Hazards of Flux Fumes

Note:  These health risks are those associated with industrial exposure – frequent and for extended periods.  They do not apply directly to occasional and shorter periods of exposure.

Risks are assessed as acute and chronic.  Acute means immediate reaction.  Chronic means the effects are cumulative and may take years to appear.
 

Composition of Flux

The major components of commercial flux are varying combinations and proportions of zinc chloride (or ammonium chloride), hydrochloric acid, phosphoric acid, citric acid, and hydrobromic acid.  It comes in many forms and many brand names.  It is important to use water soluble flux in stained glass work to enable thorough cleaning.
 
 

 

Zinc Chloride Risks

Zinc chloride inhalation from smoke screen generators or smoke bombs may cause transient cough, sore throat, hoarseness, a metallic taste, and chest pain.  Exposure to high zinc chloride concentrations produces a chemical pneumonitis with marked dyspnoea, a productive cough, fever, chest pain and cyanosis. Pneumothorax and the adult respiratory distress syndrome (ARDS) have been reported. Fatalities have occurred….
http://www.inchem.org/documents/ukpids/ukpids/ukpid86.htm#:~:text=Toxicity%20Zinc%20chloride%20is%20corrosive,anorexia%2C%20fatigue%20and%20weight%20loss.
 

Ammonium Chloride Risks

Exposure to Ammonium Chloride is moderately hazardous, causing irritation, shortness of breath, cough, nausea, and headache. Most exposure is a result of contact with the fume form of this chemical (Ammonium Muriate Fume and Sal Ammoniac Fume), which is a finely divided particulate dispersed in the air. The fumes are capable of causing severe eye irritation. Consistent exposure can cause an asthma-like allergy or affect kidney function.
 
In the event of accidental contact, get immediate medical attention and follow these first aid measures:
·        Skin Contact: Immediately flush skin with water and disinfectant soap and use an emollient on irritated area.
·        Eye Contact: Rinse eye(s) with water for at least 15-20 minutes. Protect unexposed eye.
·        Ingestion: Rinse mouth thoroughly with water. Do NOT induce vomiting.
·        Inhalation: Move to fresh air and administer artificial respiration if needed.
https://www.msdsonline.com/2017/05/05/chemical-spotlight-ammonium-chloride/#:~:text=Exposure%20to%20Ammonium%20Chloride%20is,particulate%20dispersed%20in%20the%20air.
 
 

Hydrochloric Acid Risks

Hydrochloric acid is corrosive to the eyes, skin, and mucous membranes.  Acute (short-term) inhalation exposure may cause eye, nose, and respiratory tract irritation and inflammation and pulmonary edema in humans.  Acute oral exposure may cause corrosion of the mucous membranes, oesophagus, and stomach and dermal contact may produce severe burns, ulceration, and scarring in humans.
 

Acute Effects: 

Hydrochloric acid is corrosive to the eyes, skin, and mucous membranes.  Acute inhalation exposure may cause coughing, hoarseness, inflammation and ulceration of the respiratory tract, chest pain, and pulmonary edema in humans.  Acute oral exposure may cause corrosion of the mucous membranes, oesophagus, and stomach, with nausea, vomiting, and diarrhoea reported in humans.  [Skin] contact may produce severe burns, ulceration, and scarring…. Acute animal tests in rats, mice, and rabbits, have demonstrated hydrochloric acid to have moderate to high acute toxicity from inhalation and moderate acute toxicity from oral exposure.

 

Chronic Effects: 

(Non cancer): Chronic occupational exposure to hydrochloric acid has been reported to cause gastritis, chronic bronchitis, dermatitis, and photosensitization in workers.  Prolonged exposure to low concentrations may also cause dental discoloration and erosion.  Chronic inhalation exposure caused hyperplasia of the nasal mucosa, larynx, and trachea and lesions in the nasal cavity in rats.  The Reference Concentration (RfC) for hydrochloric acid is 0.02 milligrams per cubic meter (mg/m 3) … The RfC is an estimate … of a continuous inhalation exposure to the human population (including sensitive subgroups) that is likely to be without appreciable risk of deleterious noncancer effects during a lifetime.  It is not a direct estimator of risk but rather a reference point to gauge the potential effects.  At exposures increasingly greater than the RfC, the potential for adverse health effects increases.  Lifetime exposure above the RfC does not imply that an adverse health effect would necessarily occur.
https://www.epa.gov/sites/production/files/2016-09/documents/hydrochloric-acid.pdf
 

 
Phosphoric Acid Risks

Phosphoric acid can be very hazardous in the case of skin contact, eye contact, and ingestion. It can also cause irritation if vapours are inhaled. This chemical can cause damage to the skin, eyes, mouth, and respiratory tract. Because of the potential hazards posed by this chemical, it is important to use care when handling it.
 
