Striking glass

Yes, much glass is striking in its effect.  But the term is used in a technical sense to indicate the glass has not reached its intended colour without further firing.

A striking glass is one that changes to its true colour. Not one which takes up a different colour.  There seem to be differing ideas on how striking works, but it is an intentional process.

Several glasses coloured with copper or silver strike to Their final colour when heated.  It seems that copper when used to make red (rather than blue or green) can undergo a chemical change during the heating.  The copper oxide used is normally Cu₂O.  When heated the copper and oxygen molecules can separate and form bonds with other molecules.  The rapid cooling that is used in glass prevents the copper and oxygen from combining in the Cu₂O formation.  The extent of this dissociation determines the degree of colour change.  Thus, the colour is affected by the heat work given to the glass – assuming the starting proportions of materials are the same.  This can occur with some other colouring metals too.

Another form of striking is caused by the growth of crystals within the glass. In these cases, usually in silver bearing glass, the metals separate from the silica and form small crystalline structures which are also fixed by the rapid cooling required for glass.

There is another theory that the colour change is due to the orientation of the colouring molecules within the glass matrix.  The idea is that the molecules will change from the clearer state to the struck colour due to the orientation caused by reheating and cooling.

The actual process seems to be unknown in a definitive sense.  What is known is that temperature, a reducing or oxidising atmosphere, and heat work will vary the intensity of the strike in colour.  This means that where the project is especially sensitive, you must undertake experiments to help predict the colour that will be achieved with the conditions you choose to use.

Break Diagnosis in Slumping

The usual advice in looking at the reasons for breaks in your pieces must be considered in relation to the process being used.  Breaks during slumping need to be considered differently to those occurring during fusing.  

The advice normally is that if the edges are sharp, the break occurred on the way down in temperature. Therefore, the glass must have an annealing fracture or a compatibility break.  It continues on to say if the edges are rounded it occurred on the heat up, as it broke while brittle and then rounded with the additional heat.

This is true, but only on rounded tack and fused pieces.

When the process is a slump, there is not enough heat to round the edges.  So, the edges will be sharp whether the break was on the heat up or the cool down.

How can you tell in a slump process when the break occurred?

If you can put the pieces of the slump back together and they fit perfectly, the break was on the cool down, as the piece was already fully formed.

If the pieces do not fit together perfectly, the break was on the heat up.  This is because the break occurred, and then the two (or more) pieces slumped independently, thus leaving slightly different shapes at the break line.

There is a special case here, of course.  Sometimes the break is only a split in the bottom, that does not come all the way to the top of the piece. This split (or splits) occur when the heat up is too fast.  The top becomes plastic while the bottom is still brittle/stiff.  The weight of the hotter, more pliable glass overcomes the strength of the cooler and heat stressed bottom, causing it to split.  More information is given here: Diagnosis of Breaks

There is also more extensive information on diagnosis of breaks in this blog entry on slumping cracks.  

Slip cast moulds

Hard spots in some moulds are the result of the method of creating the moulds. Most of the ceramic moulds we use in kilnforming are slip cast.

This diagram shows the main stages of slip casting

Slip casting is a way of quickly producing multiples from a mould.  The original shape is surrounded by a one - or multiple - part plaster mould.  This mould is used to contain the clay slip which is poured in.  

The plaster absorbs water from the slip, stiffening the clay in contact with the plaster. After a defined time, the remaining slip is poured out of the mould.  The clay remains in the mould a short time until it begins to contract from the plaster mould and is described as leather hard.  

It is then de-moulded, trimmed and cleaned before it is further dried.  When appropriately dry, it is fired.

Some moulds we receive show a spot where the kiln wash does not cover the surface in the same way as the rest.  This is a result of the method of pouring the slip into the mould.  Slip that is hand poured does not fall in the same place for long.  But industrially poured slip often falls in the same place for the whole of the pour.  This creates a hard spot - an area where the slip is more compacted than the rest of the object.

