Fast Ramps - Kiln Forming Myths 26

Firing AFAP harms your kiln.

This may be a hangover from the time when ceramic kilns were being used commonly.  There certainly is a tradition of this kind in ceramics practice.  However, nowadays we are firing in kilns with light weight bricks or fibre, or a combination of the two, making this less relevant.

The light weight bricks are much less subject to temperature shock than the dense ones.  Fibre is completely unaffected by rapid changes in temperature.

Firing as fast as possible is much more likely to damage the glass you have in the kiln than the kiln itself.  It is also likely to have over runs in temperature.  The controllers compare the actual increase in temperature with that requested by the schedule.  It takes time for the controller to “learn” the rate of advance being achieved within the kiln.  On fast rises in temperature, it does not have the capacity to stop the input of energy early enough to prevent the kiln temperature rising beyond that which is programmed.  This can lead to unexpected and unexplained results (unless you think about the effects of an AFAP rate on the controller's computer).

Dog boning in Slumping

Often even in shallow rectangular moulds the sides pull in during the slump.  To know what things to try to correct this effect, you need to understand why this effect is occurring.  These two pieces show the effect in different ways.

ebay 0916_slump_01

 This slump shows that even with thick glass the sides curve inwards even on shallow slumps.

theglassundergroundnj.org

This slump shows the interesting effect that the further up the piece you look, the greater the curvature. This relates to the greater amount of movement required by the glass to conform to the mould at the outer edges.

Why

During the slump of a rectangle or square the whole shape of the glass sheet is changing.  It is slightly stretching to form into the “hollow” of the mould, but it cannot stretch evenly all over, especially at the corners.  If you think of the analogy of Draping a piece of cloth into a rectangular depression, you will find it wrinkles up at the corners if you smooth it at the sides. This indicates the material is attempting to overlap there as it does not have a dart to take up the excess cloth.

This similar to what is happening to the glass sheet.  It is relatively thicker at the corners than along the sides.  Therefore, it does not slide down the mould at the corners as on the sides. It is simply thicker and is compressed by the movement of the glass at the sides.

Prevention

The question is how to use that knowledge to avoid or minimise the dog boning during the slump.  There are probably lots of methods, but three have occurred to me and others.

Add more material along the sides.  This involves fusing a piece with shallow arcs rather than straight sides.  This gives more material to counteract the dog boning effect when slumping a rectangle.  The difficulty is getting the proportions of the arc correct in relation to the length of the sides. You also need to ensure the arcs on the sides are not so much larger than the mould that they slump over the edge.  This means the whole piece will need to be cut smaller than the mould.

Remove material at the corners.  This takes the opposite approach.  To avoid the increased amount of glass at the corners, you remove some of it.  That is, you round the corners of the pieces to be fused. How much you will need to round the corners is a matter of experience, but is a shorter learning curve than cutting the edges in an arc.

Reduce the temp and increase soak time.  This approach requires less skill in cutting a shape.  It relies on giving the glass time to relax into mould with a minimum of stretch.  You need to find the lowest practical temperature at which to slump.  This will be the temperature at which you can first see the deformation of the glass in the mould.  Hold the temperature there for as long as it takes – possibly one or two hours. It is likely that you will still need some rounding of the corners of the glass, but only your experience will determine that, and if so how much.

Cold work the edges until straight.  This can be done by hand or by machine.

Further information is available in the ebook: Low Temperature Kiln Forming.

You Can Re-fire 3 Times Only - Kiln Forming Myths 25

Bullseye claims that you should only fire a piece 3 times

       

No. They only say the glasses are tested three times and that you are on you own after that.

There is not a general answer that can be given for the number of times you can fire a piece.  In general, Bullseye glass (and probably others, although they do not state what their limits of confidence are) can be fired three times with confidence.  Beyond that you need to do your own testing.

Bullseye states: 

At Bullseye, glasses known to be fairly stable are tested by firing to a top temperature of 1500°F (815°C) and soaking for 15 minutes before annealing. Once cooled, these tests are viewed for stress through polarized light and graded accordingly. We fire glasses known to be less stable three times to make sure they'll perform well under multiple firing conditions, such as those used to fuse and slump a plate.