Repeated or prolonged exposure to phosphoric acid mist can lead to chronic eye irritation, severe skin irritation, or prolonged respiratory tract issues.  In case of accidental exposure to phosphoric acid, follow these first aid guidelines:

Inhalation — Seek fresh air and immediate medical attention.

Eye Contact — Remove contact lenses if present. Immediately flush eyes with plenty of water for at least 15 minutes and get medical attention.

Skin Contact — Wash skin with soap and water. Cover any irritated skin with an emollient. Seek medical attention. 

Ingestion — Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Seek medical attention if any adverse health symptoms occur.
https://www.msdsonline.com/2015/06/17/phosphoric-acid-safety-tips/
 
  

Citric Acid

Citric acid can be a minor skin irritant, causing itchy skin and even minor burns to those that are sensitive to it. Hands should be washed immediately if citric acid comes into contact with bare skin. Protective gloves should be worn during handling to avoid any accidental contact. The acid can also irritate the walls of the throat if ingested or burn the lining of your stomach if ingested in large quantities.
 
Eye Irritation - Citric acid is a severe eye irritant. Accidental contact with the eyes can occur … by touching the eyes after the acid has contacted the fingertips. …  Protective eyewear should be worn when working with citric acid under laboratory conditions. Eyes should be flushed with water immediately if they happen to come in contact with the acid.
https://sciencing.com/hazards-citric-acid-8165149.html

Remember that this irritation is equivalent to squirting lemon juice into your eye.  It is not a chronic risk.
 

Hydrobromic Acid (HBr)

Hydrobromic acid and hydrogen bromide gas are highly corrosive substances that can cause severe burns upon contact with all body tissues. The aqueous acid and gas are strong eye irritants and [tear producers]. Contact of concentrated hydrobromic acid or concentrated HBr vapor with the eyes may cause severe injury, resulting in permanent impairment of vision and possible blindness. Skin contact with the acid or HBr gas can produce severe burns. Ingestion can lead to severe burns of the mouth, throat, and gastrointestinal system and can be fatal. Inhalation of HBr gas can cause extreme irritation and injury to the upper respiratory tract and lungs, and exposure to high concentrations may cause death. … Hydrogen bromide has not been found to be carcinogenic or to show reproductive or developmental toxicity in humans.
https://web.stanford.edu/dept/EHS/cgi-bin/lcst/lcss/lcss47.html#:~:text=The%20aqueous%20acid%20and%20gas,gas%20can%20produce%20severe%20burns.
 
 
 

Precautions to be taken by glass workers

The risks outlined above are related to dealing with concentrated amounts of the materials in industrial settings.  Risk levels are much reduced in the craft setting.  The risks are mainly centred on breathing and eye exposure. 
 
It is important to wear masks of the quality that will deal with inorganic fumes.  In Europe these are designated as FFP2.  In general masks rated at N95, P95, or R95 are the level required for filtering out 95% of particles that are larger than 3microns.  Dust masks are not sufficient protection. 
 

Usually overlooked is eye protection.  The risks outlined here show that risks to eyes are equal to - or in some cases greater than – respiratory ones.  Eye protection is as important as breathing filters.  To fully protect the eyes, goggles of some sort are the minimum requirement.  Glasses will not be sufficient to prevent fumes reaching eyes.

 
For a “one stop solution” a full-face mask may be the simplest solution.  The filters on these are long lasting and replaceable.  They can be put on as one unit and are available in various face sizes.
 

At soldering temperatures, there are no lead or tin fumes created.  It is the fumes from the flux that are the risks in soldering.  These risks are small and can be dealt with by using adequate ventilation, masks, and goggles.

