Firing silicone mastic

Several people have asked over time about the consequences of firing glass with some silicone mastic (or caulking) still attached to the glass. 

I can say with confidence that it does not break the glass.

I can also say, that it really is not a good idea.  Take as much as possible off with knives, then use silicone disolvers to remove the remainder.  These photos show the results of firing silicone residue.

Where there were pieces of silicone, a divot appeared with the black combustion product from the mastic/caulking.  Where there were strips of silicone, a small valley occurred.  The smallest amount of silicone appeared as a dark divot in the glass.  

It is possible to remove the silicone residue with sandblasting.  Other abrasive methods are possible, but much more time consuming.   Once the silicone has been sandblasted away, the glass needs to be cleaned of all the dusts, and covered with a fine layer of fine frit, or if prefered, powder.  But I find fine frit works better, although it requires a full fuse to form a smooth surface.

Silicone Removal

Removing silicone residues from glass is difficult as silicone combines with the surface molecules of the glass.

The best advice seems to use a very sharp flat blade similar to a paint scraper. There is a tool which holds razor blades or Stanley knife blades which is suitable. Keep the blade as near parallel to the glass surface as possible. Take thin slices of the silicone away at each pass. Keep the blade free from nicks. Change the blade frequently. You may be able to remove almost all the silicone, depending on the smoothness of the glass surface, in this way.

However when you have removed as much as possible by the mechanical means, you may need to use a chemical process to get rid of the remaining silicone. Silicone dissolvers are available from most do-it-yourself shops. Make sure you use them in accordance with the instructions as they can be mildly toxic.