If you have plans for multiple re-firings, tests are needed. The tests should replicate the temperatures, colours and thickness of the proposed project.  You probably do not need to reproduce the size of the project in these tests though.

Results from each firing should be tested for stress and these tests should include a test for annealing each time. 

You may wish to note that I have fired up to 7 times on several two layer with powder pieces.  Many people fire more times successfully.  It is my belief, but I have no proof, that multiple firings of a piece to slightly lower than full fuse will be more successful than each of them being to the full fuse.  My practice is to go to a rounded tack each of the firings subsequent to the first full fuse, but the final firing will be to a full fuse if I wish a gloss finish.  If I do not, my final firing will be about 10C - 15C below full fuse.

Dog Boning Causes

I fired a one-layer piece of glass and it shrank. What did I do wrong?

Cause

This result relates to the thickness that glass, under kiln forming circumstances achieves.  The combination of gravity and viscosity lead to this effect.  As the glass becomes less viscous (more runny), the surface tension is greater than gravity and so it becomes thicker at the edges.  This additional glass is supplied from the edges and to some extent from the interior. The glass in the middle becomes thinner, allowing in certain circumstances bubbles or holes to appear.

This illustration from Fusedglass.org shows the effects of gravity, which is related to mass, and viscosity.  The lack of mass means the surface tension allows the glass to draw up to be come thicker, forming the classic dog boning appearance.

Prevention

Knowing why this occurs allows you to take come precautions, when firing single layer pieces, to help prevent the shrinkage, often known as dog boning.

Fire larger

You can cut the glass larger than the final piece will be.  After firing, you cut it down to the size you want.  You may have to do a bit of cold working to get a rounded edge to the glass before any further processing.

Fire lower  

You can fire at a lower temperature for a longer time.  You will need to observe to determine when the glass begins to shrink. Either stop the temperature rise and soak there for a time, or reduce the temperature a little and soak for as long as needed to get the surface texture wanted.

Fire oval or circular pieces.  

With these shapes the shrinking is not so obvious, as it occurs all the way around.  With rectangular pieces, as the glass shrinks, the corners become thick more quickly and so do not shrink as much, giving that dog bone appearance.  Rounded pieces become thicker all the way around more evenly and the shrinkage is not so obvious.  However, you still get thinning in the interior which can lead to holes or bubbles, so observation is still necessary to prevent excessive thinning and bubble formation.

Fire thicker

The real prevention is to fire two layer pieces as that is the thickness at which viscosity, surface tension and gravity are in balance.  So the glass does not change size at kiln forming temperatures.

Cold work

Alternatively, you can cold work the edges back to straight parallel edges.  This can be done by hand grinding or by machine.

Further information is available in the e-book: Low Temperature Kilnforming.

Pre-programed Schedules - Kiln Forming Myths 24

Don’t use the pre-programed schedules that come with your kiln. 

As a universal approach, this does not stand up.  They do have the disadvantage of trying to cover all possibilities at once. This means they will fail if used uncritically. But everyone needs a place to start. 

An analogy might be the oven temperatures and times in recipes for cooking.  You have to start somewhere.  After a little experience you modify the schedule to fit the equipment you have and the material you are cooking.  This is similar to what happens with people starting in kiln forming.  Prior to the time when manufacturers began putting programs into the controllers, we all copied schedules from text books, guides and other workers.  We put them into the controller and tried them out.

I use pre-programmed schedules all the time – but they are built from my own from observations. They have been based on what others have done, writings and research, but modified by my equipment, the style of work I am doing and many other considerations as indicated in another post.

The instruction should be more about understanding what your schedule does than just dumping the pre-programed schedules.  You should know what your pre-programed schedule does. It is not enough to say “I used full fuse #1.”  You need to know what that schedule does.  You have look at the steps and temperatures and times that the schedule instructs the kiln to do.  Only in this way can you know what is working.  If it is not possible to see what the program is doing by reviewing the steps on the controller, then you need to delete it and copy a program from the glass manufacturer.  This is a reliable indicator of what will work in a wide variety of situations and can later be modified to meet your needs.