Oxidisation of Foil

Often, life intervenes between foiling and soldering.  This frequently results in the foil not accepting the solder very well, because of the mild tarnish that has occurred in the meantime.

It is a good idea to clean the foil of any possible corrosion before soldering when there has been an interval between the two processes. It is enough to clean foil with a mild abrasive such as a foam-backed scrubber from the dish washing, or fine steel wool.  I prefer the scrubber as it does not introduce another metal.  

Some people prefer a vinegar and salt solution to apply to the tarnished foil.  I am concerned about the introduction of an acid into the process causing further problems later.  I don't recommend this method of cleaning.

I then coat the exposed foil with a film of paste flux to protect from further tarnish. This acts better than any loose covering of cloth or plastic to protect from oxidation.  The purpose of flux is to both provide a "wetting" agent for the foil to accept the solder,  and to prevent oxidisation. Liquid flux cannot provide protection, once dry,  from the copper tarnishing.  I prefer the use of paste flux to reduce boiling of flux and to keep the copper free from corrosion.  The paste flux will not indefinitely prevent oxidisation, but will do so for a week or two.

Soldering Lead Came

Soldering lead came is different from soldering electronics or copper foil. For electronic soldering less heat is needed, cleanliness is all important, suitable flux is required, and the iron is held differently, among other things.

Soldering lead came The lead needs to be clean and bright to start with. If it's fairly new lead it should be solder-able without more than a scrubbing of the joints with a brass wire brush. However, if the lead is dull and oxidized, you should scrape the lead in the area to be soldered with a nail, the blade of a lead knife or other sharp edged tool until the bright metal is revealed.

an example of paste flux

Example of a tallow stick.  It has the appearance of a candle, but without the wick.

Example of the application of tallow to a joint

Then the flux can be applied.  Paste flux or tallow works best as neither flows in its cold state.  This means that you can flux the whole panel at one time without the liquid flowing away or drying.  Once the whole panel is fluxed, you do not need to stop during the soldering process.

Example of a gas powered soldering iron. The flat face of the soldering bolt is held in full contact with the joint.

An electric soldering iron is held over-handed (as you would a bread knife) in order to get the handle low enough to have the tip flat on the lead. This will be a 15 to 20 degree elevation from the horizontal. Allow the weight of the soldering iron to do the work for you. 

Let it rest on the joint after you apply the solder between the lead and the iron. In order to heat both pieces of lead you may have to rock the tip slightly to contact all leads being soldered. Take the solder away from the iron so it doesn't become attached to the joint. As soon as the solder spreads, lift the iron straight up. This process will take only a few seconds, much less than 5.

Example of smooth flat solder joints.

Avoid "painting" or dragging the iron across the joint. The object is to have a shiny, smooth, slightly rounded solder joint. Moving the iron and solder around does two things.  It makes for a weak joint as the solder does not have the chance to become stable and so forms a "pasty" joint.  Moving the iron around during the soldering of the joint often provides sharp points where the iron was moved quickly off the join. There should be no points sticking up from the solder joint. If a solder joint is not satisfactory you can re-flux and re-heat. Don't apply too much solder. It's easier to add more solder than to remove excess.

The Purpose of Flux

The primary purpose of flux is to prevent oxidation of the base and filler materials in the short time between cleaning and soldering. Tin-lead solder, for example, attaches very well to copper, but poorly to the various oxides of copper that form quickly at soldering temperatures. This applies to lead and brass too.

Flux is a substance that is nearly inert at room temperature, but it becomes strongly reducing at elevated temperatures, preventing the formation of metal oxides. Secondarily, flux acts as a wetting agent in soldering processes for lead, copper and brass.

Without flux the solder does not firmly attach to the lead or copper foil and often forms sharp peaks.


See also
Flux, an introduction
Fluxes, a description
The Purpose of flux
The action of fluxes

Soldering fluxes

The Action of Fluxes

All common untreated metals and metal alloys (including solders) are subject to an environmental attack in which their bare surfaces become covered with a non-metallic film, commonly referred to as tarnish. This tarnish layer consists of oxides, sulfides, carbonates, or other corrosion products and is an effective insulating barrier that will prevent any direct contact with the clean metal surface which lies beneath. When metal parts are joined together by soldering, a metallic continuity is established as a result of the interface between the solder and the surfaces of the two metals. As long as the tarnish layer remains, the solder and metal interface cannot take place, because without being able to make direct contact it is impossible to effectively wet the metals surface with solder.