This hard spot does not affect the appearance or performance of the object.  However, it does not absorb the water from the kiln wash as well as the other areas. And this is when the hard spot becomes apparent. It will still have enough separator to keep the glass from sticking, although visually it appears bare. If concerned, you can coat that area more than the rest after the kiln wash has dried a little.  You need to be careful that you do not introduce an unevenness into the kiln washed surface, as that might appear on the slumped surface of the glass.

Float Annealing Temperatures

Float glass annealing temperatures vary quite a bit from one manufacturer to another; and even within one manufacturer’s product line.

Comparisons of various float glasses

Some companies are more informative that others.  Pilkington are one of the more open of European glass manufacturers on various bits of information.

Pilkington Float

CoLE 83 *^10-5

Softening point:  715°C

annealing point:  548°C

strain point: 511C

Pilkington Optiwhite ™

Softening point:  ca. 732°C

annealing point:  ca. 559°C

strain point:  ca. 526°C

There is a difference of 11C between two of the Pilkington product lines for the annealing points.  The softening and strain points are slightly wider.

Glaverbel, a Belgian company, restricts their information to CoLE and the softening point.

CoLE 91 * 10^-5

Softening point: 600°C

Saint-Gobain, a French company, shows some more of the variation in the product lines, although they do not give specific annealing points for the different products.

CoLE 90 * 10^-5

annealing range:  520 - 550°C

Low E glass

softening – 840°C

strain - 617°C

R glass (sound reducing)

softening – 986°C

strain - 736°C

D glass (decorative)

softening point – 769°C

Compatibility

Even this small sample of float glasses shows there is a significant difference between manufacturers for the softening, annealing and strain points.  This means that, unless you are sure of the glass merchant’s source of glass, you will need to test each batch of glass for compatibility with previous batches, if you are combining from different suppliers.

I included the CoLE numbers (which all the manufacturers specified as an average change in length for each degree C increase in temperature from 0 to 300°C) to show the variation and to challenge anyone to find Bullseye and Saint-Gobain or Glaverbel compatible with each other.  My experience has shown that the Optul coloured frit and confetti is more likely to be compatible with Pilkington than the other two.

Annealing

I have been beginning my annealing of float glass at 525°C.  This little bit of literature research shows that my annealing soak should be starting higher, possibly at 540°C, certainly no lower than 530°C.  Other areas of the world may find their float glass has significantly different annealing ranges.

Broken base glass

Firing a piece with a partially covered base layer requires more care than two even layers to avoid the fracture of the glass during the heat up stage of a firing.  Slower rates of advance need to be used.

Glass is a poor conductor of heat and electricity. This can be good in certain circumstances but is usually one of the limitations in kilnforming.  The poor conductivity of glass means the top layer of glass will need to be heated before it begins to transmit heat to the glass below. 

A while back an example was shown that is a special case, but also illustrates the general principle (apologies to the poster, as I didn’t take down the name at the time and can’t find the original post now).

This sheet of clear glass was covered by an arrangement of stringers, with a border of clear exposed.  I don’t know positively, but I presume this was done in the knowledge that the single sheet of clear glass would become smaller, and the border would be cut down to the appropriate size.

Be that as it may, the exposure of the clear allowed the edges of the clear to heat up faster than the covered part of the sheet.  The stress of the temperature differential between the centre and the edges led to the fracture of the glass during the heat up.  This can be confirmed by the rounding of the broken edges.  It is further confirmed, by observing the relative straightness of the stringers, that the break occurred before the stringers became sticky enough to even laminate to the base glass - the clear glass broke underneath, leaving the stringers relatively undisturbed. It is also an indication that the glass broke earlier than the slumping temperature, as the stringers would have been sticky enough to break with the clear otherwise.