 The following are schedules for fusing and slumping.  You need to look at these and decide how you want to modify them - if at all - for your purposes.

An example of a fusing schedule

For this program, you have to decide, on the Goldilocks principle: 

• Is the rate of advance is too fast, too slow or just right.  
• Do I need a soak at 200C? 
• Is the next rate of advance right? 
• Do I need a bubble squeeze? 
• Is the top temperature right and the soak long enough?  
• Is the anneal soak long enough? 
• Is the anneal rate too slow, too fast or just right?  
• Do I need to control the rate of fall below the initial anneal cool, or just let the kiln cool naturally?

An example of a slumping schedule

Again apply the Goldilocks principle:

• You need to think about the speed of the rate of advance. Too fast, too slow or just right?
• Is the top temperature right? Too high, too low?
• Is the soak too long, too short, just right?  
• Is the annealing soak right, too short, too long?
• Is the annealing cool too fast, too slow?

When you have thought about these things, you are well on the way to writing your own programs.

Scheduling Relates to the Piece

My piece cracked, but I've always used this schedule and it has worked.

One schedule is not for all pieces. A number of factors affect the scheduling of a firing.  Some of them are:

Thickness

• The thicker the stack of glass, the slower the advance and anneal should be. 
•  The more layers of glass there are, the slower the rate of advance should be. 
•  The more uneven the thickness, the slower the temperature changes should be.

Angularity

• Glass with right angles or even more acute angles needs slower schedules than round or oval shapes.  

Degree of fuse

•  Laminated and tack fused pieces need much slower annealing and re-firing schedules.  

Contrasting colours

• Pieces with strongly contrasting colours of glass need slowing in heating and annealing.

Size

• To some extent the increased size will need some slowing of the schedule. Size becomes more important as you near the edge of the shelf or nearer to the sides of the kiln. Jewellery scale items can have an accelerated schedule.  

Mould base

• The size and shape of the mould will affect the speed and temperature of the scheduling.         
• The type and style of mould affect the schedule.  Drapes and especially over steel moulds require slower schedules. 

Position in the kiln

• The closer the glass is to the elements whether top or side, the slower the schedule must be.
• The less central on the shelf, the more care must be taken in scheduling.  

Type of kiln

• A kiln constructed for ceramics needs different scheduling considerations than one for fusing.  
• A kiln with side elements needs more careful firing than one with only top elements.

Re-Firing Schedules

Pieces need to be fired after their initial firing for various reasons – additions, corrections, fire polishing, etc.  You need to think about how this next firing differs from the previous one when thinking about the schedule to use.

The most common need for re-firing is after the full fuse or tack fuse to do the slumping.  On the first firing you had two independent pieces, so they could be fired faster than the fused piece.  It is now at least six millimetres thick – at least in parts. As glass is a poor conductor of heat, it needs a slower initial rate of advance than the assembly of thinner pieces did.

If you have fused a blank and now want to add tack fused elements to it, you need to consider how the pieces on the top will shade the heat from the glass below.  Unless the upper pieces almost completely cover the base, you will need to go much slower than the two-layer piece.  The blank is not only thicker, it also is shaded from the heat by the upper pieces.  If they are of both dark and light tones over the same base, the differential shading will be even greater, requiring slower rates of advance.

If you are adding layers of powder, you are not adding much to the thickness or unevenness of the glass.  So no additional reduction, other than that used for previous powder layers, in firing rates is required.

You need to think about the changes you have made to an already fired piece.  If you have made significant changes in thickness or are going to a tack fuse, you need to slow the rates of advance.  Some advice is given on rates of advance for tack fused items here.  If you have added only a layer of powder or thin coating of frit evenly spread, you will not need reductions in rates of advance.

Of course, the annealing soak will need to be longer for thicker or more complicated pieces, and the annealing cool will need to be slower. This blog post gives information on annealing considerations.

Bubble Squeeze

What is a bubble squeeze?

The term bubble squeeze refers to the process of allowing the glass to relax gradually allowing the air to escape to the edge of the piece.

The exact temperature is dependent on the softening point of the glass, its weight, and the complexity of the layup.  Normally the bubble squeeze is performed with a soak of about 30 minutes at the slumping temperature. 