The surface tarnishes that form on metal are generally not soluble in (and cannot be removed by) most conventional cleaning solvents. They must, therefore be acted upon chemically [or mechanically] in order to be removed. The required chemical reaction is most often accomplished by the use of soldering fluxes. These soldering fluxes will displace the atmospheric gas layer on the metal’s surface and upon heating will chemically react to remove the tarnish layer from the fluxed metals and maintain the clean metal surface throughout the soldering process.

Chemical reactions
The chemical reaction that is required will usually be one of two basic types. It can be a reaction where the tarnish and flux combine forming a third compound that is soluble in either the flux or its carrier.

An example of this type of reaction takes place between water-white rosin and copper oxides. Water-white rosin, when used as a flux is usually in an isopropyl alcohol carrier and consists mainly of abietic acid and other isomeric diterpene acids that are soluble in several organic solvents. When applied to an oxidized copper surface and heated, the copper oxides will combine with the abietic acid forming a copper abiet (which mixes easily with the un-reacted rosin) leaving a clean metallic surface for solder wetting. The hot molten solder displaces the rosin flux and the copper abiet, which can then be removed by conventional cleaning methods.

Another type of reaction is one that causes the tarnish film, or oxidized layer to return to its original metallic state restoring the metals clean surface.

An example of this type of reaction takes place when soldering under a blanket of heated hydrogen. At elevated temperatures (the temperature that is required for the intended reaction to take place is unique to each type of base metal) the hydrogen removes the oxides from the surface, forming water and restoring the metallic surface, which the solder will then wet. There are several other variations and combinations that are based on these two types of reactions.

Acids commonly in fluxes

Flux as a temporary protective coating
Once the desired chemical reaction has taken place (lifting or dissolving the tarnish layer) the fluxing agent must provide a protective coating on the cleaned metal surface until it is displaced by the molten solder. This is due to the elevated temperatures required for soldering causing the increased likelihood that the metal’s surface may rapidly re-oxidize if not properly coated. Any compound that can be used to create one of the required types of chemical reactions, under the operating conditions necessary for soldering, might be considered for use as a fluxing material. However, most organic and inorganic compounds will not hold up under the high temperature conditions that are required for proper soldering. That is why one of the more important considerations is a compound's thermal stability, or its ability to withstand the high temperatures that are required for soldering without burning, breaking down, or evaporating.

When evaluating all of the requirements necessary for a compound to be considered as a fluxing agent, it is important to consider the various soldering methods, techniques and processes available and the wide range of materials and temperatures they may require. A certain flux may perform well on a specific surface using one method of soldering and yet not be at all suitable for that same surface using a different soldering method. When in doubt it never hurts to check with the flux, or solder manufacturer for recommendations.

Courtesy of American Beauty Tools


See also:
Flux, an introduction
Fluxes, a description
The Purpose of flux
The action of fluxes
Soldering fluxes

Flux

Flux is a material that provides a “wetting” action between the metal (lead or copper in our case) and the solder.


There are various types of flux. Some are of more use in some circumstances than others. Among them are:

Tallow
This normally comes in a candle-like stick. It is made from rendered animal fat. Although this may put some vegetarians off, it is one of the best fluxes for leaded glass work and will work for copper foil, but is not generally preferred.  It is relatively natural, does not contain chemicals, and does not require re-application if left for a while. Over generous application does not produce any problems during the soldering. It just leaves more solidified tallow to clean after soldering. The cleaning normally requires a mild abrasive such as a brass or fibreglass brush to get the cooled tallow off the piece.

 




Oleic acid and other safety fluxes
Many of the safety fluxes are made of oleic acid (sometimes called stearin oil). These fluxes do not produce chemical fumes in the soldering process. They are easy to clean up with detergents and warm water. Safety fluxes require re-application if left to dry, as they are only effective while wet. Putting too much on leads to boiling off the liquid, making holes in the solder joint or line.

