frequently leads to emphasis on making the lead came longer. However, this is a misinterpretation of the phrase.

The object in pulling on the lead is to straighten it.  No more effort needs to be put into the lead once it is straight.  In fact, further stretching can lead to weakness.

The upper strectched came has an orange peel texture and the lower straightened does not

You will see an “orange peel” texture on the surface of the came when it has been stretched beyond its tensile strength.  This indicates considerable weakness in the metal.


The upper piece illustrates the visual effect of over stretching leading to the weakening of the came

A test to show relative strengths in stretched and straightened came uses two short pieces of came from the original pair.





After three 90° bends from the straight to a right angle, the stretched came has begun to break.  The straightened came is deformed at the inside bend, but not broken. 

This test shows stretching the came to the extent that there is an "orange peel" appearance to the surface, dramatically weakens the lead came.  Only draw the lead came to make it straight, not to lengthen it.

When you are trying to get kinks and twists out, there is a point between straight and stretched where you begin to weaken the came instead of simply making it straight. There is a point in straightening linked or twisted lead that goes so far in trying to get it straight that the whole is weakened. When the orange peel appearance shows on the came, you have stretched to the weakening point. 

It is often better with kinked and twisted came to cut out the damaged portions and straighten the rest.

Wednesday 11 April 2018

Copper inclusions

Inclusions of metals can be achieved with care.  Copper is a very good metal, as it is soft, even though its expansion characteristics are very different from glass.  This note provides some things you might consider when planning to include copper in your fused pieces.

The copper sheet should be stiff, but not thick. If the metal can be incised with a scribe and maintain that through gentle burnishing, it is suitably thick. The usual problem is that the copper is too thick rather than too thin.  Copper leaf can be very faint if a single layer is used.  Placing several layers of leaf improves the colour, but often provides wrinkles.  In summary, the requirement is to get a thickness of copper that will retain its structure, but not be so thick and stiff as to hold the glass up during the fusing process.  

Do not use the copper foil as used for stained glass applications. The adhesive backing produces a black colour from the adhesive and many bubbles -  sometimes a single large one.

Copper can provide several colours.

Copper sheet normally turns burgundy colour when oxidised.  This means that there is enough air reaching the copper to oxidise it to deep copper red.  This most normally happens, because a lot of air can contact the metal during the extensive bubble squeeze usually given to inclusions.

To keep the copper colour, clean the metal well metal well with steel wool or a pot scrubber. If you use steel wool, wash and polish dry the metal before fusing.  Reduction of air contact with the metal helps to retain the copper colour.  There are two methods I have used.  Addition of a glass flux like borax or other devitrification spray will help prevent the air getting to the surface.  Another method of avoiding oxidisation, is to cover the copper with clear powdered frit, as well as the surrounding glass.

In certain circumstances you can get the blue green verdigris typical of copper in the environment.  This is an extent of oxidisation that is between the clean copper coloured metal and the burgundy colour of extensive oxidisation.  The key seems to be be a combination of restricted air supply, shorter bubble squeezes and lower temperatures.  Experimentation is required to achieve this consistently.


The spaces under and over the copper give the opportunity for bubbles to form. 

This means that the copper needs to be as flat as possible for one thing.  Burnishing the copper can have a good effect on reducing the undulations in the copper.  Thinner copper is easier to make flat than thicker.  If you can stamp a shape from the copper with a stamper designed for card making, it is a good indication that it will burnish flat.  Thicker copper sheet holds the glass up long enough in the temperature rise during the bubble squeeze to retain air around the metal.  This remains the case even after burnishing to be as flat as possible.

The second element that can help to reduce bubbles around the copper is to sprinkle clear powder over the copper sheet once in place on the glass.  The spread of the powder over the glass assists in giving places for the air between layers to escape.

These two things combined with a long slow squeeze can reduce the amount of bubbles you get.  It cannot totally eliminate them.

Of course, a longer bubble squeeze allows air to be in contact with the copper and promotes the change to a blue green or burgundy colour.

Foiling Space

There are a lot of views on what amount of space is required between copper foiled glass pieces.  Some say the pieces should be tight, others that a consistent space is needed, and some who say that variable spaces are fine.

It is necessary to consider what holds a foiled panel together.

Adhesive
The foil is supplied with an impact adhesive which helps keep the foil attached to the glass before soldering.  However, the heat of soldering deteriorates the adhesion of the glue.  If you must take a foiled piece apart you will find that the adhesive is sticky rather than firm. Also, the adhesive will continue to degrade during the life of the object.

Solder
The solder bead is significant in creating the matrix required to hold the panel in one piece.  The bead on each side holds the glass in place and resists deformation away from a single plane. This resistance is significantly reduced if there is not a fin of solder connecting the two beads.  The beads and the fin of solder form an “I” beam which together resists movement of the glass.