Of course, glass being glass, the slumping point of any glass is a range temperatures.  This can be taken advantage of for complex layups or potentially difficult projects.  Pick the temperature about 50°C below the standard slumping point.  For example, Bullseye recommend 677°C as the slumping point.  Programme a slow rise - say 50°C per hour - from 625°C to 677°C where you also soak for at least 30 minutes.  This slow rise allows an even more gradual and progressive relaxation of the upper glass toward the lower.

For more information look at this post. 

Mica - Kiln Forming Myths 23

Mica will not stick to glass unless it's capped with clear.

Almost by definition, any material that needs to be encased, does not stick to glass.

However, mica does stick to glass.  But it is only the surface that is in contact with the glass that sticks.  Mica shears into very fine sheets and particles (almost microscopic), meaning that there many layers of mica even with a thin layer.  So only a minor portion of the mica you sprinkle, sift or paint onto the glass can stick. 

It is possible to add a flux such as borax to the mica solution to soften the surface of the glass, allowing more mica to sink into and stick to the glass.

Of course you can encase much more mica than will stick to the surface.  However, you have to be very careful about avoiding bubbles.  There is so much air (relative to the volume of the mica) that bubbles in encased mica is a constant problem.  Very good bubble squeezes and supporting the edges on shards of glass to keep the glass open while beginning to slump are required.

All myths have an element of truth in them otherwise they would not persist.

They also persist because people listen to the “rules” rather than thinking about the principles and applying them.  It is when you understand the principles that you can successfully break the “rules”.

Scum on Ground Edges

Almost without exception, ground edges show scum after fusing.  This scummy appearance is devitrification. This is caused by the powdered glass from grinding remaining in the pits caused by the action of refining the shape of the glass with a grinder. 

The suggestion that the glass should be placed in water immediately is of course a good precaution, although addition of vinegar is less efficacious than grinder lubricant added to the soak water.  This lubricant helps to keep the glass in suspension rather than settling into the scratches and pits of the grinding marks. The vinegar, which is often recommended, will etch the glass if left to soak and  smells up the place.  A better solution to soak the glass in is a 6% solution of tri-sodium citrate.

The glass needs to be made smoother than the standard grinding bit will achieve.  Normally, a 600 grit grinding bit will be sufficient to allow a good fire polish without any devitrification. Sometimes 400 grit will be enough. You will need to step down in grit from the standard (about 100) to fine (about 200) to at least super fine (about 400) grit.  If you can find a 600 grit bit, that can be your final smoothing before cleaning and placing on your piece for fusing.  Of course, this grinding can be done by hand with wet and dry sandpaper without any great labour.

There is, of course, a more simple solution - don't grind. I rarely grind any pieces for kiln forming.  Often, this is because I am working thicker than 6mm and know the gaps will fill during the forming.  If I need to make adjustments for 6mm pieces, and I often do, I groze the edges of the glass.  This gives a much cleaner break of the glass than grinding.  Of course, the edges are not as precise as when ground, but the glass remains absent of all the scratches that harbour the devitrification.  Often the fit does not need to be precise anyway. 

When the fit does need to be precise, the parts that do not fit perfectly can be filled with the appropriate colour of powder. This should be kept as near the gap as possible and piled up only a little over the gap to compensate for the lack of mass that powder has in comparison with sheet glass.  This powder technique, of course, does not work well on tack fused pieces.  There, the grinding and smoothing needs to be pursued.

Use of Untested Glass - Kiln Forming Myths 22

You must use art glass rather than recycled glass.

This seems to refer to the use of untested glass in kiln forming.  If you are going to use untested glass for kiln forming, it does not much matter which you use.  Because, in every case you will need to test for forming and annealing temperatures to be able to make use of the glass with unknown properties. 

Of course, people use glass that is not tested fusing compatible in many circumstances.  Float glass is frequently used in many kiln forming applications.  And bottle glass is of very little different in composition.  So-called art glass can be used in a variety of ways also.  There are many other variations of glass including handmade, casting, lamp working, and borosilicate, among others.  Each has their own set of characteristics, which overlap with each other.  The forming and annealing temperatures must be determined to enable you to use them. Some of this information is often available from the manufacturer’s web site or other sources.  Many times you have to do the testing for yourself.  One guide to help determine the critical temperatures is here. 

