Super Glue - Kiln Forming Myths 29

The use of super glue in the kiln causes cyanide gas

This is not true.  But because it is such a persistent belief, a lot of detail is given below.  In short the precautions are: 

• use the minimum amount, 
• use an organic gas face mask, 
• do not wear natural fibres or gloves, 
• let the glue cure before placing it in the kiln, 
• have the solvents at hand while using the glue.

Super Glue Safety

Super glue is frequently used as a temporary fixative in assembly of kiln forming projects. There is some concern about safety, as it is known that super glue is made from cyanoacrylate, which it is feared will break down in the kiln into cyanide gas.

Greg Rawls, a certified industrial hygienist says

"I looked at the MSDSs for several forms of super glue. The main component is Ethyl 2-cyanoacrylate, which has a TLV of 0.2 ppm which is relatively toxic. [However,] the thermal decomposition products are carbon monoxide and carbon dioxide. I did not see a reference to cyanide gas. However, as I recall cyanide gas dissociates into elemental carbon and nitrogen at about 800 F. Since you use it in such small quantities, I would not worry about it. In my opinion the worst thing that could happen is you glue your fingers to the glass."

Safety issues

To treat the safety issues seriously and determine if you feel Greg Rawls' view is justified, you need to look at the issues of toxicity, reactions, adhesion of tissue, ventilation, first aid and decomposition products in the whole context.

Toxicity

The fumes from cyanoacrylate are a vaporized form of the cyanoacrylate monomer that irritate sensitive membranes in the eyes, nose, and throat. They are immediately polymerized by the moisture in the membranes and become inert. These risks can be minimized by using cyanoacrylate in well ventilated areas. About 5% of the population can become sensitized to cyanoacrylate fumes after repeated exposure, resulting in flu-like symptoms. It may also act as a skin irritant and may cause an allergic skin reaction. On rare occasions, inhalation may trigger asthma. There is no single measurement of toxicity for all cyanoacrylate adhesives as there is a wide variety of adhesives that contain various cyanoacrylate formulations.

The United States National Toxicology Program and the United Kingdom Health and Safety Executive have concluded that the use of ethyl cyanoacrylate is safe and that additional study is unnecessary. 2-octyl cyanoacrylate degrades much more slowly due to its longer organic backbone that slows the degradation of the adhesive enough to remain below the threshold of tissue toxicity, so the use of 2-octyl cyanoacrylate for sutures is preferred.

Reaction with cotton

Applying cyanoacrylate to some materials made of cotton or wool results in a powerful, rapid exothermic reaction. The heat released may cause serious burns, ignite the cotton product, or release irritating white smoke. Users should not to wear cotton or wool clothing, especially cotton gloves, when applying or handling cyanoacrylates.

Adhesion of the Skin

Various solvents and de-bonders can be used. These include:

·         Acetone, commonly found in nail polish remover, is a widely available solvent capable of softening cured cyanoacrylate

·         Nitromethane

·         Dimethyl sulfoxide

·         Methylene chloride

Commercial de-bonders are also available.

Warnings include:

·         It is a mild irritant to the skin.

·         It is an eye irritant.

·         It bonds skin in seconds.

·         Any skin or eye contact should be copiously flushed with water and medical attention be sought immediately.

·         Do not attempt to separate eye tissues – the bond will separate naturally within a few days.

Precautions

·         Use goggles.

·         Do not wear cotton or wool clothing while using super glue

·         Ventilate the area well. Since cyanoacrylate vapours are heavier than air, place exhaust intake below work area. Activated charcoal filters using an acidic charcoal have been found effective in removing vapours from effluent air so the bench top air filters are suitable for use while using super glue.

·         Avoid use of excess adhesive. Excess adhesive outside of bond area will increase level of vapours.

·         Assemble parts as quickly as possible. Long open times will increase level of vapours.

Evaporation Effects

·         The effects of heating cyanoacrylate are not completely known. The flash point is known to be greater than 85ºC. As a precaution do not remain in the area of the kiln after that temperature has been reached.

·         The decomposition products are carbon monoxide and carbon dioxide. There is no reference in the literature to cyanide gas. It is highly unlikely that heat will cause the release of cyanide gas at any time during the heating. To be certain, you should make sure the evaporation of the glue is complete before firing the kiln.

See this tip for the use of super glue in kiln forming. http://glasstips.blogspot.co.uk/2013/12/super-glue.html

Super Glue Safety

Super glue is frequently used as a temporary fixative in assembly of kiln forming projects. There is some concern about safety, as it is known that super glue is made from cyanoacrylate, which it is feared will break down in the kiln into cyanide gas.

Greg Rawls, a certified industrial hygienist says "I looked at the MSDSs for several forms of super glue. The main component is Ethyl 2-cyanoacrylate, which has a TLV of 0.2 ppm which is relatively toxic. [However,] the thermal decomposition products are carbon monoxide and carbon dioxide. I did not see a reference to cyanide gas. However, as I recall cyanide gas dissociates into elemental carbon and nitrogen at about 800 F. Since you use it in such small quantities, I would not worry about it. In my opinion the worst thing that could happen is you glue your fingers to the glass."

Safety issues

To treat the safety issues seriously and determine if you feel Greg Rawls' view is justified, you need to look at the issues of toxicity, reactions, adhesion of tissue, ventilation, first aid and decomposition products in the whole context.

