Wednesday, 2 October 2013

What is Viscosity

What is Viscosity?

An example of differing viscosities

There are a variety of definitions, but these two capture the main elements.

Informally, viscosity is the quantity that describes a fluid's resistance to flow. Fluids resist the relative motion of immersed objects through them as well as to the motion of layers with differing velocities within them.  Source

Viscosity is a measure of a fluid's resistance to flow. It describes the internal friction of a moving fluid. A fluid with large viscosity resists motion because its molecular makeup gives it a lot of internal friction. A fluid with low viscosity flows easily because its molecular makeup results in very little friction when it is in motion.  Source

A demonstration of the resistance of different viscosities of oil to a weight moving through the liquid.

Almost all liquids are viscous fluids having viscidity. For example, when rotating a drum container filled with water on its vertical central axis, the water that was at rest in the beginning starts moving as it is dragged by the container’s inside wall and then whirls completely together with the container as if it were a single rigid body. This is caused by the force (resistance) generated in the direction of the flow (movement) on the surfaces of the water and the container’s inside wall. A fluid that generates this kind of force is regarded as having viscosity.

Temperature is a very important factor for measuring viscosity. In fluids, as temperature goes up, viscosity goes down and vice versa. In the case of distilled water, if the temperature changes 1 centigrade, it produces a difference of 2 % to 3 % in viscosity.  Source

Viscosity is the measurement of a fluid's internal resistance to flow. This is typically designated in units of centipoise or poise but can be expressed in other acceptable measurements as well. Source

Why is viscosity important?

Near the strain point the expansion increases rapidly and sometimes erratically.” The links between the molecules has reduced in strength and so have a lesser role in the forces acting at higher temperatures. “In those upper ranges – the temperatures where glasses are formed and re-formed with heat – viscosity is a much more useful indicator of how glasses will behave.

“The combination of viscosity and COE are what make glasses more or less compatible, i.e., containing stress in amounts low enough to allow them to hold together without breaking at room temperature for extended periods of time under normal circumstances.

Bullseye found in the early 1980s in their efforts to mix coloured glasses in streaky colour combinations that the COE could not be used to predict compatibility. In trying to correct the compatibility of certain mixed glasses, the closer they brought together the COEs, the more incompatible became the mixes.

“The reason that we could not use COE to successfully predict whether a coloured glass would fit the base clear glass was/is because, as the base glass composition is altered with the addition of the necessary oxides to colour it, the viscosity is inevitably changed. This viscosity change causes the coloured glass and the clear base glass to strain themselves in the cooling cycle of the fusing process (a viscosity mismatch). Therefore once the two glasses reach room temperature they have undue residual strain that may lead to failure.

“In order to prevent this undue residual strain an equal but opposite strain must be introduced into the coloured glass to cancel out the strain induced by the viscosity mismatch. This is accomplished by introducing an expansion mismatch of equal but opposite strain. The two mismatches cancel each other out, leaving the two glasses nearly strain free.

“It is this phenomenon (viscosity mismatch cancelled out by an equal but opposite expansion mismatch) that enables glasses of very different compositions to be formulated to fit each other. The very fact that the expansion of a coloured glass has to be altered to make it fit a base clear glass implies that COE cannot be used as an indicator of compatibility. It is also why it only makes sense to describe these glasses as tested compatible to a specific manufacturer's base glass for a specific glass forming process.“ [L. MacGreggor]

Even different formulations of glass have different viscosities and different rates of softening with temperature increases.

How does viscosity apply to us?

Although viscosity is of major importance to the manufacturer, it does have some relevance to kiln formers too.

Understanding that glasses have different viscosities – most often referred to as hard and soft – can help in the choice of colours and styles of glass to combine. Some glass will spread more, and also allow other glass to sink deeper into the layer than others. It might help avoid combining extremely hard and soft glasses next to each other.

It should also help explain some results that were not planned. It may help in when thinking about uneven slumps.

It is important to recognise that glass chemistry is extremely complicated, and to see that the expansion characteristics have to be balanced with the viscosity characteristics as the two main elements in compatibility. There are others, of course, but these appear to the two main ones.