An example only.  There are many water soluble paste fluxes available

Chemical Paste fluxes
These fluxes come in a variety of compositions. You need to be careful about choosing, as some are very difficult to clean off the glass or solder line or joint. They do produce chemical fumes, so a fume mask is advisable while using this kind of flux. The paste does not require re-application if left, so the whole piece can be fluxed at once.

Acid fluxes
Acid fluxes such as the kind that is in the core of plumbers solder are intended to clean the joint at the same time as acting as the wetting agent. These are not recommended for stained glass work as they can affect the glass surfaces, especially irridised glass. They do produce fumes that require the user to have on a fume mask while soldering. The ease of cleaning relates to the particular composition of the flux, so testing samples is required before application.

See also:
Flux, an introduction
Fluxes, a description
The Purpose of flux
The action of fluxes
Soldering fluxes

Flux, an Introduction

Flux is a key contributor to most soldering applications. It is a compound that is used to lift tarnish films from a metals surface, keep the surface clean during the soldering process, and aid in the wetting and spreading action of the solder. There are many different types and brands of flux available on the market; check with the manufacturer or reseller of your flux to ensure that it is appropriate for your application, taking into consideration both the solder being used and the two metals involved in the process. Although there are many types of flux available, each will include two basic parts, chemicals and solvents.

an example of paste flux

The chemical part includes the active portion, while the solvent is the carrying agent. The flux does not become a part of the soldered joint, but retains the captured oxides and lies inert on the joints finished surface until properly removed. It is usually the solvent that determines the cleaning method required to remove the remaining residue after the soldering is completed. 

It should be noted that while flux is used to remove the tarnish film from a metal's surface, it will not (and should not be expected to) remove paint, grease, varnish, dirt or other types of inert matter. A thorough cleaning of the metal's surface is necessary to remove these types of contaminates. This will greatly improve the fluxing efficiency and also aid in the soldering methods and techniques being used.

Courtesy of American Beauty Tools


See also:
Flux, an introduction
Fluxes, a description
The Purpose of flux
The action of fluxes
Soldering fluxes

Copper inclusions

Inclusions of metals can be achieved with care.  Copper is a very good metal, as it is soft, even though its expansion characteristics are very different from glass.  This note provides some things you might consider when planning to include copper in your fused pieces.

The copper sheet should be stiff, but not thick. If the metal can be incised with a scribe and maintain that through gentle burnishing, it is suitably thick. The usual problem is that the copper is too thick rather than too thin.  Copper leaf can be very faint if a single layer is used.  Placing several layers of leaf improves the colour, but often provides wrinkles.  In summary, the requirement is to get a thickness of copper that will retain its structure, but not be so thick and stiff as to hold the glass up during the fusing process.  

Do not use the copper foil as used for stained glass applications. The adhesive backing produces a black colour from the adhesive and many bubbles -  sometimes a single large one.

Copper can provide several colours.

Copper sheet normally turns burgundy colour when oxidised.  This means that there is enough air reaching the copper to oxidise it to deep copper red.  This most normally happens, because a lot of air can contact the metal during the extensive bubble squeeze usually given to inclusions.

To keep the copper colour, clean the metal well metal well with steel wool or a pot scrubber. If you use steel wool, wash and polish dry the metal before fusing.  Reduction of air contact with the metal helps to retain the copper colour.  There are two methods I have used.  Addition of a glass flux like borax or other devitrification spray will help prevent the air getting to the surface.  Another method of avoiding oxidisation, is to cover the copper with clear powdered frit, as well as the surrounding glass.

In certain circumstances you can get the blue green verdigris typical of copper in the environment.  This is an extent of oxidisation that is between the clean copper coloured metal and the burgundy colour of extensive oxidisation.  The key seems to be be a combination of restricted air supply, shorter bubble squeezes and lower temperatures.  Experimentation is required to achieve this consistently.


The spaces under and over the copper give the opportunity for bubbles to form. 

This means that the copper needs to be as flat as possible for one thing.  Burnishing the copper can have a good effect on reducing the undulations in the copper.  Thinner copper is easier to make flat than thicker.  If you can stamp a shape from the copper with a stamper designed for card making, it is a good indication that it will burnish flat.  Thicker copper sheet holds the glass up long enough in the temperature rise during the bubble squeeze to retain air around the metal.  This remains the case even after burnishing to be as flat as possible.