One characteristic that all untested glasses share is a tendency to devitrify by the second or third firing, so attempting to get the most work done in the fewest firings is a good idea.  This tendency to devitrify is frequently shown when manipulating bottle glass.

Peeking Without a Vent

What can I do if my kiln does not have a plug?

To understand thoroughly what is happening to your glass while firing, observation is key.  This means that an observation port is an ideal feature of any kiln.

However, many kilns are made without ventilation or observation ports.  This means that several possibilities need to be considered.

The easiest is simply to open the door or lid a small amount to make a brief observation.  This means that you have to set up the piece to be fired in such a place it can be seen from a small opening of the door/lid.  This brief opening of a small space will not normally cause any problem to the glass or kiln.  At the higher temperatures, you need to take personal safety precautions against the heat and light from the kiln.

It is possible to be more radical and drill an observation port through the metal casing and brick or fibre lining of the kiln.  This is then filled with a piece of fire brick or roll of fibre blanket.  This is sufficient to insulate the heat from the external part of the kiln.  This port should be about 50mm diameter to give a decent field of view.

A further refinement is to place a quartz viewing window in the hole you have drilled.  This viewing piece will become very hot, but not visibly red.  So, you must provide some insulating cover over the window.

But best of all, is to purchase a kiln with a viewing port in the first place.

Powders Burn Away - Kiln Forming Myths 21

Glass powders will burn off at high temperatures.

No.  The powder is glass.  Glass does not evaporate or otherwise combust at kiln forming temperatures.

The appearance of glass powders fading at fusing temperatures is related to the different appearance before and after firing.  Before firing, the powder looks both denser and paler than the final colour.  The initial experience with glass powder always is to put less on than needed. 

You need to remember that a thin film of powder is a tiny fraction of the thickness of the glass it is made from, so the colour will be much fainter.  A considerable amount of powder is required to give the colour shown by the colour charts – as much as 2mm for paler and transparent colours.  Opalescent colours show a little better with thin applications, but still require significant amounts.

This shows the application of powder on a piece where the powder provides almost all the colour for the piece.

The best procedure is to make test tiles with varying amounts of the powder to determine the thickness required for your desired result.  This gives a visual reference and experience in laying down the powder in appropriate thicknesses.

The appearance of the glass powder burning off, is merely the application of too little powder.

Organic and Mineral Inclusions

Encasing organic materials adds a new level of complexity to inclusions.  In addition to bubble formation, you need to consider how to eliminate the combustion gases from the vegetable matter.  On the other hand you don’t need to worry about expansion differences.

Some examples of metal and glass inclusions

The requirement is to burn out all of the vegetable matter to avoid creating big bubbles from the burn off of the material.  There are two elements to this burnout.  One is the amount of moisture contained in the object and the second is the volume of dry material that has to burn out.

Drying

Unless you have dried the material before including it, you will need to leave enough soak time before the glass begins to move to ensure all the water is removed.  It is also advisable to place small shards of glass at the corners of the piece, to allow easy ventilation both for the moisture to evaporate and the vegetation to burn easily.  You can estimate the time required and then put a witness piece of glass or better mirror above the vent or peep hole to see if there is any fogging on the glass from escaping moisture.  You need to continue soaking until there is no fogging.

Burnout

The second element is to give the vegetable matter enough time to burn out.  The burn out should occur at about 400°C.  This is high enough to ignite carbon based materials, but not so high that an extended soak will allow the glass to sufficiently deform to seal the un-burnt material inside.  If you have a really good sense of smell you can tell when the carbon has burned away by the absence of the smell.  For the rest of us, we need to open the peep hole and use a strong light to tell how much is left to burn away.  The burning is much more like a smouldering with very little light coming from it.

An incompletely burned out leaf in a large trivet with felt feet at the corners. 150mm square

The length of time you need to soak below the softening point of the glass is directly related to both the water content and the amount of combustible material you have included.  The burning will not begin until everything is dry.  If the material is not dry, the time for this needs to be added to the burnout time.  The length of soak for burnout is much more difficult to determine and needs periodic observation beyond the time when the smoke stops coming out of the kiln ports.

