Flux, an Introduction

Flux is a key contributor to most soldering applications. It is a compound that is used to lift tarnish films from a metals surface, keep the surface clean during the soldering process, and aid in the wetting and spreading action of the solder. There are many different types and brands of flux available on the market; check with the manufacturer or reseller of your flux to ensure that it is appropriate for your application, taking into consideration both the solder being used and the two metals involved in the process. Although there are many types of flux available, each will include two basic parts, chemicals and solvents.

The chemical part includes the active portion, while the solvent is the carrying agent. The flux does not become a part of the soldered joint, but retains the captured oxides and lies inert on the joints finished surface until properly removed. It is usually the solvent that determines the cleaning method required to remove the remaining residue after the soldering is completed. It should be noted that while flux is used to remove the tarnish film from a metal's surface, it will not (and should not be expected to) remove paint, grease, varnish, dirt or other types of inert matter. A thorough cleaning of the metal's surface is necessary to remove these types of contaminates. This will greatly improve the fluxing efficiency and also aid in the soldering methods and techniques being used.

Courtesy of American Beauty Tools

Even Solder Beads on Edges

Running an even bead on the edges of copper foiled projects is often difficult. Several things can help.

Hold the panel vertically and ensure the edge you are applying solder to is horizontal. This means that you have to keep moving anything that is not rectangular.

To apply solder and move the piece ideally needs three hands – one for the solder, one for the iron, and one to manipulate the piece. Failing such an evolutionary leap, you can use a small vice to continually alter the angle of the edge, you can get a friend or colleague to manipulate the panel, or you can place the solder so that you can pick up little drops of solder and place them on the edge. With practice, you can pick up some solder and transfer it to the edge before the previous dot of solder has cooled, so leaving a smooth bead by the joining of the dots.

Alternatively, you can place dots of solder near each other around the piece. You then come back and with one hand manipulating the piece the other can use the solder iron to heat and join the dots.

You do have to be careful that you do not move the panel before the solder has hardened, or it will run down the newly created slope to the new horizontal edge.

I find that it is much more difficult to run a bead on an edge than it is to “pat” the solder dots. This patting motion allows the solder to join together, but does not heat such a long line that it flows as you turn the piece to keep the edge currently being soldered horizontal.

Even Solder Beads

Getting even solder beads is a lot about where you look while you solder. Unlike drawing or cycling looking at where you are going is not so useful when soldering. You need to see the effects of what you are doing so looking behind the solder bit will help you understand what you are doing. If the bead begins to get small or narrow you either slow down the forward movement of the solder bit or add solder to it more quickly. If the bead begins to get too thick, you do the opposite. You can move the bit faster, or reduce the speed of feeding the solder to the bit.

Another element in getting an even bead is the heat being delivered. If you use a wide soldering bit you are delivering more heat to the joint. You hold the chisel bit so that it runs along the foil. The bigger the bit, the more heat is being held. And the more heat held in the bit, the more heat is applied to the soldering. Small bits are for getting into tight spots and for decorative soldering. Big wide bits are best for running beads.

Glueing Glass Pieces

The best solution is to avoid the use of glue completely. If you cannot, use as little as possible and make sure it burns out cleanly.

The glues to which kiln workers have normal access, do not survive to tack fusing temperatures. Therefore they can only be considered as a means to get the glass assembly to the kiln. The glue will not hold the pieces in place until the glass begins to stick, so the pieces must have a stable placement. If not, the pieces will slip, roll and move once the glue has burned out.

The second requirement of glues is that they burn out without leaving a residue.

Glues that have been used with little or no residue include:

- CMC (carbyl methyl cellulose) is a cellulose based binder used in a wide variety of industries, including food. For our purposes, it is also used in the ceramics industry and is often called glaze binder. It is a main constituent of “glasTac” from Bullseye. This can be made up into a viscous solution to catch and hold frits and other sprinkled elements in place.

- PVA (Polyvinyl Acetate) is water-based glue. It is sometimes known as school glue. It can be diluted to about 10parts water to 1 part PVA. This is sufficient to hold the glass pieces together with only a drop for each piece of glass. It does not work so well for small sprinkled elements.

- Super glue burns off with no concerns about cyanide. It should be used sparingly and also works best for pieces of glass.

