Is all stainless steel non-magnetic? The answer is “No”.
The scientific answer is of this nature:
“The magnetic behaviour of stainless
steels varies considerably, ranging from the paramagnetic (nonmagnetic) in fully
austenitic grades to hard or permanent magnetic behaviour in the hardened
martensitic grades.
“All austenitic stainless steels are
paramagnetic … [but the magnetic] permeability increases with cold work due to
deformation-induced martensite, a ferromagnetic phase. For certain grades such as types 302 and 304,
the increase in magnetic permeability can be appreciable, resulting in these
grades being weakly ferromagnetic in the heavily cold-worked condition. The susceptibility of a particular grade to becoming
ferromagnetic when heavily cold-worked depends on the stability of the
austenite, which, in turn, depends on chemical composition and homogeneity.”
From https://www.cartech.com/techarticles.aspx?id=1476
The layman’s
explanation is of this nature:
Stainless
Steels are identified by series numbers ranging from 100 to 600. Each series is organised by the alloy and grain
structure. The ones we are interested
are mainly the 300 and 400 series. The
300 series have an austenitic grain structure and the 400 series has a
martensitic structure.
"In the martensitic structure at the atomic level all the
iron atoms are acting as mini magnets aligned in the same direction. Cumulatively they are all adding to the
overall magnetisation of the material, this is known as ferromagnetism. However the addition of nickel disrupts this
regular structure giving it an austenitic nature, so inhibiting the magnetism
of the stainless steel."
This makes the 300 series in its
un-worked state non-magnetic and the 400 series magnetic.
A relatively
general characteristic of the 300 series is the approximate 18% chromium and 8%
nickel (among other alloying elements) content.
There is an interplay between the chromium and nickel content. Chromium allows the stainless steel to have a
magnetic structure, while nickel reduces the magnetic properties of the steel. The 300 series mostly contain enough nickel
to make them non- magnetic or only weakly magnetic.
However, cold
working to form the sheets into vessels or other objects can break down the
non-magnetic structure of the steel by aligning the atoms together. So some highly worked 300 series steels can
become magnetic, although their corrosion resistance does not change. The 316 stainless steel contains higher
amounts of nickel than others and exhibits almost no magnetism in its cold
worked state. But 304 with less nickel
does become mildly magnetic. Another advantage of high nickel content is that
assists the chromium to form a passive surface layer, so resisting corrosion.
This is of assistance to kiln formers, as it reduces spalling. But note that magnetic response is a function
of the metallic structure, not the corrosion resistance formed by the chromium
and nickel (as well other trace metals) content.
The addition
of nickel in the 300 series eases the workability and welding of stainless
steel over the 400 series. You are more likely to find the 300 series in worked
vessels and other kitchen equipment. But
the stainless steel knives are much more likely to be of the 400 series. Both of these stainless steels have a high degree
of corrosion resistance.