Kiln Wash

Kiln forming techniques require separators between the glass and the shelf or mould on which it rests during the heating process. These separators have different generic names – kiln wash and batt wash are two.

There are a number of brands of kiln wash. All of them contain two main ingredients – alumina hydrate (sometimes called slaked alumina) and kaolin (also called china clay). Different producers use these ingredients in various proportions. 

A number of makes also include a colourant that changes when fired above certain temperatures to indicate the wash has been fired.  It also distinguishes between the unfired and the already fired kiln washed shelves.

An important thing to remember is that the kaolin changes its composition once it is fired over 600C/1113F. This change of composition is completed by 900C/1620F.  The change is progressive.  It is so slow that slumping and draping moulds coated with kiln wash will last indefinitely. However this change is great enough by 770C/1419F that the kiln wash sticks to the glass on the next firing. Thus, it is essential to change the kiln wash after every firing that reaches tack fusing temperatures or higher.

It is possible to apply a fresh coat of kiln wash over the old one to save time. However, as soon as the kiln wash flakes you must scrape off all the old kiln wash and apply a new coat to the bare shelf or mould.

Some makers use much less of the binder (china clay) than others which makes them better for the popular casting moulds than those for shelves and slumping moulds as they can be brushed away without abrasion.


In addition, boron nitride is a suitable release from moulds.  It is very stable at reltively high temperatures and so can provide a smooth, "slippery" separator between the glass and its supports, whether shelves, moulds or kiln furniture.  It does seal porous surfaces, meaning that air cannot move through the treated surfaces.  It has to be removed with abrasion and so thought must be given to which surfaces it is applied.

Boron Nitride

What is boron nitride? What makes it a good separator?

Boron nitride is a heat resistant refractory compound of boron and nitrogen with the chemical formula BN. It is also chemically stable at elevated temperatures.  It exists in various crystalline forms that are similar to a structured carbon lattice. The hexagonal form corresponding to graphite is the most stable and soft among BN forms.  It is the form most useful in kiln forming as a smooth release separator, especially for steel.  It is also used as a high temperature lubricant, and has a wide use in cosmetic products.

There is a cubic form that is similar to diamond (called c-BN), but softer.  It has a superior thermal and chemical stability.  There is a harder form called wurtzite, but which is rare. Neither of these is of much use in kiln forming.

Hexagonal BN

Hexagonal BN (h-BN) is the most widely used form of boron nitride. It is a good lubricant at both low and high temperatures (up to 900C, even in an oxidizing atmosphere). Another advantage of h-BN over graphite is that its lubrication properties do not require water or gas trapped between the hexagonal sheet layers. So, h-BN lubricants can be used even in vacuum, e.g. in space applications. The lubricating properties of fine-grained h-BN are used in cosmetics, paints, dental cements, and pencil leads.  In kiln forming, the high temperature lubricating properties are made use of as separator between metal, ceramic and other supporting materials for the glass.

“Hexagonal BN was first used in cosmetics around 1940 in Japan. However, because of its high price, h-BN was soon abandoned for this application. Its use was revitalized in the late 1990s with the optimization h-BN production processes, and currently h-BN is used by nearly all leading producers of cosmetic products for foundations, make-up, eye shadows, blushers, kohl pencils, lipsticks and other skincare products.”   
https://en.wikipedia.org/wiki/Boron_nitride

It has wide application in materials to give them self-lubricating properties.  Boron nitride has the properties of stabilisation of materials, reducing expansion and resistance to electrical conduction, making for wide use in plastics and electronics among a wide variety of other products.

Health and Safety

There are some health issues related to its use.  It is reported to have a weak association with the formation of fibrous material in the lungs and so result in pneumoconiosis when inhaled in quantity in particulate form.  It is best to wear a dust mask when applying and to do it outdoors, as simple ventilation will not prevent dust settlement indoors.

Reversibility of Boron Nitride

After using Zyp/MR97, can I sand it off and use kiln wash?

Some people are applying boron nitride to ceramic moulds for the "smoother" surface.  Boron nitride is an excellent separator for metal moulds and casting moulds whether metal or ceramic. But it has limitations, including the price and requirement for a repeated application at each firing.  Some are beginning to wonder if they can go back to kiln wash after having used the boron nitride. Some say you cannot unless you sand off the separator.

The general experience has been that you can't apply kiln wash on top of the boron nitride. It just beads up and flows off, because the boron nitride creates a non-wetting surface that survives relatively high temperatures.  The water in the kiln wash mixture merely beads up or washes away. This means the kiln wash in suspension has no opportunity to adhere to the mould.

The most accepted way to get rid of the boron nitride is by sandblasting. Then apply kiln wash as normal. The sandblasted ceramic mould previously coated accepts kiln wash with no difficulty. In the absence of a sandblaster, you can use a sanding pad. You do need to be cautious about taking the surface of the mould when using abrasive removal methods, as the ceramic is relatively soft in relation to the abrasive materials.

The difficulty of removal of the boron nitride means that you have to think carefully about which moulds you put it onto.  If the mould has delicate or fine detail, removing the boron nitride risks the removal of some of the detail.  This indicates that this kind of mould, once coated, should not be taken back to the bare mould to change the kind of separator.

Another use of boron nitride is to spray a very small amount on a fiber strip to be used for damming. This will give you fewer needles as it provides a non-wetting surface at relatively high temperatures. This allows the glass to slide down the fibre paper without hanging up and creating the needles.

One advantage of kiln wash over boron nitride is that you do not have to reapply every firing as with boron nitride. With the boron nitride you need to apply before every firing.  It is best to use a paint brush to dispose of any lose material before giving a light re-coating. Not a whole lot is required on subsequent coatings.

If you are using boron nitride to get a smoother surface to the object, consider using a lower slumping or draping temperature, as this will also minimise mould marks.