Conditions for Re-firing Kiln Wash

I do not know the exact chemical changes of kiln wash at fusing temperatures.  But I do suspect it has to do with the kaolin.  The aluminium hydrate is stable to much higher temperatures (melting point of 2,072°C/3,762°F).  So, I don't believe that part of kiln wash is changing. 

The Influence of Kaolin

Some reading has led me to learn that by 600°C/1113°F the kaolin begins going through a non-reversable chemical change.  Prior to that, water can rehydrate the kaolin.  In the hydrated state kaolin forms hexagonal plates that can slip over one another.  Once 600°C/1113°F has been exceeded the crystallisation formed cannot be reversed. It is a gradual process.  It does not become fully crystalline until 935°C - 950°C/1717°F - 1744°F. The crystallisation stops the lubricating effect of the kaolin.  I suspect that on the second full fuse firing these crystals (which contain silicon dioxide) interact with the glass (also silicon dioxide) and stick to the glass.  Although it does not fully combine with the glass.  Why this does not happen in the first firing, I do not know.

The fact that the crystallisation cannot be reversed must be the key as to why kiln wash with kaolin cannot be re-used once fusing temperatures have been reached.  The crystallisation at 800°C/1473°F is nearly complete.  It begins to exhibit the "stickiness" to the glass.  

People who consistently avoid contour and full fuse firings find they can get more than one firing from kiln wash.  This will be because the crystallisation is only partially completed.  But it indicates that repeated tack fusing on kiln wash will ultimately fail as the crystallisation will gradually increase with each firing.  The number of firings possible on one coating of kiln wash will be dependent on temperature and times, among a few other things.

However, at slumping temperatures, it appears the crystal formation is so slow as to have no effect with multiple firings.  Many people experience no difficulty with kiln wash sticking to the glass over many firings, when low temperatures are used.  High temperature slumps will reduce the life of the kiln wash (where life is taken to mean the degree of crystallisation).

 

Picture Credit: Amazon

Avoiding Kaolin

There are of course, ways to avoid kaolin. There is a kiln wash, called Primo Primer that does not have kaolin in it. And you could make your own kiln wash from aluminium hydrate. This is known as slaked alumina in ceramics. It can be used on its own with or without a medium to assist the smooth application of the kiln wash.  One good medium is CMC.

When selecting the aluminium hydrate, be aware there are finer and coarser particles.  The grades used in ceramics are usually coarser than glass people want. But it can be made finer by putting it in a rock tumbler with stainless steel ball bearings. You can run the result through a fine screen. Mix with water to brush on, or sprinkle dry over the shelf. Both these can be re-used. Neither provide as smooth results as when the kiln wash contains kaolin.

Chalk, also known as whiting, is calcium carbonate. This is often used as a separator in vitreous paint firings and some forming operations. It has low solubility in water, so cannot be painted onto shelves or moulds. It needs to be used as a loose or compacted powder. It goes through chemical changes too, making renewal after firing advisable. Above 800°C/1473°F calcium carbonate changes to calcium oxide, or quicklime. This corrosive form is another reason it is disposed of after any higher temperature firings.

Kiln wash and calcium carbonate can be fired many times at low temperatures, because their chemical composition remains relatively stable. Once higher temperatures are used, chemical changes occur. This seems to enable them to stick to the glass or form undesirable compositions. This phenomenon requires removal and re-coating of shelves and moulds after full fuse firings.  Their advantages are ease of use and low cost.

Lead Light Cement

You can make your own lead light cement as the materials are fairly common and safe to use.  I have altered the original recipe through experience.  Too much of mineral spirits dries out the mix so quickly that the linseed oil cracks early in its life.  This results in the possibility of water leaking through the cracked cement.  One third or less of the dryer (mineral spirits) reduces the chance of too rapid drying.  I no longer use a drier at all.  This is my modified recipe.

Recipe
7 parts whiting/chalk
2 parts boiled linseed oil
(measured by volume)
1-2 Tablespoons colorant
This can be lamp black (carbon), black poster paint, concrete colorant powders, or black oil paint in sufficient quantity to give a black or dark gray colour to the otherwise off-white colour of the whiting and linseed oil.  

Do not use water based colorants, such as acrylic paint.  This does not mix with the linseed oil. Instead it forms a collodial mixture that interrupts the formation of the long linseed molecular chains that make it so good as a long term sealant.

The mixed leaded light cement

Method
Add the whiting (reserving about one quarter) to the linseed oil. Mix this well, by hand or with a domestic mixer capable of mixing bread dough. When these are mixed thoroughly, check the consistency. It should be like molasses on a cold morning - barely fluid.  At this point, add the colorant, so you will know the current colour and can adjust to make it darker.

Add more whiting as required to get the consistency you want. Experiment a little to find what suits you best. If you have to deliver the panel quickly, for example, you need to increase the proportion of whiting to make it stiffer. 

Comment
You should make only what you will be using on the current project, as the whiting separates from the linseed oil and sinks to the bottom in only a few days. The commercial cements have emulsifiers to keep the whiting from settling and so extend the life of the product. Since making your own is cheap and quick to make, there is no saving in making a lot.


Lead light cement is a simple, inexpensive sealant for leaded glass that you can make for yourself.

Texture Moulds

Texture moulds are popular but expensive and with limited designs. You can make your own unique ones with only a few items of equipment. 

An example made by someone else

Clay

Various forms of clay can be used. Roll out a flat piece using boards of 8-10mm thick to support the rolling pin and give consistent thickness to the clay. The board underneath should be covered in paper or cloth to make an easy release. I have found that grease-proof paper as used in baking works very well.  It releases easily from the clay.  

Paper clay provides light weight moulds that do not hold a lot of heat, but any standard clay will do the job. There are two approaches to developing the pattern. You can stamp the pattern into the wet clay with any prepared design on a stamp or other textured material. The other is to dry the clay to leather hardness. You can then incise the pattern you desire directly into the clay. Fire to bisque temperatures, and sand to remove any rough areas or undercuts. Kiln washing the mould before use is essential.

Using a patterned roller to impress the design on the clay

Fibre board

Various fibre boards can be used. Ceramic fibre board, Kaiser Lee board, Vermiculite board, insulating ceiling tiles such as Armstrong, and calcium silicate boards can be incised and marked as desired. The advantage to the ceramic fibre, insulating ceiling tiles, and Kaiser Lee boards is that they allow air to pass through the material. Kaiser Lee board of these three provides the easiest surface for incising. Calcium silicate has no fibres, but requires a separator. Ceramic fibre and Armstrong ceiling tiles have fibres, requiring a bit more work to get a smooth surface. Armstrong tiles require a separator, but ceramic fibre boards do not unless you harden them for durability.

Fibre paper

Three millimetre fibre paper gives a easy material for cutting with craft knives or scissors to the design wanted. You can draw through an existing stencil or copy the design with carbon paper. It is not easy to produce designs with lots of detail.  It is quick, does not require separators, but is probably a single use material, unless you use mould hardener and then kiln wash, although it still will be delicate. For large projects, the paper should be fired first to ensure the combustion of the binders do not produce gasses to cause bubbles or fogging.

Loose Material

Sand, whiting, and kiln wash provide easy materials for one-off designs. You can quickly draw the design you want into the flat loose material with your fingers, or tools. You can also use found items to press into the loose material. Place the glass gently on top of the material and fire. If you use sand, you should dust it with kiln wash or aluminium hydrate to ensure the sand does not stick to the glass.

Unique Designs

All of these methods will provide unique designs which will distinguish your work from others.