The second element that can help to reduce bubbles around the copper is to sprinkle clear powder over the copper sheet once in place on the glass.  The spread of the powder over the glass assists in giving places for the air between layers to escape.

These two things combined with a long slow squeeze can reduce the amount of bubbles you get.  It cannot totally eliminate them.

Of course, a longer bubble squeeze allows air to be in contact with the copper and promotes the change to a blue green or burgundy colour.

Composition of Glass

Glass can do most anything. From bottles to spacecraft windows, glass products include three types of materials:

• Formers are the basic ingredients. Any chemical compound that can be melted and cooled into a glass is a former. (With enough heat, 100% of the earth's crust could be made into glass.)
• Fluxes help formers to melt at lower temperatures.
• Stabilisers combine with formers and fluxes to keep the finished glass from dissolving, crumbling, or falling apart.

Chemical composition determines what a glass can do. There are many thousands of glass compositions and new ones are being developed every day.

Formers
Most commercial glass is made with sand that contains the most common former, Silica. Other formers include:

• Anhydrous Boric Acid
• Anhydrous Phosphoric Acid

Fluxes
But melting sand by itself is too expensive because of the high temperatures required (about 1850°C, or 3360°F). So fluxes are required. Fluxes let the former melt more readily and at lower temperatures (1300°C, or 2370°F). These include:

• Soda Ash
• Potash
• Lithium Carbonate

Stabilisers
Fluxes also make the glass chemically unstable, liable to dissolve in water or form unwanted crystals. So stabilizers need to be added. Stabilisers are added to make the glass uniform and keep its special structure intact. These include:

• Limestone
• Litharge
• Alumina
• Magnesia
• Barium Carbonate
• Strontium Carbonate
• Zinc Oxide
• Zirconia

Based on an article from the Corning Museum of Glass

Mica

What it is

Mica is widely distributed throughout the world and occurs in igneous, metamorphic and sedimentary rocks. Mica is similar to granite in its crystalline composition.  The nearly perfect cleavage, which is the most prominent characteristic of mica, is explained by the hexagonal sheet-like arrangement of its atoms.

Mica can be composed of a variety of minerals giving various colours and transparency. Purple, rosy, silver and grey colours come from the mineral called lepidolite.  

Dark green, brown and black come from biotite.  

Yellowish-brown, green and white come from phlogopite.  

Colourless and transparent micas are called muscovite.  

All these have a pearly vitreous lustre.

The melting point of mica depends on its exact composition, but ranges from 700⁰C to 1000⁰C.

Glass has a specific gravity of about 2.5, and mica ranges from 2.8-3.1, so it is slightly heavier than glass.

Tips on uses of mica powder and flakes

The naturally occurring colours are largely impervious to kiln forming temperatures.  Other added colours have various resistances to the heat of fusing. This is determined by the temperatures used to apply the colour to the mica.  Cosmetic mica is coloured at low temperatures and will not survive kiln forming with their colour in tact.

Mica does not combine with glass, but is encased by glass as it sinks into the glass surface.  You can use various fluxes to soften the surface of the glass.  Borax is one of those.  The cleaving of the mica results in only the layer in contact with the glass sticking.  The upper layers brush off.  This applies to both powder and flakes. One solution is to fire with mica on top in the initial firing and then cap for the final one.

When encasing mica exercise caution. Micas flakes must be applied thinly, as air is easily trapped between layers which leads to large bubbles from between layers of glass.  This is the result of the shearing of layers of the flakes allowing air between layers.  Although powdered mica is less likely to create large bubbles, air bubbles are often created for the same reason.  This is the reason it is most often recommended to fire the mica on top. 

Of course, one use of the mica to make complicated designs is to cover the whole area and fuse.  Then sandblast a design removing the mica from areas of the glass. You can then fire polish, or cap and re-fire to seal the mica.

Mica safety

MSDS for mica only mentions the inhalation of the dust as a risk. Mica is resistant to acid attack and is largely inert.  Inhalation of the dust is a (low level) risk.  Any significant health and safety problems relate to the coloured coatings.

Borax Characteristics

Borax is a glass making flux used to reduce the melting temperature of glass. 