Bubble squeeze
Once the drying and burnout are completed, you need to advance to the bubble squeeze.  This will need to be longer or slower than usual to ensure all the combustion gasses are out for organic materials.  Minerals will normally be thicker than the organic materials and so need long bubble squeezes. These can be at or just below slumping temperature, or a slow rate of rise, taking an hour or more, from about 50C below the slumping point.

It is possible to include other minerals such as bone, or ash, or other inert particles that will not stick to the glass. Materials that contain silica are not suitable, as they stick to the glass and cause breakages.  So most stone, which contain silica, however thinly sliced will not be suitable as an inclusion.

Crash Cooling - Kiln Forming Myths 20

Crash cooling will harm your kiln or break your glass.

Crash or flash cooling was often a requirement in the early days of fusing to avoid devitrification. The kilns used were ceramic ones that did not lose heat very quickly.  The glass also was more subject to devitrification than the glass being made now.  Since those early days, kiln design has advanced so the kilns lose heat more quickly, although still well insulated; and the glass is more resistant to devitrification.  Thus, crash cooling is no longer advised.

If you have a brick lined kiln, crash cooling is hard on the bricks.  The cold air causes rapid shrinking of the brick.  The more rapidly the brick heats and cools, the more fractures will develop in the brick.  This effect will take place over many firings before there is any noticeable damage to the structure of the brick.  However, if you have brick tops or lids, there is the increasing likely development of crumbs of brick falling onto your work.  Brick lids and tops should be vacuumed frequently to remove the crumbs as they form.

Crash or flash cooling from top temperature toward annealing temperature is unlikely to break any glass other than thick glass pieces.  However, when using glass formulated for kiln forming, you do not need to crash cool. The crash cooling may be more useful when using glass that is not formulated for kiln forming.  The purpose in this case would be the same as that for the early fusing – avoiding devitrification by moving as quickly as possible through the devitrification range.

Sometimes flash/crash cooling is required to fix a free drop in place.  If allowed to cool on its own, the glass will continue to move for a while.  If the extent of the drop is critical, crash cooling is required.  This should be to a point below the slumping but above the annealing temperature.  The flash cooling will cool the outer portions of the glass, stopping any further movement. Meanwhile the inner portions are still hot.  This sets up significant stresses.  By stopping the cooling just below the slumping temperature, you allow the internal and external temperatures of the glass to approach one another before going into the anneal soak where the temperature equalises throughout if the differentials are not too great from the flash cooling.

All myths have an element of truth in them otherwise they would not persist.

They also persist because people listen to the “rules” rather than thinking about the principles and applying them.  It is when you understand the principles that you can successfully break the “rules”.

Metal Inclusions in Glass

There are a number of reasons to include metals in glass, not least colour.  However there are some things of which you should be aware.

Coefficient of Linear Expansion of some metals and glass is very different.  This listing gives some of the characteristics:

(All numbers given as 10^-7)

Aluminium          230

Glass              ca. 85

Brass                 180

Bronze               190

Copper              170

Borosilicate glass   33

Gold                  140

Iron                  116

Lead                  280

Nickel                130

Platinum              90

Quartz               7.7 to 14

Silver                195

Stainless steel     100 to 170

Mica                    30

Porcelain              65

Clay tile               59

Stainless steel     (in general) 100 to 170

Stainless steel     (418 series)          99

Stainless steel     (310 series)        144

Stainless steel     (316 series)        160

Tin                    234

Zinc                  297

Titanium              86

From this you can see there is little that is similar in expansion coefficient to glass.  Those that are, are expensive.  The implications of this difference in expansion are that the metals upon cooling contract more than the glass and so these are the effects you need to watch for:

• ·         Metals create strain when fused within the glass. 
• ·         Thin section is required to reduce the strength of the metals. 
• ·         The tensile strength of the metal may be more important than the CoLE
• ·         The amount of the metal should not be great or concentrated in one spot
• ·         Where thick sections of metal are required, a space should be created for later insertion of the metal.