Strength
To form that “I” beam there does need to be space between the foiled pieces. It does not need to be wide, but it does need to be enough to wiggle the pieces.  This will allow the solder to flow from one bead to the one on the other side, forming a strong “I” beam.

In vertical panels, the glass is the strong element.  The solder lines serve to hold the matrix together.  Where people indicate the strong border will keep the whole panel from falling apart, they are correct in part. But, if there is not a sufficient “I” beam between each piece, the whole panel is subject bowing, either from wind pressure, vibration or mechanical pressure from handling.  Therefore, you cannot rely on the border to make your panel strong and long lasting.

Dissent
Some take the view that there will be enough unintentional spaces created between pieces to allow the fin form between beads intermittently.  But the gaps in the “I” beam due to tight fiting pieces will make it much weaker than a continuous bridge between beads.  The existence of gaps puts greater pressure on the solder that does bridge between beads.

An example was provided for me in a lamp brought in by client which spontaneously fell apart one evening.  (Not made by me, I add). The upper band of glass remained attached to the vase cap, but separated from the rest of the shade.  Fortunately, it fell straight down and only a little of the bottom edge was broken.  Investigation showed there was very little solder between pieces, although there was a good bead on each side of the lamp.  The lamp pieces separated, in different places, at the foil-glass interface and elsewhere at the foil to foil interface.  This indicates there was little or no solder where the foil remained on the glass, as the adhesive is much weaker than even a thin fin of solder running between the inner and outer beads. This case is an example of the need for a fin of solder to be formed between the beads on either side to provide a strong, long lasting object.

Heat Cracks
There is sometimes a fear expressed that tight fitting of foiled pieces can lead to heat fractures when soldering due to expansion.  Yes, when soldering pieces with a lot of variation in width, you do need to move reasonably quickly. Come back later to improve a bead if you need, to avoid overheating the glass.  Even the thin copper foil can transmit heat along its length, which reduces direct heat transfer to the glass.  Mostly, breaks occur from dwelling too long in one place with the soldering iron. It may be better to tin the foil all around the suspect piece just before running the bead.  This will warm the glass around the edges in preparation for the greater heat of laying down the bead.



The main point is that the solder needs to connect the beads on either side of the glass to provide a stable, strong and long-lasting piece.

Wednesday 4 April 2018

Relative stress in Tack and Full Fused Glass


There is a view that there will be less stress in the glass after a full fuse than a tack fuse firing.

This view may have its origin in the difficulties in getting an adequate anneal of tack fused pieces and the uncritical use of already programmed schedules. There are more difficulties in annealing a tack fused piece than one that has all its elements fully incorporated by a flat fuse. This does not mean that by nature the tack fused piece will include more stress. Only that more care is required.

Simply put, a full fuse has all its components fully incorporated and is almost fully flat, meaning that only one thickness exists.  The annealing can be set for that thickness without difficulty or concern about the adequacy of the anneal due to unevenness, although there are some other factors that affect the annealing such as widely different viscosities, exemplified by black and white.

However, tack fused annealing is much more complicated.  You need to compensate for the fact that the pieces not fully fused tend to react to heat changes in different amounts, rather than as a single unit.  Square, angled and pointed pieces can accumulate a lot of stress at the points and corners. This needs to be relieved through the lengthening of the annealing process.

The uneven levels need to be taken into consideration too.  Glass is an inefficient conductor of heat and uneven layers need longer for the temperature to be equal throughout the piece.  The overlying layers shade the heat from the lower layers, making for an uneven temperature distribution across the lower layer.

The degree of tack has a significant effect on annealing too.  The less incorporated the tacked glass is, the greater care is needed in the anneal soak and cool.  This is because the less strong the tack, the more the individual pieces react separately, although they are joined at the edges.

More information is given on these factors and how to deal with them in this post on annealing tack fused glass.


If you have taken all these factors into account, there will be no difference in the amount of stress in a flat fused piece and a tack fused one.  The only time you will get more stress in tack fused pieces is when the annealing is inadequate (assuming compatible glass is being used).

Wednesday 28 March 2018

Marker Pens


A lot of us use marker pens on our glass to determine cut lines, indicate areas that need grozing, etc.  These pens have a variety of names – felt tips, Sharpies, paint pens, fibre tips, permanent markers, laundry markers, and many other generic and trade names.




Most, except the paint markers, contain water or spirit based colours. Many of these pigments are reputed to burn away during the firing of the glass. 

Paint markers and the ones that contain metallic colours rarely fire off.  They are more likely to fire into the glass.  Some people take advantage of this fact to quickly add marks that will survive the firing.



I no longer trust anything to burn off. Even if the marks do apparently burn away, the residues are sites for devitrification to begin.



