Chemical Compositions of Glass

Nearly all commercial glasses fall into one of six basic categories or types. These categories are based on chemical composition. Within each type, except for fused silica, there are numerous distinct compositions.

Soda-lime glass is the most common (90% of glass made), and least expensive form of glass. It usually contains 60-75% silica, 12-18% soda, 5-12% lime. Resistance to high temperatures and sudden changes of temperature are not good and resistance to corrosive chemicals is only fair.

Lead glass has a high percentage of lead oxide (at least 20% of the batch by weight). It is relatively soft, and its refractive index gives a brilliance that may be exploited by cutting. It is more expensive than soda-lime glass and is favoured for electrical applications because of its excellent electrical insulating properties. Thermometer tubing and art glass are also made from lead-alkali glass, commonly called lead glass. This glass will not withstand high temperatures or sudden changes in temperature.

Borosilicate glass is any silicate glass having at least 5% of boric oxide in its composition. It has high resistance to temperature change and chemical corrosion. Not quite as convenient to fabricate as either lime or lead glass. Borosilicate's cost is moderate when measured against its usefulness. Pipelines, light bulbs, photochromic glasses, sealed-beam headlights, laboratory ware, and bake ware are examples of borosilicate products.

Aluminosilicate glass has aluminum oxide in its composition. It is similar to borosilicate glass but it has greater chemical durability and can withstand higher operating temperatures. Compared to borosilicate, aluminosilicates are more difficult to fabricate. When coated with an electrically conductive film, aluminosilicate glass is used as resistors for electronic circuitry.

Ninety-six percent silica glass is a borosilicate glass, melted and formed by conventional means, then processed to remove almost all the non-silicate elements from the piece. By reheating to 1200°C the resulting pores are consolidated. This glass is resistant to heat shock up to 900°C.

Fused silica glass is pure silicon dioxide in the non-crystalline state. It is very difficult to fabricate, so it is the most expensive of all glasses. It can sustain operating temperatures up to 1200°C for short periods.


The full article is available from the Corning Museum of Glass