One speculation given for the break was that it was affected by the size.  You can see the size is relatively large for the kiln.  This may have had some influence on the fracture as well.  But it is not so much the size as the shielding of the heat from above for a large part of the base sheet. We don’t know if this was a side fired kiln, but if it was, there would be an increased exposure of the edges of the glass to the heat and so increase the likelihood of temperature differentials leading to too much stress for the base glass.

The rate of advance for partially covered sheets needs to be reduced to be slower than for evenly covered base sheets.  Even on evenly covered base sheets, there is a risk of breakage of the bottom sheet, if the rate of advance is too quick.  Slower heating reduces the temperature differentials, as the gradual rise in heat allows the glass to be closer in temperature from top to bottom.

Specific Gravity, CoLE, and Colourants of Glass

I’ve been asked the question “is there is differential in specific gravity as related to COE or colorant used in the glass (white opal v clear)”? 

Using the typical compositions of soda lime glass (the stuff we use in fusing), both transparent and opalescent and combining the specific gravity of the elements that go to make up the glass, I have attempted to answer question - the last part of the question first.

Difference in specific gravity between transparent and opalescent glass

Transparent glass

Typical transparent soda glass composition % by weight (with specific gravity) Material                         Weight        S.G. Silicon dioxide (SiO2)           73%         2.648 Sodium oxide (Na2O)            14%         2.27 Calcium oxide (CaO)               9%         3.34 Magnesium oxide (MgO)          4%         2.32 Aluminium oxide (Al2O3)          0.15%    3.987 Ferrous oxide (Fe2O3)               0.1        5.43 Potassium oxide (K2O)             0.03       2.32 Titanium dioxide (TiO2)            0.02        4.23

There are, of course minor amounts of flux and metals for colour in addition to these basic materials.

The specific gravity of typical soda lime glass is 2.45.

Opalescent glass

Initially opalescent glass was made using bone ash, but these tended to develop a rough surface due to crystal formation on the surface.  The incorporation of calcium phosphate (bone ash) and Flouride compounds and/or arsenic became the major method of producing opalescent glass for a time.

The current typical composition by weight (with specific gravities) is:

Silicon Dioxide (SiO2) –             66.2%,     2.648 SG

Sodium Oxide (Na2O) –            12%,        2.270

Boric Oxide (B2O3) –                10%,        2.550

Phosphorus pentoxide (P2O5) –  5%,         2.390

Aluminum Oxide (Al2O3) –         4.5%,      3.987

Calcium oxide (CaO) –              1.5%,      3.340

Magnesium oxide (MgO) -         0.8%,      2.320

The combined specific gravities are within 0.03% of each other -  a negligible amount.  So, the specific gravity of both opalescent and transparent glass can be considered to the same. For practical purposes, we take this to be 2.5 rather than the more accurate 2.45.

Other glasses exhibit different specific gravities due to the materials used, for example:

Lead Crystal Glass

Lead Crystal glass contains similar proportions of the above materials with the addition of between 2% and 38% lead by weight.  Due to this variation the specific gravity of lead crystal is generally between 2.9 and 3.1, but can be as high as 5.9.

Borosilicate glass

Non-alkaline-earth borosilicate glass (borosilicate glass 3.3)

The boric oxide (B₂O₃) content for borosilicate glass is typically 12–13% and the Silicon dioxide (SiO₂) content over 80%. CoLE 33

 

Alkaline-earth-containing borosilicate glasses

In addition to about 75% SiO₂ and 8–12% B₂O₃, these glasses contain up to 5% alkaline earths and alumina (Al₂O₃).  CoLE 40 – 50

 

High-borate borosilicate glasses

Glasses containing 15–25% B₂O₃, 65–70% SiO₂, and smaller amounts of alkalis and Al₂O₃

All these borosilicate glasses have a specific gravity of ca. 2.23

Correlation between CoLE and and specific gravity?

This comparison of different glasses shows that the materials used in making the glass have a strong influence on the specific gravity.  However, there does not appear to be a correlation between CoLE and specific gravity in the case of borosilicate glass.  If this can be applied to other glasses, there is no correlation between specific gravity and CoLE.