In addition to expansion characteristics, the strength of the metal should be considered. Numbers are MPa (approximately equivalent to one atmosphere pressure)

Aluminium          40-50

Glass (float)        55-138

Brass                 250

Bronze               172

Copper              210

Gold                  120

Iron                  350

Lead                    12

Nickel                140-195

Platinum            125-240

Quartz               48.3 (and borosilicate glass)

Silver                170

Mica                  250-300

Porcelain            110-160

Stainless steel     (in general) 860

Tin                    15-200

Zinc                  110-200

Titanium            200

The greater the strength of the metal, the thinner the pieces should be to avoid excessive stress.

Melting temperatures are also a factor in including metals in glass

(°C)

Aluminium          660  

Brass                 930-1000

Bronze               913

Copper              1084

Gold                  1064

Iron                  1149

Lead                  328

Nickel                1453

Platinum            1770

Quartz               1670

Silver                961

Stainless steel     1510

Mica                  600-900

Tin                    232

Zinc                  420

Titanium            1670

This shows that aluminium, lead, tin and zinc are not good inclusions as their melting temperatures are below the fusing temperatures of glass. This means they will not retain their structure when fired.  It can of course provide a “frozen” liquid appearance.

Finally, the oxidisation characteristics should be considered.  The following metals tend toward the description after the arrow “>”

Aluminium    > brown

Brass   > some browning

Bronze  > sometimes a red cast

Copper > from red oxidising to green in the presence of soda or chloride

Iron  > black

Nickel  > retains its colour well

Platinum > > retains its colour well

Silver > reacts with sulphur to form a yellow

Stainless steel > blackens

Mica  > retains its natural colour, although some is low temperature coloured and so blackens, others have high temperature colours

Titanium  >  oxidises to white

Gold  > generally retains its colour except in leaf form when it becomes silver in colour

These are not exhaustive descriptions of oxidisation characteristics of metals in glass. They are a good starting point though.

Stainless Steel Magnetism

Is all stainless steel non-magnetic?  The answer is “No”. 

The scientific answer is of this nature:

“The magnetic behaviour of stainless steels varies considerably, ranging from the paramagnetic (nonmagnetic) in fully austenitic grades to hard or permanent magnetic behaviour in the hardened martensitic grades.

“All austenitic stainless steels are paramagnetic … [but the magnetic] permeability increases with cold work due to deformation-induced martensite, a ferromagnetic phase.  For certain grades such as types 302 and 304, the increase in magnetic permeability can be appreciable, resulting in these grades being weakly ferromagnetic in the heavily cold-worked condition.  The susceptibility of a particular grade to becoming ferromagnetic when heavily cold-worked depends on the stability of the austenite, which, in turn, depends on chemical composition and homogeneity.”

From https://www.cartech.com/techarticles.aspx?id=1476

The layman’s explanation is of this nature:

Stainless Steels are identified by series numbers ranging from 100 to 600.  Each series is organised by the alloy and grain structure.  The ones we are interested are mainly the 300 and 400 series.  The 300 series have an austenitic grain structure and the 400 series has a martensitic structure. 

"In the martensitic structure at the atomic level all the iron atoms are acting as mini magnets aligned in the same direction.  Cumulatively they are all adding to the overall magnetisation of the material, this is known as ferromagnetism.  However the addition of nickel disrupts this regular structure giving it an austenitic nature, so inhibiting the magnetism of the stainless steel."  

This makes the 300 series in its un-worked state non-magnetic and the 400 series magnetic.

A relatively general characteristic of the 300 series is the approximate 18% chromium and 8% nickel (among other alloying elements) content.  There is an interplay between the chromium and nickel content.  Chromium allows the stainless steel to have a magnetic structure, while nickel reduces the magnetic properties of the steel.  The 300 series mostly contain enough nickel to make them non- magnetic or only weakly magnetic. 