I clean all my marks off before firing.  It only takes the marks to be fired into a favourite piece to convert you to cleaning. If you use paint markers on black glass or coloured felt tip marks on clear, clean it all off before firing.  This removes the chance that the pigment will remain throughout the firing and ensures the glass is spotless when it goes into the kiln.


Wednesday 21 March 2018

AFAP firings


As Fast As Possible (AFAP), sometimes referred to “as soon as possible” (ASAP) firings need caution.  Usually, this AFAP rate is applied only above ca. 540⁰C or higher.

This is possible for small pieces in smaller kilns.  It is often desirable for pieces under 100mm.  In the case of smaller items, the heat can be distributed across and through the pieces easily.  There is no need for the same caution as for larger or thicker pieces.

But

There are effects on glass and kiln that AFAP rates have and need to be considered when setting the schedule for the firing.

Effects on glass
An AFAP rate softens the upper surface of the glass early and before bottom can catch up. This leads to greater possibilities of creating bubbles, as the surface is more easily moved by the air underneath.  So, the air can push upwards rather than be pushed by the weight of the glass from under and escape out the sides. 

The characteristic dog boning of thinner glass is increased, as the temperature overshoots, allowing the glass to become much less viscous, so the surface tension of glass can take over to draw the glass in to create a greater thickness.  This “robbing” of glass occurs both from the interior and edge.  The interior glass becomes thinner and so less able to resist bubble formation.


Effects on the Kiln Control
The controller is learning the relationship between the energy input and the temperature achieved all the way through each firing, even though you fired the same piece yesterday.  The controller is constantly (well, about once a second) comparing the actual rate of temperature increase or decrease with the programmed one.  When there is a difference, power is applied. On the way down there is no input of energy unless the cooling is too fast, so there are no concerns about the controller having to catch up.

If you programme AFAP, especially in a small kiln, you will get overshoots in temperature.  This is because considerable time is required for the controller to determine the continuing energy requirements for the rate set.  In small kilns, the upper temperature can rise quickly as there is less kiln mass to heat than in a larger kiln.

Also, the amount of energy required at the higher temperatures is greater than at the lower ones. This means the controller must constantly adjust the rate of energy input at different temperatures.

Both the above factors combine to give overshoots of the top temperature, sometimes by as much as 20⁰C.  During the soak time at top temperature, the kiln will attempt to adjust the energy input to maintain an even temperature. The result of this constant comparison is that the temperature drops considerably below the one set. The controller then overcompensates and goes over the set point again.  It continues bouncing above and below with less and less variation as the soak proceeds, because the controller is “learning” the heat input required.

This bouncing of the temperature gives you less control over the results of the firing.  This is especially so when there are voltage variations in the electricity supply.



Wednesday 14 March 2018

Cooling the Kiln


“Why does my kiln take so long from boiling point to room temperature?”

The rate at which a kiln cools is dependent several factors:
  • ·        The mass of the kiln. Some kilns have dense insulation bricks.  These are very good at holding heat, and release it slowly.
  • ·        Its insulation characteristics. Other kilns have light weight bricks or fibre insulation. Both these materials have less mass and can release heat quickly at high temperatures, but much less slowly at lower temperatures.
  • ·        The environment. The temperature of the surroundings has a big effect at lower temperatures.  The amount of air movement around the kiln also influences the cooling rate at these lower temperatures.


The physics of heat transfer determine the cooling rate. if all other factors are the same, the rate of temperature fall is faster when there is a greater temperature differential.  And it is slower where the temperatures are closer together.  You can see this by comparing the rates of fall at 800⁰C and at 300⁰C.  It is much faster at the higher temperature and slower at 300⁰C.  You will also notice that the kiln cools more slowly at the lower regions when the outside temperature is high than when low.

Rather than waiting hours or days for the kiln to get 
to room temperature, there are some things you can 
do.

·        Open any vents or peep holes your kiln has. Not only are peep holes good for observing the progress of the kiln work, they are important in cooling.  Their relatively small size insures that there is not such a great air exchange that could cause thermal shock.  The temperature at which you do this is relative to the thickness or variation in thickness of the pieces in the kiln, of course.

·        Open the kiln lid/door a little. As the temperature fall rate reduces, you can crack the kiln open a little.  Many times, you need to put a prop under the lid to keep it open only a little.  Again, this should only be done at a low enough temperature to avoid any thermal shock to the glass.

·        Create greater air movement around the kiln.  You can of course create greater air circulation around the kiln by opening doors and windows, or by a fan.  If you use a fan, it is best to avoid direct air current from the fan onto the kiln. This is because when the vents or lid are open, dust can be spread over the glass and throughout the studio.  If using a fan, it is best to have the kiln closed.  Some kilns have powered ventilation to speed cooling, but these are usually industrial.

How do I tell if I am cooling too fast?