Correlation between specific gravity and colourisation minerals and CoLE?

The minerals that colour glass are a very small proportion of the glass composition (except copper where up to 3% may be used for turquoise).  The metals are held in suspension by the silica and glass formers.  That means the glass is moving largely independently of the colourants which are held in suspension rather than bring part of the glass structure. There is unlikely to be any significant effect of the metals on the Coefficient of Linear Expansion.  The small amounts of minerals are unlikely to have an effect on the specific gravity.  So, the conclusion is that there is no correlation between CoLE, specific gravity, and colouring minerals.

The short answer

This has been the long answer to the question.  The short answers are:

·         The specific gravity of soda lime transparent glass and opalescent glass is the same – no significant difference is in evidence.

·         There appears to be no correlation between specific gravity and CoLE.

·         There is unlikely to be any correlation between colourant minerals and CoLE or specific gravity.

Lubrication for cutters

You can cut glass without oil.  It has been done for a long time.  But it has been found that there are advantages to using oil on a score line.

The purpose of oil:

·        A minor element is to oil the cutter wheel.

·        A major element is to oil the score line.  An oiled score line stays open longer than a dry one.  

·        An oiled score line reduces the amount of visible chipping from the score line.

The kind of oil

·        Mineral oil does not oxidise to gum up the scoring wheel.

·        Any light mineral oil from sewing machine oil to WD40 is acceptable. Some use very light oils such as turpentine or white spirits.

·        There are cutting oils that are synthetic and easier to clean than the standard oils and spirits, in that less residue is left when the oil is wiped off.

·        Vegetable oils might appear to be a good substitute.  But they oxidise and become sticky, attracting dust and other particles which soon block the turning of the scoring wheel.  This requires frequent checking and cleaning.  Avoid vegtable oils.

Methods of applying

·        The oil can be put into the cutters that have a reservoir.

·        The cutter can be dipped into a container of oil with or without an oil-soaked material.

·        The oil can be painted onto the glass before scoring.

  Any combination of the above will work.

Frit by thermal shock

Frit can be created by thermal shock.  You will still need to do some manual breaking up. The principle is that you heat the glass and then cool it rapidly, causing the glass to break into pieces.

Place the glass in a stainless steel bowl and heat as fast as possible to 300C – 400C. Turn the kiln off and pull out the bowl, using heat resistant gloves and dump the hot glass into a large bucket of water. Once the glass is cool, pour off the water and dry the glass.  When dry, you can break the crazed glass into smaller bits just as you would with other glass.  Note that pouring water over the glass has two disadvantages – one, it does not completely thermal shock the glass, and two, the large amount of steam released is very dangerous.

The advantages of this quenching method of obtaining frit are that you can create frit with less effort.  You also get less fines and powder with this method. And less effort is required to smash up the glass.

Some indicate that ice cold water to quench the glass is a good idea.  This is because warm water will not provide enough of a shock to the glass to craze it throughout.  But if you have a large bucket of water, there is no necessity, as the volume of water will cool the glass quickly enough.  Of course, if you are planning another quenching, you need to renew the water, as it will not be cold enough to thoroughly craze the glass.

You can, in part, control the size of the resulting frit.  Firing at 300C results in larger frit than firing at 400C.  However, firing at 500C does not provide even smaller frit.  The best results are between 300-400C, although frit can be made at 200C as well.  Experiment with temperatures to get the frit you want.

Once you have dried the frit, you can begin to break it up. Some can be done by hand, but the pieces are often sharp, so gloves are essential.  The other standard methods of breaking up glass to make frit are applicable. But it does not take as much effort as breaking from cullett.

Annealing vs toughening

The statement “annealing stained glass makes it stronger” appeared on the internet some time ago.  Of course, without annealing there is no glass, it would simply crumble.  Annealing is the process of allowing the glaseous state to be achieved.