However, cold working to form the sheets into vessels or other objects can break down the non-magnetic structure of the steel by aligning the atoms together.  So some highly worked 300 series steels can become magnetic, although their corrosion resistance does not change.  The 316 stainless steel contains higher amounts of nickel than others and exhibits almost no magnetism in its cold worked state.  But 304 with less nickel does become mildly magnetic. Another advantage of high nickel content is that assists the chromium to form a passive surface layer, so resisting corrosion. This is of assistance to kiln formers, as it reduces spalling.  But note that magnetic response is a function of the metallic structure, not the corrosion resistance formed by the chromium and nickel (as well other trace metals) content.

Based in large part on: Magnetism and Other Properties of Stainless Steel, by Gregg V. Summers, P.E. Director of Product Development, Peninsula Components Technical Bulletin http://www.pencomsf.com/wp-content/uploads/2012/08/TB_MAG_SS.pdf 

The addition of nickel in the 300 series eases the workability and welding of stainless steel over the 400 series. You are more likely to find the 300 series in worked vessels and other kitchen equipment.  But the stainless steel knives are much more likely to be of the 400 series.  Both of these stainless steels have a high degree of corrosion resistance.

The Effect of Glass Temperature on Cutting

There are many opinions on how glass cuts when cold.  Some report cutting outdoors in sub-freezing temperatures, others that only warm glass cuts well.  I decided to see what scientific information there may be on this idea.

The Science

The scientific literature mostly concentrates on the effects at higher temperatures than we are concerned with.  However, there are some things that are applicable, and some of these effects of temperature are outlined below.

·         High humidity results in loss of strength. 

·         The strength of glass is reduced by 25% at 100°C compared to 0°C.

·         Glass needs several days to be at an even temperature throughout.

·         Variance in temperature across the glass causes unwanted breakages.

·         Colder glass becomes more brittle due to loss of elasticity.

·         Hardness of glass increases with decreasing temperature.

The terms of strength, hardness and brittleness have scientific definitions that are hard to apply to the everyday glass cutting that we do.  Strength may or may not have applicability to glass cutting.  Elasticity may or may not be an important factor in cutting.  Surface hardness may play a part in cutting while cold.

Applicability of the Science

However some things seem to apply. 

High humidity results in loss of strength.  This may be a factor in low temperature cutting.  The humidity in a relatively closed environment increases with the reduction in temperature.  Breaking glass is about the creation of a weakness in the glass along the score line.  In so far as strength is a factor in the break running along the score line, this may be an element in cold glass cutting.  If the whole glass is weaker, the difference in strength at the score line is less and so promotes unwanted breaks.

Variance of the temperature of the glass throughout the substance of the glass promotes unwanted breakages.  Perhaps the cold glass that is difficult to cut is not equally cold throughout.  Certainly a number of people report that they store their large glass outdoors and can still score and break the glass during the winter perfectly well before bringing it into the studio. 

Glass becomes more brittle with decreasing temperature, and it also becomes harder.  Perhaps these two elements are a factor in controlling breakages.  If the glass is both harder and more brittle, a different scoring method is required. 

The way in which glass at any temperature breaks is related to the force of the score, the speed of the score and the angle of the cutting wheel.  If the glass is both harder (at the surface) and more brittle it requires less scoring force or a blunter wheel angle.  The more blunt the wheel on a thicker (i.e. stronger) glass, the more vertical the stress lines are created in the glass.  So in a cold and harder glass, a blunter wheel angle seems appropriate, even though the glass is not thicker.

It is not usual for people to have cutting wheels of different angles, so an easier, although more skilled, approach is to reduce the scoring force in cold conditions.  Reducing the force in scoring a hard and brittle glass causes the stress lines to be more vertical than increased forces do.  Increased forces cause lateral lines of stress to be created, leading to unwanted breakages.

Secondly, the glass being more brittle, less force in breaking stress is required.  As the glass becomes colder, the less elastic it is.  This elasticity is an important element in breaking the glass at room temperatures. The score needs to be run gently to counteract the loss of elasticity and the consequent increase in the brittle strength of the glass.

Conclusions

My conclusion, after the reading I’ve done, is that cold glass becomes slightly stronger and more brittle than room temperature glass, and so requires a slightly different method of cutting. This difference is to reduce the pressure of scoring and the force of breaking (applying stress to the glass).  

Of course you can warm the glass up before scoring it, but the research seems to indicate that significantly long times are required to equalise the temperature throughout.