- Hair gel can be used to catch and hold small elements in place.

- Hair lacquer is normally sprayed over the assembled piece and so can be used to hold pieces of glass as well as sprinkled elements.

In all uses of glue the principle to remember is: use the minimum to hold pieces together while getting the work into the kiln. And in all cases, you need to test to see if a residue is left on the glass at full fuse when using a new glue.

Removing Kiln Wash from Shelves

There are at least three ways to remove kiln/batt wash from mullite kiln shelves.

One quick way is to use a broad wallpaper scraper held at a very acute angle to the shelf. This rapidly removes the separator. One down side to this method is that any uneven pressure can put a gouge into the surface of the shelf.

So a more gently way to remove the wash is to use a drywall/plaster board sanding sheet or other open weave sanding material. This allows the powdered wash to come through the sanding material rather than clog up the material. The disadvantage to this is that it takes much longer to remove the wash, although it does leave a very smooth shelf after many sandings.

A third way is to wash off the kiln wash. This is relatively quick, but it gets the shelf wet and requires a longer period before the shelf becomes dry. You can, of course put the next application of kiln wash on as soon as the shelf is clean. They both can dry off at the same time.

Effect of Heat on Sandblasted textures

This is based on Graham Stone’s work with float glass. The temperatures are applicable to float glass, and so need to be adjusted for other glasses, but illustrate the principle of how heating temperatures affect the glass.
Temperatures in degrees Celsius.

650 Blasted surface softened, evened, less "brutal".
690 Blasting still opaque but less "white
700 Blasting becoming too sheeny but still okay for certain effects.
740 Blasting now subtle and glossy

Based on Firing Schedules for Glass; the Kiln Companion, by Graham Stone, Melbourne, 2000, ISBN 0-646-39733-8, p24

Viscosity Changes with Temperature

This is based on Graham Stone’s work with float glass. The temperatures are applicable to float glass, but illustrate the principle of how viscosity changes in a non linear pattern with the increase in temperature.
Note: the temperatures are in Celsius.

515 Viscosity of float 10145 poises (approximate strain point of float)
555 Viscosity 1013 poises
610 Viscosity approx. 1010 poises
730 Viscosity 1076 poises
850 Viscosity decreasing faster
900 Viscosity now 105 poises and falling

Based on Firing Schedules for Glass; the Kiln Companion, by Graham Stone, Melbourne, 2000, ISBN 0-646-39733-8, p24

Plaster Properties - Effect of Plaster-Water Ratio

Plaster-water ratio (by weight) of 100 plaster to 30 water gives:
a setting time of 1.75 mins,
a compression strength of 813 kg/sq cm., and
a density of 1806 kg/cubic metre

Plaster-water ratio (by weight) of 100 plaster to 40 water gives
a setting time of 3.25 mins,
a compression strength of 477 kg/sq cm., and
a density of 1548 kg/cubic metre

Plaster-water ratio (by weight) of 100 plaster to 50 water gives
a setting time of 5.25 mins,
a compression strength of 318 kg/sq cm., and
a density of 1352 kg/cubic metre

Plaster-water ratio (by weight) of 100 plaster to 60 water gives
a setting time of 7.24 mins,
a compression strength of 230kg/sq cm., and
a density of 1207 kg/cubic metre

Plaster-water ratio (by weight) of 100 plaster to 70 water gives
a setting time of 8.75 mins,
a compression strength of 176 kg/sq cm., and
a density of 1083 kg/cubic metre

Plaster-water ratio (by weight) of 100 plaster to 80 water gives
a setting time of 10.5 mins,
a compression strength of 127 kg/sq cm., and
a density of 990 kg/cubic metre

Plaster-water ratio (by weight) of 100 plaster to 90 water gives
a setting time of 12 mins,
a compression strength of 99 kg/sq cm., and
a density of 908 kg/cubic metre

Plaster-water ratio (by weight) of 100 plaster to 100 water gives
a setting time of 13.75 mins,
a compression strength of 70 kg/sq cm., and
a density of 867 kg/cubic metre

Properties of Typical Gypsum Plasters and Cements

No. 1 pottery plaster
Water to be added as % of dry mix by weight - 70%
Setting time - 27-37 mins
Dry density (kg/cubic metre) - 1106
% expansion on setting - 0.21
Compressive strength (kg/sq cm) - 127.26