I think the statement is more about the difference between annealed and toughened/tempered glass.  In summary, it relates to the amount of stress within the glass.  Well annealed glass has less stress than inadequately annealed glass and so is more stable.  Toughening is a process that balances stress and tension in the glass.

The processes are for different purposes and follow different processes. 

Annealing

Annealing of glass is a process of slowly cooling hot glass to relieve residual internal stresses introduced during manufacture. Annealing of glass is critical to its durability. Glass that has not been properly annealed retains thermal stresses caused by rapid cooling, which decreases the strength and reliability of the product. Inadequately annealed glass is likely to crack or shatter when subjected to relatively small temperature changes or to minor mechanical shock. It even may fail spontaneously from its internal stresses.

To anneal glass, it is necessary to soak it at its annealing temperature. This is determined mathematically as a viscosity of 10¹³ Poise (Poise is a measure of viscosity). For most soda lime glass, this annealing temperature is in the range of 450–540°C, and is the so-called annealing point or temperature equalisation point of the glass. At such a viscosity, the glass is too stiff for significant change of shape without breaking, but it is soft enough to relax internal strains by microscopic flow. The piece then heat-soaks until its temperature is even throughout and the stress relaxation is adequate. The time necessary for annealing depends on its maximum thickness. The glass then is cooled at a predetermined rate until its temperature passes the strain point (viscosity = 10^14.5 Poise), below which even microscopic internal flow effectively stops and annealing stops with it. It then is safe to cool the product to room temperature at a rate limited by the thickness of the glass.

At the annealing point (viscosity = 10¹³ Poise), stresses relax within minutes, while at the strain point (viscosity = 10^14.5 Poise) stresses relax within hours.  Stresses acquired at temperatures above the strain point, and not relaxed by annealing, remain in the glass indefinitely and may cause either immediate or delayed failure. Stresses resulting from cooling too rapidly below the strain point are considered temporary, although they may be adequate to promote immediate failure.

But annealed glass, with almost no internal stress, is subject to microscopic surface cracks, and any tension gets magnified at the surface, reducing the applied tension needed to propagate the crack. Once it starts propagating, tension gets magnified even more easily, causing it at breaking point, to propagate at the speed of sound in the material.

In short, the aim of annealing is to relieve the stress to create a stable piece of glass. The above describes when and how that occurs.

Toughened/Tempered Glass

Toughening or tempering glass starts with annealed glass to form one type of safety glass.  This done through a process of controlled thermal or chemical treatments to increase its strength compared with normal glass. Tempering puts the outer surfaces into compression and the interior into tension. Such stresses cause the glass, when broken, to crumble into small granular chunks instead of splintering into jagged shards as annealed glass does. The granular chunks are less likely to cause injury – thus safety glass.

Toughened glass is stronger than normal glass.  The greater contraction of the inner layer during manufacturing induces compressive stresses in the surface of the glass balanced by tensile stresses internally. For glass to be considered toughened, the compressive stress on the surface of the glass should be a minimum of 69 megapascals (10,000 psi). For it to be considered safety glass, the surface compressive stress should exceed 100 megapascals (15,000 psi).

It is the compressive stress that gives the toughened glass increased strength. Any cutting or grinding must be done prior to tempering. Cutting, grinding, and sharp impacts after tempering will cause the glass to fracture.

Toughened glass is normally made from annealed sheet glass via a thermal tempering process. The glass is placed onto a roller table, taking it through a furnace that heats it well above its transition temperature of ca. 540°C (depending on the glass concerned) to around 620°C. The glass is then rapidly cooled with forced air drafts while the inner portion remains free to flow for a short time.

An alternative chemical toughening process involves forcing a surface layer of glass at least 0.1 mm thick into compression by ion exchange of the sodium ions in the glass surface with potassium ions (which are 30% larger), by immersion of the glass into a bath of molten potassium nitrate. Chemical toughening results in increased toughness compared with thermal toughening and can be applied to glass objects of complex shapes. 