It is almost colourless - grey, white, or yellowish; seldom bluish or greenish; and colourless in transmitted light.

The chemical composition of Borax is:  Na₂(B₄O₅)(OH)₄ · 8H₂O

It has a hardness rating of 2 – 2.5, about half that of glass at approximately 5.5.

The melting point is 878°C. At this temperature borax dissolves numerous metal oxides. In spite of this high melting temperature, it acts as a flux reducing the softening point at the surface of the glass at kiln forming temperatures.

The specific gravity of borax is approximately 1.7, considerably ligther than glass at ca.2.5.

Borax is sparingly soluble in cold water, although readily soluble in boiling water. It is insoluble in ethanol.

Description of devitrification
Temperature range

Devitrification spray

Oxidized Copper Foiled Pieces

If copper foiled pieces sit out for any length of time after foiling they will oxidize. This means that the solder will not stick to the foil, as it requires a clean surface to attach to.

Clean the foiled pieces with fine steel wool, pot scrubber or flexible mild abrasive. Make sure you do not damage the foil or pull it up from the glass during this process. It is likely that the adhesive holding the foil to the glass is not as strong as it once was.

I do not recommend using a stronger flux to overcome the oxidisation, as this is often highly acidic and may damage the glass.

Once cleaned, you can flux the foil and proceed as normal.

Liquid Flux Use

Liquid Flux

It is important to put the minimum amount of liquid solder on the copperfoil seams. A surplus of liquid flux will bubble and splatter, leaving holes in the solder bead. Cutting your flux brush about in half, at a slight angle will reduce the amount of flux on your brush and ease the application.

Pour a small amount of flux, just enough for the task at hand, into a small container. Don't pour the leftovers back into the flux jar, it will contaminate the rest. Do not use the lid of your current flux jar, as it should be sealed at all times so it won't become sticky by evaporating.

When finished soldering, wash off the flux by washing it with warm water and a very little dish washing liquid and a soft sponge, then rinse with water. Clean your flux off right away after you finish soldering. Flux will oxidize your solder seams if left over time. It also becomes more difficult to remove when it has begun to dry.


See also:
Flux, an introduction
Fluxes, a description
The Purpose of flux
The action of fluxes
Soldering fluxes

Soldering Fluxes

Fluxes fall into 2 categories: rosin based, and so called water-soluble

1. Rosin Fluxes
Rosin based fluxes are made from rosin which is extracted from pine sap. The purified product is known as "Water White Rosin". The active ingredient is an organic acid, abietic acid and may contain homologs such as dehydro abietic acid and leviopmaric acid.

In addition to rosin other activators may be present at different levels to increase the ability to clean and deoxidise. Activators are compounds that decompose at soldering temperatures yielding ammonia or hydrochloric acid in the process. Flux activity is categorised as R (rosin only), RMA (rosin mildly activated) and RA (rosin activated). A low boiling solvent such as isopropanol is used as the vehicle so they are flammable.

Type R containing only rosin is the least active and is recommended for surfaces very clean to start with. It leaves virtually no residue behind. Thus this is the best rosin based flux for copper foil and lead cames.

Type RMA contains a small amount of additional activator to enhance cleaning and deoxidisation leaving only a minimum amount of inert residue behind. A characteristic of RMA fluxes is that the remaining residue be non-corrosive, tack free, and exhibit a high degree of freedom from ionic contamination after cleaning. These fluxes are acceptable, but more difficult to clean. They are not acceptable for conservation work.

Type RA are most active of the rosin fluxes, and leave the most residue, however the residues can be removed with appropriate flux cleaners. The residues are really difficult to remove in decorative glass work circumstances and should not be used.

2. Water Soluble Fluxes
These are called water-soluble, as the residue left after soldering is water soluble, although the flux is not. The so-called water-soluble fluxes are divided into two categories, organic and inorganic, based on composition. 

Organic fluxes are more active than RA rosin, and inorganic are the most active of all. Both of these are the best of all fluxes to use in decorative glass work, as the residues are water soluble making clean-up easier, and they are more effective in wetting and keeping the copper and lead free from oxidisation at soldering temperatures.


See Also:
Flux, an introduction
Fluxes, a description
The Purpose of flux
The action of fluxes

Soldering fluxes