No. 1 molding plaster
Water to be added as % of dry mix by weight - 70%
Setting time - 27-37 mins
Dry density (kg/cubic metre) - 1106
% expansion on setting - 0.20
Compressive strength (kg/sq cm) - 141

Plaster of Paris
Water to be added as % of dry mix by weight - 70%
Setting time - 27-37 mins
Dry density (kg/cubic metre) - 1106
% expansion on setting - 0.20
Compressive strength (kg/sq cm) - 141

No. 1 Casting plaster
Water to be added as % of dry mix by weight - 65%
Setting time - 27-37 mins
Dry density (kg/cubic metre) - 1162
% expansion on setting - 0.22
Compressive strength (kg/sq cm) - 170

Pottery plaster
Water to be added as % of dry mix by weight - 74%
Setting time - 27-37 mins
Dry density (kg/cubic metre) - 1057
% expansion on setting - 0.19
Compressive strength (kg/sq cm) - 127

Hydrocal cement
Water to be added as % of dry mix by weight - 45%
Setting time - 25-35 mins
Dry density (kg/cubic metre) - 1442
% expansion on setting - 0.39
Compressive strength (kg/sq cm) - 35

Hydroperm cement
Water to be added as % of dry mix by weight - 10%
Setting time - 12-19 mins
Dry density (kg/cubic metre) - <641
% expansion on setting - 0.14
Compressive strength (kg/sq cm) -


Hydro-Stone cement
Water to be added as % of dry mix by weight - 32%
Setting time - 17-20 mins
Dry density (kg/cubic metre) - 1914
% expansion on setting - 0.24
Compressive strength (kg/sq cm) - 707

Ultracal cement (30)
Water to be added as % of dry mix by weight - 38%
Setting time - 25-35 mins
Dry density (kg/cubic metre) - 1588
% expansion on setting - 0.08
Compressive strength (kg/sq cm) - 424

Drop Rings

Mould

It is possible to purchase drop rings of various sizes. It is also easy to construct one from vermiculite board or ceramic fibre board. Merely cut a circle of the desired radius from the board. Leave at least 50mm of board outside the circle, and more for thinner boards.

Batt wash the top and inner sides of the drop ring

Glass
The glass should be larger than the hole in the ring. This will vary by radius of the hole. The glass will need to be from 50mm larger diameter than the hole for smaller holes to 100mm larger diameter for holes over 300mm.

Glass should be at least 6mm thick for the first 100mm of drop and an additional 3mm for each 50mm more. So, a drop of 200mm would require glass of 12mm thick

Temperatures
The temperature rise should be no more than 200C per hour to about 675C for 6mm glass and less for thicker glass. Remember the glass is much closer to the elements than normal and it is possible to thermal shock the glass.

The rate and amount of slumping is controlled by temperature, span (the width of unsupported glass on the mould) and time. The higher the temperature the faster a piece will slump. However you can slump at lower temperatures by holding the temperature for a longer time.

Also note that the wider the span, the faster the glass slumps.

If you slump at high temperatures with a drop ring the sides of the bowl tend to be straight and steep. The strain is limited to the region immediately inside the rim. Therefore the glass tends to thin next to the rim and the colours are diluted. If you slump at a lower temperature for a longer period of time the strain is distributed over the entire unsupported area. This results in a more rounded shape for the bowl and even thickness of the glass across the bottom of the bowl.

Experiment
Finding the right combination of time and temperature requires a bit of experience and guess work. If you want a rounded bottom, heat the glass to the point that it starts to bend on the mould and wait for 30 minutes. If it has slumped about 1 inch in that time wait another 30 minutes. You are looking for a slumping rate that is acceptable. If it hasn't moved very much then increase the temperature 15C and check again in 15 minutes. Keep moving temp up and waiting for 15 minutes until the piece has completely slumped. This might take several hours.

If you want straight sides keep heating the piece rapidly.

Stopping
When the piece has slumped to the desired shape, flash cool the kiln to about 30C above the annealing point to stop movement in the glass. Extend the annealing soak and increase the length of the annealing cool time (reduce the rate of fall) over normal slump firings of the same thickness.