This blog entry is largely based on Wikipedia

https://en.wikipedia.org/wiki/Toughened_glass

and other sources.

Slumping Different Glasses in the Same Firing

The question has arisen as to whether it is possible to slump Bullseye and Spectrum in same slump firing.

Yes, it is possible.

But precautions are necessary.

Different temperatures are generally recommended for Spectrum and Bullseye.  Spectrum is generally expected to do the same slump as Bullseye at 25C less.

This implies that Bullseye should be put in larger or easier slump moulds than Spectrum and fired to the lower temperature required by Spectrum. The thinking behind this is that smaller spans require longer or more heat to slump.  Steeper moulds require more time and heat than less steep ones.

In general, shallow slumps will work better for both glasses together than more steep or textured ones.

To be certain of a good result, you should fire as low as practical for an extended soak.  Follow this with an extended annealing and a slower cooling rate than normal for Spectrum.

This applies to almost all the glass that is being produced with the aim of being compatible with these two glasses.  It is not possible to get a good result for float glass if it is put into the same firing as for Bullseye or Spectrum.

Tack Fuse vs Fire polish

Are tack fuse and fire polish the same thing?

Maybe

They both occur in the same temperature same range, depending on the degree of tack fuse you want.

What you are doing in the fire polish process is heating the top surface enough to appear polished. Very little time is needed in a fire polish at top temperature as opposed to a tack fuse.

In a tack fuse, you want the bottom of the upper pieces to be hot enough to stick to the bottom layer. This requires a higher temperature or longer soak than a fire polish.

At around 730C, depending on your kiln, you will be softening the upper surface of the glass enough to give a polished appearance.  To determine whether the polished surface has been achieved, you can peek into your kiln at the chosen temperature to see if the polish is complete.

This is also the temperature at which sintering, or a lamination of the glass pieces occurs.  The edges will still be sharp, but cannot be pulled apart.  This kind of fusing needs careful annealing – long soaks and slow cools.

Tack fusing of various degrees occurs in the temperature range from 730C to 770C.  To determine which temperature and soak time will give you the result you desire will require experimentation and observation.  Generally, you can achieve the desired level of fuse with lower temperatures and longer soaks, as you can at higher temperatures and longer soaks. 

It is also possible to give a fire polish to your glass at a really low temperature, such as 550C, with a very long soak. This will avoid significantly flatening the surface of your piece.  This is the effect of heat work.

Further information is available in the ebook Low Temperature Kiln Forming.

The relative order of kiln forming events

When preparing for multiple firings of elements onto a prepared piece, you need to consider the order and temperatures of events so that you do not harm an earlier stage of the project.  This blog entry will not give definitive temperatures, as that varies by glass and by kiln.  Instead, it indicates what happens in progression from highest to lowest temperatures in approximate Celsius degrees.  

ca. 1300C  -  Approximate liquid temperature 

ca. 850 – 1000C  -  Glass blowing working temperature

ca. 950C  -  Raking and combing

ca. 850C  -  Casting

ca. 810C  -  Full fuse

ca. 790C  -  Large bubble formation

ca. 770C  -  High tack, low contour fuse

ca. 760C  -  Tack fuse

ca. 750C  -  Fire polish

ca. 700C – 760C  -  Devitrification range

ca. 700C  -  Lamination tack

ca. 600C – 680C  -  Slump and drape

ca. 650C  -  Vitreous paint curing temperature

ca. 600C  -  No risk of thermal shock above this temperature 

ca. 540 – 580C  -  Glass stainers enamel curing temperature

ca. 520 – 550C  -  Silver stain firing temperature

ca. 550C  -  Glass surface beginning to soften

Slow rates of advance needed from room temperature to ca. 500C

These temperatures are of course, affected by the soak times. The longer the soak time, the lower temperature required. The rate at which you achieve the temperature also affects the effective temperature.  Slower rates of advance require lower temperatures, than fast rises in temperature.  These illustrate the effect of heat work.