Toxicity

The fumes from cyanoacrylate are a vaporized form of the cyanoacrylate monomer that irritate sensitive membranes in the eyes, nose, and throat. They are immediately polymerized by the moisture in the membranes and become inert. These risks can be minimized by using cyanoacrylate in well ventilated areas. About 5% of the population can become sensitized to cyanoacrylate fumes after repeated exposure, resulting in flu-like symptoms. It may also act as a skin irritant and may cause an allergic skin reaction. On rare occasions, inhalation may trigger asthma. There is no single measurement of toxicity for all cyanoacrylate adhesives as there is a wide variety of adhesives that contain various cyanoacrylate formulations.

The United States National Toxicology Program and the United Kingdom Health and Safety Executive have concluded that the use of ethyl cyanoacrylate is safe and that additional study is unnecessary. 2-octyl cyanoacrylate degrades much more slowly due to its longer organic backbone that slows the degradation of the adhesive enough to remain below the threshold of tissue toxicity, so the use of 2-octyl cyanoacrylate for sutures is preferred.

Reaction with cotton

Applying cyanoacrylate to some materials made of cotton or wool results in a powerful, rapid exothermic reaction. The heat released may cause serious burns, ignite the cotton product, or release irritating white smoke. Users should not to wear cotton or wool clothing, especially cotton gloves, when applying or handling cyanoacrylates.

Adhesion of the Skin

Various solvents and de-bonders can be used. These include:

Acetone commonly found in nail polish remover, is a widely available solvent capable of softening cured cyanoacrylate

Nitromethane

Dimethyl sulfoxide

Methylene chloride

Commercial de-bonders are also available.

Warnings include:

• It is a mild irritant to the skin.
• It is an eye irritant.
• It bonds skin in seconds.
• Any skin or eye contact should be copiously flushed with water and medical attention be sought immediately.
• Do not attempt to separate eye tissues – the bond will separate naturally within a few days.

Precautions

• Use goggles.
• Do not wear cotton or wool clothing while using super glue
• Ventilate the area well. Since cyanoacrylate vapours are heavier than air, place exhaust intake below work area. Activated charcoal filters using an acidic charcoal have been found effective in removing vapours from effluent air so the bench top air filters are suitable for use while using super glue.
• Avoid use of excess adhesive. Excess adhesive outside of bond area will increase level of vapours.
• Assemble parts as quickly as possible. Long open times will increase level of vapours.

Evaporation Effects

• The effects of heating cyanoacrylate are not completely known. The flash point is known to be greater than 85ºC. As a precaution do not remain in the area of the kiln after that temperature has been reached.
• The decomposition products are carbon monoxide and carbon dioxide. There is no reference in the literature to cyanide gas. It is highly unlikely that heat will cause the release of cyanide gas at any time during the heating. To be certain, you should make sure the evaporation of the glue is be complete before firing the kiln.

See this tip for the use of super glue in kiln forming.

Keeping Copper Inclusions from Oxidising

The colour change in the copper foil is due to oxidisation - if the copper foil is completely deprived of oxygen it stays shiny and copper coloured. If you leave copper exposed at all it will go metallic blue or even bottle green, mostly it turns a lovely burgundy red colour- an intermediate oxidisation stage.

Klyr fire or borax solutions may help the copper stay bright.

Through doing some experiments with art school students, I have found the speed of firing is critical in an electric kiln. In a gas kiln the speed is normally fast anyway and produces better results than an electric kiln. It also is a kiln with a reducing atmosphere rather than oxidising one of an electric kiln.

Summary:

The main elements in keeping copper inclusions (and by extension, other metals) bright is to keep the metal from oxidising. Two elements are important in this:

• Keep oxygen from the metal
• Reduce the time the metal is exposed to high temperatures

Various methods are used to keep the metal from exposure to oxygen. Some of these involve: 

• coating the metal with fluxes to reduce the amount of oxygen in contact with the metal. 
• using a reducing atmosphere, such as a gas kiln. 
• placing an oxygen hungry material in the kiln with the glass and metal. 
• coating the metal with glass powder before encasing it within the glass.

Reducing the heat exposure of the metal also indicates that firing fast would provide better results. This requires very even heating within the kiln to avoid heat shocking the glass.  This is where a gas kiln is most advantageous - it can be fired fast without breaking the glass and it has a reducing atmosphere within it.

In general, it is easier to make use of the effects of the oxidised metal rather than striving for bright metal inclusions.

Gas Fired Kilns

Installing a Gas Fired Kiln

There are a number of considerations about the location of a gas kiln.

Air exchange

The kiln should be placed in an area where there is good air exchange. For a number of reasons, it is usually convenient to place the kiln near an outside wall – ventilation and canister storage are the two most important.

Ventilation

There should be a low level vent to the outside to allow air to rise for the use of the combusting gas. There needs to be high level vent for the gas to escape. Ideally a hood with powered extraction would be installed.

Space

As with any kiln, you need to have sufficient space around the kiln to avoid heating any flammable materials. In the case of a gas kiln you need to be careful to avoid storing any thing that might ignite above the kiln. You can put heat resistant materials around the kiln if desired.

Location and storage of gas canisters

The safest place to put the gas canisters is outside the building. This does mean going outside to turn the valve on the gas canister on and off. However this is the safest place, should any fire start in the building, because the fire brigade can find and remove it from the fire. This placing applies to both the in use canister and any other full or empty canisters.

Detectors

Finally, even with these precautions, you should install a carbon monoxide detector. Carbon monoxide has no smell and can overcome you very quickly. Even a few minutes of exposure can leave you feeling ill for days.