Wire in glass

 

The cracks around the wire imbedded in the glass in the above image are not incompatibility cracks. They do not surround the square piece that traps the wire into the glass. These are from differential expansion/contraction stress between the wire and the glass. 

 

Picture credit: Charmaine Maw

This picture shows the stress that a single strand of wire will induce in glass (the bright light around the wire).  Wire is never going to have similar characteristics to the glass, so the glass must be strong enough to contain the resulting stress.  Anything that increases the mass of the wire, such as twisting or spirals, will increase the stress. 

 

Kanthal and nichrome wires are best as included wire hangers. They are designed for high temperature work and so do not weaken from the heat. This means that high temperature wire as thin as 0.5mm/22 gauge can hold a lot of weight.  Much greater weight than is used in most glass objects to be hung rather than fixed.

Keep the wire as a single strand and as thin as possible, consistent with sufficient strength.  Hammering wire flat can also help reduce the stress by thinning it.

Profile

A sharp tacked piece needs to be fired as though thicker. This example is a single layer base and a square of glass to trap the wire fired to a sharp tack.  It needs to be fired as though 2.5 times the thickest part - 15mm.  A rounded tack fuse of the same layup would need to be fired as for 12mm.

Layup

The use of wire in glass needs to consider how the air will escape from around the wire.  Yes, if the wire exits the glass, there is a channel for it to dissipate.  But air tends to collect along the length of the wire.  If the wire is fully enclosed in the glass, the layup must accommodate the need for air escape routes.  This might be with a fine layer of powder, design elements, chips of glass to hold the outer edges of the glass up for longer, or other devices.

 

Scheduling

The example shown at the start of this blog, is a sharp tack and needed the 2.5 times scheduling.  That probably would have avoided the crack in the single layer base.  That single layer cools faster than the wire with the added piece of glass.  A bubble squeeze is a good idea, even though it would not normally be considered.  This gives the best chance of reducing the bubbles that form around the inclusion.

 

You need to be careful about increasing the ramp rate until the glass has passed out of the brittle phase.  This is about 540˚C/1005˚F. The increase in the ramp rate during the brittle phase may cause cracks. It is, of course, more likely to occur during cooling because the metal will be contracting more than the glass during the brittle phase.  This contrast in contraction rates induces stress that may be great enough to crack or break the glass.

 

 

Element Coatings

You will notice that after the initial few firings of your new kiln that a grey residue forms on the elements.  This is a protective layer.  It is a surface oxidisation that protects the underlying metal from further corrosion. 

Kiln elements are generally made from Kanthal or Nichrome wire. 

Kanthal wire is an alloy of iron, chrome and aluminium.  The aluminium oxidises to provide a protective layer of aluminium oxide.

Nichrome wire is an alloy of nickel (the main element) and chromium in various proportions for different applications. It is the most common heating element for high temperatures. The chrome forms a protective layer of chromium oxide at red hot temperatures.  But once heated, it becomes brittle, so it can be manipulated only when hot.

This layer is not a chemical reaction to the things you put into your kiln.  It is the necessary protective layer to give long life elements. This coating should not fall from the elements unless it is disturbed by bending, abrasion or impact. If it does, check for damage to the elements and look closely for any break.

Kanthal vs. Nichrome

Both Kanthal and Nichrome are high temperature wires.

Kanthal

Kanthal is the trademark (owned by Sandvik) for a range of iron-chromium-aluminium (FeCrAl) alloys used in resistance and high-temperature applications. The first Kanthal alloy was developed by Hans von Kantzow in Sweden.

“Kanthal alloys consist of mainly iron, chromium (20–30%) and aluminium (4–7.5 %). The alloys are known for their ability to withstand high temperatures and having intermediate electric resistance.”  So, it is often used in kiln elements.

“Kanthal forms a protective layer of aluminium oxide (alumina) when fired.”  This layer resists further oxidisation of the elements when firing.  Aluminium oxide is an electrical insulator with a relatively high thermal conductivity.  Ordinary Kanthal has a melting point of 1,500°C.

“Kanthal is used in heating elements due to its flexibility, durability and tensile strength.” Its uses are widespread, with it being used in home appliances and industrial applications as well as glass and ceramic kilns.  As an aside, it is being used in electronic cigarettes as a heating coil as it can withstand the temperatures needed in this application.

Based on Wikipedia https://en.wikipedia.org/wiki/Kanthal_(alloy) and other sources.

Nichrome

Nichrome is an alloy of various amount of nickel, chromium, and often iron.  The most common usage is as resistance wire.  It was patented in 1905.

“A common Nichrome alloy is 80% nickel and 20% chromium, by mass, but there are many other combinations of metals for various applications.”  Nichrome is silvery-grey, corrosion-resistant, and has a high melting point of about 1,400°C.

It has a low manufacturing cost, it is strong, has good ductility, resists oxidation and is stable at high temperatures.  Typically, nichrome is wound in coils to a certain electrical resistance, and when current is passed through it, the resistance produces heat.  This is probably the most common material used for kiln elements.

When heated to red hot temperatures, the nichrome wire develops an outer layer of chromium oxide, which is stable in air, being mostly impervious to oxygen.  This protects the heating element from further oxidation.  However, once heated the nichrome wire becomes brittle and must be heated to red hot before bending.

Based on Wikipedia https://en.wikipedia.org/wiki/Nichrome and other sources.