The table shows for example you need to do all the flat operations and firings before slumping or draping.  It also shows you can use vitreous glass paints at the same time as slumping and draping.  This emphasises that the standard practice is to plan the kind of firings you will need for the piece and do them in the order of highest temperature first, lowest last.

In general, you do need to do the highest temperature operation first and lowest last.  But there are some things you can do with heat work.  For example, if you needed to sandblast a tack fused piece, but did not want to risk reducing the differences in height there things you can do.  From the list above, you can see the glass surface begins to soften around 500C.  It is possible to soak the glass for a long time around 500C to give it a fire polish, instead of going to a much higher temperature.  You will need to experiment to find the right combination of temperature and soak length, but it can be done.

This article is to show that knowledge of what is happening to the glass at different temperatures, can help in “fooling” the glass into giving you the results you want without always following the “rules”.  This may also be what it is to be a maverick glass worker.  Use the behaviour of glass to your advantage.

Repairs to a Vermiculite Mould

Occasionally, during the demoulding of a form, the mould will break.  Not all is lost.  It can be repaired. 

In this example, the mould is not yet fully cured and is damp.  But this can be applied to fully cured and dried moulds too. Notes will be included where the practice varies for the dried mould.

The first stage is to make up a paste of the ciment fondue for the edge to edge repair.  This should be the consistency of pancake batter or slightly wetter.  The mixed cement is shown at the top of the picture in a small plastic tub.

Wet the edges of the mould pieces thoroughly.  This is to prevent the mould from sucking too much water from the cement, which would give a weak adhesion.  On dried moulds, you may have to do this several times to thoroughly wet the mould and the broken piece.

Then begin applying the wet cement thinly to all the edges.  Do not put it on thickly, as you want the pieces to fit back together smoothly. 

Place the pieces together with gentle pressure. 

Then begin to smooth the wet ciment fondue into the cracks between the broken pieces and the main body.  Be careful to smooth the ciment fondu immediately, as it is very difficult to change once cured.

Continue to work the ciment fondue into any cracks that appear as the mould is wetted.

Make sure the cement is smoothed into the cracks so there are no proud areas above or around the cracks.

This photo shows the smoothed ciment fondu on the interior.

Continue smoothing the cement into the cracks at the edges.

Fill the cracks from the outside also

When the application of the cement is completed, make up a mixture of 1:4 ciment fondue to vermiculite. 

The purpose of this is to strengthen the mould in the weak area.  It is not wise to rely entirely on the strength of the edge bonding of the ciment fondue.

You will need to estimate the total volume required, but it is better to mix too much rather than too little.  Make this mix a little wetter than for the original mould.  Water should not be standing in the mix, but you will be able to squeeze water from the ball of mix easily. 

This is especially important for moulds which have already been cured.  You should also put water on the surface that you are going to back up.

It is important to put a water proof material on the workbench to avoid the mould sticking to the bench, or water dripping over other things.

Having wetted the mould exterior again, begin applying the mix to the outside of the mould.

Continue building up the mixture in thin layers.  This allows the best adhesion of the material to the mould and to each layer.  It is easier to compact a small amount of material than a large amount all at one time.

In this photo, you see some of the water being forced out of the mixture by the compaction of the mix onto the mould.

Continue building around the broken area until you have applied sufficient material to the mould to strengthen it.

When you have finished, one area of the mould may be a little larger than the rest.  This is not a problem in its use, as it does not thermal shock, and it does not keep one part of the glass hotter than the glass touching the rest of the mould.

You can now loosely wrap the water proof material around the mould.  Do not seal it completely.  Place the mould in a plastic bag to cure for a day or more, just as for the original mould.

You can then unwrap the mould and fire it to cure it just as the original. The method for curing vermiculite moulds is given here.