The risk of opening your kiln after the end of the second part of the annealing cool (generally around 370⁰C) is thermal shock from the relatively cool air contacting the glass and cooling one part too much, causing a break or fracture.

You can select how fast a cool rate is safe for your piece and programme that into the controller down to room temperature.  Doing this does not use any more electricity than simply turning the kiln off.  The controller will only put more energy into the kiln if it is cooling more quickly than the rate you set. 

And this is the point of programming to room temperature.

When you vent your kiln, and have the controller set for a cooling rate, it will only add more heat if you have opened the kiln too much.  If you hear the controller switch on the elements, you know to reduce the size of the opening, because it is cooling faster than you set the rate to be.  This makes for a safe, but more rapid cooling than just letting the kiln cool with no ventilation.

"My controller shuts off when I open the kiln."

If your kiln does not allow any opening of the lid/door without the controller switching off, you need an alternative.  In this case, you will need to take note of the temperature drop over set periods to learn if the temperature is falling too fast or too slowly.  Usually 15-minute intervals are all that is required.  Record the temperature at the switch off and before venting the kiln. Vent the kiln. Fifteen minutes later record the temperature. Multiply the difference by four to get the hourly rate.  If that rate is above the one you intended, close the venting a little.  If it is less, open the venting a little more. Then record the temperature after another quarter of an hour. You continue to do this until you are satisfied you have settled on the rate of cooling you intended.



You must exercise patience with the cooling.  

The larger, thicker, more important the piece is, the more caution is required. 

Wednesday 7 March 2018

Kanthal vs. Nichrome

Both Kanthal and Nichrome are high temperature wires.

Kanthal
Kanthal is the trademark (owned by Sandvik) for a range of iron-chromium-aluminium (FeCrAl) alloys used in resistance and high-temperature applications. The first Kanthal alloy was developed by Hans von Kantzow in Sweden.

“Kanthal alloys consist of mainly iron, chromium (20–30%) and aluminium (4–7.5 %). The alloys are known for their ability to withstand high temperatures and having intermediate electric resistance.”  So, it is often used in kiln elements.

“Kanthal forms a protective layer of aluminium oxide (alumina) when fired.”  This layer resists further oxidisation of the elements when firing.  Aluminium oxide is an electrical insulator with a relatively high thermal conductivity.  Ordinary Kanthal has a melting point of 1,500°C.

“Kanthal is used in heating elements due to its flexibility, durability and tensile strength.” Its uses are widespread, with it being used in home appliances and industrial applications as well as glass and ceramic kilns.  As an aside, it is being used in electronic cigarettes as a heating coil as it can withstand the temperatures needed in this application.
Based on Wikipedia https://en.wikipedia.org/wiki/Kanthal_(alloy) and other sources.


Nichrome
Nichrome is an alloy of various amount of nickel, chromium, and often iron.  The most common usage is as resistance wire.  It was patented in 1905.

“A common Nichrome alloy is 80% nickel and 20% chromium, by mass, but there are many other combinations of metals for various applications.”  Nichrome is silvery-grey, corrosion-resistant, and has a high melting point of about 1,400°C.

It has a low manufacturing cost, it is strong, has good ductility, resists oxidation and is stable at high temperatures.  Typically, nichrome is wound in coils to a certain electrical resistance, and when current is passed through it, the resistance produces heat.  This is probably the most common material used for kiln elements.

When heated to red hot temperatures, the nichrome wire develops an outer layer of chromium oxide, which is stable in air, being mostly impervious to oxygen.  This protects the heating element from further oxidation.  However, once heated the nichrome wire becomes brittle and must be heated to red hot before bending.


Based on Wikipedia https://en.wikipedia.org/wiki/Nichrome and other sources.

Sunday 4 March 2018

CoE Varies with Temperature

Information from Bullseye shows that the Coeficient of Linear Expansion changes rapidly around the annealing range.

The following is from results of a laboratory test of Bullseye clear (1101F)
Temperature range.......................COE
20C-300C (68F -­ 572F).................90.6
300C-400C (572F - ­752F).............102.9
400C-450C (752F - 842F).............107.5
570C-580C (1058F-1076F)............502.0

Bullseye glass is probably typical of soda lime glasses designed for fusing.

The change of CoE by temperature is further illustrated by Kugler (a blowing glass) who state their CoE by temperature range. Remember CoE is an average expansion over a stated range of temperatures)
CoE 93 for the range 0C-300C
CoE 96 for the range 20C - 300C
CoE 100 for the range 20C - 400C

The extension of the range by 100C has a distinct effect on the average expansion over the (larger) range. 

This shows why it is not helpful to refer to CoE without also mentioning the range of temperature.

In addition, here is an illustration of the effect. 




(If the owner of this illustration comes across this, please let me know, as I have lost the source)